Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite:
Gespeichert in:
| Beteilige Person: | |
|---|---|
| Format: | Hochschulschrift/Dissertation Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
Hamburg
2024
|
| Schlagwörter: | |
| Links: | https://d-nb.info/1331344875/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=035474595&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| Umfang: | xxii, 233 Seiten Illustrationen, Diagramme 30 cm |
Internformat
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| 100 | 1 | |a Neves, André |e Verfasser |0 (DE-588)1325612359 |4 aut | |
| 245 | 1 | 0 | |a Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite |c vorgelegt von André Martins Neves |
| 264 | 1 | |a Hamburg |c 2024 | |
| 300 | |a xxii, 233 Seiten |b Illustrationen, Diagramme |c 30 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |b Dissertation |c Helmut-Schmidt-Universität/Universität der Bundeswehr Hamburg |d 2024 | ||
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 856 | 4 | 2 | |m B:DE-101 |q application/pdf |u https://d-nb.info/1331344875/04 |3 Inhaltsverzeichnis |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=035474595&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-035474595 | |
Datensatz im Suchindex
| _version_ | 1823676153200640000 |
|---|---|
| adam_text |
TABLE
OF
CONTENTS
LEBENSLAUF
.
DEDICATORY
.
ABSTRACT
.
.
ZUSAMMENFASSUNG
.
LIST
OF
FIGURES
.
XI
LIST
OF
TABLES
.
XVI
LIST
OF
ABBREVIATIONS
AND
ACRONYMS
.
XIX
LIST
OF
SYMBOLS
AND
OPERATORS
.XX
LIST
OF
INDEXES
.
XXI
LIST
OF
UNITS
.XXII
LIST
OF
METRIC
PREFIXES
.
XXII
1.
INTRODUCTION
.
1
1.1.
CLIMATE
CHANGE
AND
THE
ENERGY
SECTOR
.
1
1.2.
PRODUCTION
AND
USE
OF
RENEWABLE
ENERGY
.
4
1.3.
HYDROGEN
STORAGE
IN
HYDRIDES
.
5
1.4.
THERMODYNAMICS
OF
METAL
HYDRIDES
.
6
1.5.
KINETICS
IN
METAL
HYDRIDES
.
8
1.6.
THE
LIBH4
AND
THE
LITHIUM
REACTIVE
HYDRIDE
COMPOSITE
(LI-RHC)
.
12
1.7.
HYDRIDE-BASED
HYDROGEN
STORAGE
TANKS
AND
ADIABATIC
TANK
CONCEPT
.
16
1.8.
THE
CAO/CA(OH)
2
AS
A
TCESM
.
19
1.9.
SCOPE
OF
THE
WORK.
.20
2.
MATERIALS
AND
METHODS.
23
2.1.
PREPARATION
OF
LI-RHC
SAMPLES
.
23
2.1.1.
PREPARATION
OF
THE
POWDER
SAMPLES
(KINETIC
MODELLING)
.
23
2.1.2.
PREPARATION
OF
THE
POWDER
SAMPLES
(UP-SCALED
INVESTIGATION)
.
24
2.1.3.
PRESSING
OF
THE
PELLETS
.
24
2.2.
CHARACTERISATION
OF
THE
LI-RHC
.
24
2.2.1.
KINETICS
OF
THE
HYDROGEN
REACTIONS
AND
DATA
HANDLING
.
25
2.2.2.
PHASE
IDENTIFICATION
.
26
2.3.
MODELLING
OF
THE
REACTIONS
'
KINETICS
.
26
2.3.1.
IMPLEMENTATION
OF
THE
SEPARABLE
VARIABLE
METHOD
.
27
2.4.
FINITE
ELEMENT
SIMULATIONS
.
29
2.4.1.
SIMULATION
SUITE
.
29
2.4.2.
MAIN
ASSUMPTIONS
AND
PHYSICAL
MODELS
.
29
3.
KINETIC
MODELLING
OF
THE
LI-RHC
SYSTEM
-
ABSORPTION
REACTION
.
45
3.1.
RESULTS
.
45
3.1.1.
THERMODYNAMIC
DATA
.45
3.1.2.
KINETIC
DATA
.46
3.1.3.
DETERMINATION
OF
THE
REACTION
MODEL
-
G(A)
.49
3.1.4.
DETERMINATION
OF
THE
TEMPERATURE
DEPENDENCY
-
K(T)
.
51
3.1.5.
DETERMINATION
OF
THE
PRESSURE
DEPENDENCY
-
F(P)
.
53
3.2.
DISCUSSION
.
57
3.2.1.
CRITICAL
ASSESSMENT
OF
THE
THERMODYNAMIC
DATA
.
57
3.2.2.
EFFECT
OF
CYCLING
ON
THE
CAPACITY
.
59
3.2.3.
REACTION
MODEL
.
62
3.2.4.
PRESSURE
DEPENDENCY
.
63
3.2.5.
VALIDATION
OF
THE
MODEL
.
64
3.2.6.
THERMODYNAMIC
STABILITY
AND
KINETIC
BEHAVIOUR:
ISOKINETIC
CONTOUR
GRAPHS
.
65
4.
KINETIC
MODELLING
OF
THE
LI-RHC
SYSTEM
-
DESORPTION
REACTIONS
.
69
4.1.
RESULTS
.
69
4.1.1.
THERMODYNAMIC
DATA
.
69
4.1.2. KINETIC
DATA
.
70
4.1.3.
DETERMINATION
OF
THE
REACTION
MODEL
-
G(A)
.
71
4.1.4.
DETERMINATION
OF
THE
TEMPERATURE
DEPENDENCY
-
K(T)
.
77
4.1.5.
DETERMINATION
OF
THE
PRESSURE
DEPENDENCY
-
F(P)
.
78
4.2.
DISCUSSION
.
82
4.2.1.
POWDER
CHARACTERISATION
.
82
4.2.2.
THERMODYNAMIC
BEHAVIOUR
UNDER
DESORPTION
CONDITIONS
.
83
4.2.3. PRESSURE
DEPENDENCY
.
84
4.2.4.
VALIDATION
OF
THE
MODEL
.
84
4.2.5.
FINITE
ELEMENT
SIMULATIONS:
APPLICATION
OF
THE
DIFFERENTIAL
FORM
OF
THE
KINETIC
EXPRESSION
.
87
5.
SCALED-UP
PRODUCTION
OF
LI-RHC
FOR
THE
ADIABATIC
TANK
.
91
5.1.
RESULTS
.
91
5.1.1.
ESTIMATION
OF
THE
KINETIC
PARAMETERS
OF
LI-RHC
WITH
3TICL,
'
AICIS
.
91
5.1.2.
PREPARATION
AND
CHARACTERISATION
OF
LI-RHC
PELLETS
.
93
5.1.3.
ESTIMATION
OF
THE
HEAT
CONDUCTIVITY
FOR
LI-RHC
PELLETS
AT
HIGH
TEMPERATURES
.
95
5.1.4.
MODELLING
OF
THE
GAS
PERMEABILITY
IN
LI-RHC
PELLETS
.
97
5.1.5.
DIGITAL
TWIN
OF
THE
PELLET
'
S
LABORATORY
SCALE
EXPERIMENTS
.
100
5.2.
DISCUSSION
.
110
5.2.1.
CHANGE
IN
CATALYST:
FROM
TICIS
TO
3TICL3AICL3
.
110
5.2.2.
COMPARATIVE
STUDY
ON
PELLET
'
S
H
2
-CAPACITY
.
110
5.2.3.
DIGITAL
TWIN
OF
THE
PELLET
'
S
ABSORPTION
AND
DESORPTION
BEHAVIOUR
.
114
6.
ADIABATIC
TANK
DESIGN
APPLYING
FEM
SIMULATIONS
.
115
6.1.
OVERVIEW
AND
DESIGN
DEVELOPMENT
.
115
6.2.
RESULTS
.
117
6.2.1.
2-D
TANK
GEOMETRY
.
117
6.2.2.
3-D
TANK
GEOMETRY
.
132
6.3.
DISCUSSION
.
144
6.3.1.
INFLUENCE
OF
CAVITY
PLACEMENT.
144
6.3.2.
INFLUENCE
OF
TANK
HEIGHT
.
146
6.3.3.
PARAMETRIC
ANALYSIS:
EFFECTIVE
HEAT
CONDUCTIVITY
OF
THE
TCESM
.
149
6.3.4.
PERFORMANCE-LIMITING
FACTOR
FOR
LI-RHC
.
151
7.
CONCLUSIONS
.
153
8.
OUTLOOK
.
155
9.
ACKNOWLEDGEMENTS
.
157
10.
REFERENCES
.
159
11.
LIST
OF
PUBLICATIONS
.
171
12.
OTHER
WORKS
.
173
APPENDIX
A
-
THERMODYNAMIC
ASSESSMENT
UNDER
ABSORPTION
CONDITIONS
.
175
APPENDIX
B
-
REPORTING
OF
THE
KINETIC
CURVES
.
177
APPENDIX
C
-
DETERMINATION
OF
THE
KINETIC
MODEL
(G(A))
.
179
APPENDIX
D
-
DETERMINATION
OF
THE
EMPIRICAL
KINETIC
CONSTANT
(K(T,
P))
.
181
APPENDIX
E
-
DETERMINATION
OF
PRESSURE
DEPENDENCY
(F(P))
.
183
APPENDIX
F
-
SUMMARY
OF
DESORPTION
MODELLING
RESULTS
.
193
APPENDIX
G
-
COEFFICIENT
OF
DETERMINATION
(R
2
)
CALCULATION
.
199
APPENDIX
H
-
ERROR
PROPAGATION
AND
ERROR
ESTIMATION
.
201
APPENDIX
I
-
DESORPTION
MODELLING:
PHYSICAL
PARAMETERS
FOR
SAMPLE
HOLDER
FEM
MODEL
.
203
APPENDIX
J
-
PELLET
'
S
HEIGHT
AND
DENSITY
CALCULATION
.
207
APPENDIX
K
-
DESORPTION
KINETICS
OF
LI-RHC
PELLETS
.
209
APPENDIX
L
-DATA
AND
EQUATIONS
FOR
FEM
SIMULATIONS
.
211
APPENDIX
M
-
ADIABATIC
TANK
PROTOTYPE
.
221
APPENDIX
N
-
ESTIMATION
OF
THE
SPECIFIC
HEAT
CAPACITY
FOR
THE
LI-RHC
.
225
APPENDIX
0
-
THE
PROUT-TOMPKINS
MODEL
.
227
ANNEX
A
-
TECHNICAL
DRAWINGS
.229 |
| any_adam_object | 1 |
| author | Neves, André |
| author_GND | (DE-588)1325612359 |
| author_facet | Neves, André |
| author_role | aut |
| author_sort | Neves, André |
| author_variant | a n an |
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| indexdate | 2025-02-10T13:11:48Z |
| institution | BVB |
| language | English |
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| physical | xxii, 233 Seiten Illustrationen, Diagramme 30 cm |
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| spelling | Neves, André Verfasser (DE-588)1325612359 aut Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite vorgelegt von André Martins Neves Hamburg 2024 xxii, 233 Seiten Illustrationen, Diagramme 30 cm txt rdacontent n rdamedia nc rdacarrier Dissertation Helmut-Schmidt-Universität/Universität der Bundeswehr Hamburg 2024 (DE-588)4113937-9 Hochschulschrift gnd-content B:DE-101 application/pdf https://d-nb.info/1331344875/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=035474595&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Neves, André Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite |
| subject_GND | (DE-588)4113937-9 |
| title | Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite |
| title_auth | Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite |
| title_exact_search | Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite |
| title_full | Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite vorgelegt von André Martins Neves |
| title_fullStr | Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite vorgelegt von André Martins Neves |
| title_full_unstemmed | Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite vorgelegt von André Martins Neves |
| title_short | Development of an adiabatic hydrogen storage system based on lithium reactive hydride composite |
| title_sort | development of an adiabatic hydrogen storage system based on lithium reactive hydride composite |
| topic_facet | Hochschulschrift |
| url | https://d-nb.info/1331344875/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=035474595&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT nevesandre developmentofanadiabatichydrogenstoragesystembasedonlithiumreactivehydridecomposite |