Verfügbarkeit: Helicene chemistry | Technische Universität München

Helicene chemistry: from synthesis to applications

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Bibliographische Detailangaben
Beteiligte Personen:	Chen, Chuan-Feng (VerfasserIn), Shen, Yun 1983- (VerfasserIn)
Format:	Buch
Sprache:	Englisch
Veröffentlicht:	Berlin ; Heidelberg Springer [2017]
Schlagwörter:	Chemistry Organic chemistry Physical chemistry Catalysis Optical materials Electronic materials Organic Chemistry Optical and Electronic Materials Physical Chemistry Chemie Helicene
Links:	http://www.springer.com/ http://deposit.dnb.de/cgi-bin/dokserv?id=cae1d2120c4c4f7fb090aef7d50fec45&prov=M&dok_var=1&dok_ext=htm http://d-nb.info/1104952769/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029721875&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Beschreibung:	Literaturangaben
Umfang:	xiv, 272 Seiten Illustrationen, Diagramme 23.5 cm x 15.5 cm
ISBN:	3662531666 9783662531662

Internformat

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Datensatz im Suchindex

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adam_text	CONTENTS PART I WHAT ARE HELICENES? 1 INTRODUCTION TO HELICENE CHEMISTRY........................................................ 3 1.1 INTRODUCTION....................................................................................... 3 1.2 A HISTORICAL OVERVIEW..................................................................... 5 1.3 OBJECTIVES AND LITERATURE COVERAGE............................................... 10 1.4 BOOKS AND REVIEWS ON HELICENE CHEMISTRY ................................... 11 REFERENCES...................................................................................................... 13 2 STRUCTURES AND PROPERTIES OF HELICENES................................................. 19 2.1 STRUCTURAL FEATURES............................................................................ 19 2.2 THE 7U-SYSTEMS..................................................................................... 23 2.3 THE HELICITY....................................................................................... 27 2.4 OTHER PROPERTIES................................................................................ 31 2.5 HELICENES WITH OPEN SHELL AND CHARGES ........................................ 34 REFERENCES...................................................................................................... 36 PART II HOW TO PREPARE HELICENES? 3 OXIDATIVE PHOTOCYCLIZATION....................................................................... 43 REFERENCES...................................................................................................... 66 4 DIELS-ALDER AND FRIEDEL-CRAFTS-TYPE REACTIONS ................................. 71 4.1 DIELS-ALDER REACTIONS..................................................................... 71 4.2 FRIEDEL-CRAFTS-TYPE REACTIONS........................................................ 78 REFERENCES...................................................................................................... 84 5 METAL-MEDIATED REACTIONS ......................................................................... 87 5.1 [2+2+2] CYCLOISOMERIZATION ............................................................. 88 5.1.1 ROUTES A AND A ................................................................... 88 5.1.2 ROUTE B ................................................................................ 92 5.1.3 ROUTES C AND C ................................................................... 93 VIII CONTENTS 5.2 OTHER METAL-MEDIATED REACTIONS ....................................................... 97 5.2.1 PD-CATALYZED REACTIONS...................................................... 98 5.2.2 RU-MEDIATED REACTIONS...................................................... 106 5.2.3 TI-MEDIATED REACTIONS ........................................................ 107 5.2.4 RH-MEDIATED REACTIONS...................................................... 107 5.2.5 FE-MEDIATED REACTIONS...................................................... 109 5.2.6 AU-MEDIATED REACTIONS...................................................... ILL REFERENCES....................................................................................................... ILL 6 OTHER SYNTHETIC M ETHODS.......................................................................... 117 REFERENCES....................................................................................................... 134 7 ASYMMETRIC SYNTHESIS................................................................................. 137 7.1 ENANTIOSELECTIVE ROUTES ................................................................... 139 7.2 DIASTEREOSELECTIVE ROUTES................................................................. 144 7.3 ROUTES BASED ON OPTICALLY PURE PRECURSORS.................................. 148 REFERENCES....................................................................................................... 150 8 REACTIVITY AND TRANSFORMATIONS............................................................... 153 8.1 TRANSFORMATION OF THE HELICAL SKELETONS ........................................ 154 8.2 DIRECT C-H FUNCTIONALIZATION .......................................................... 157 8.3 TRANSFORMATION OF THE FUNCTIONAL GROUPS ...................................... 163 8.4 PREPARATION OF HELICENE-EMBEDDED ORGANOMETALLICS .................... 166 8.4.1 METALLOCENES WITH HELICENES............................................. 166 8.4.2 COMPLEXES WITH HELICENIC LIGANDS.................................. 170 REFERENCES....................................................................................................... 179 PART III WHAT ARE THE APPLICATIONS OF HELICENES? 9 HELICENES IN CATALYSIS................................................................................. 187 9.1 HELICENES AS INDUCERS........................................................................ 188 9.2 HELICENE AMIDE................................................................................. 189 9.3 HELICENES WITH OXYGEN FUNCTIONALITIES........................................... 189 9.4 HELICENES WITH NITROGEN FUNCTIONALITIES ........................................ 189 9.5 HELICENES WITH PHOSPHORUS FUNCTIONALITIES .................................... 192 REFERENCES....................................................................................................... 198 10 RECOGNITION, SENSORS, AND RESPONSIVE SWITCHES .................................... 201 10.1 HELICENES FOR MOLECULAR RECOGNITION............................................. 202 10.2 HELICENES AS SENSORS.......................................................................... 206 10.3 RESPONSIVE SWITCHES.......................................................................... 210 10.3.1 PH-RESPONSIVE SWITCHES.................................................... 210 10.3.2 REDOX-RESPONSIVE SWITCHES............................................. 213 10.3.3 PHOTO-RESPONSIVE SWITCHES ............................................... 217 REFERENCES....................................................................................................... 218 CONTENTS IX 11 HELICENES IN BIOCHEMISTRY.......................................................................... 221 REFERENCES....................................................................................................... 227 12 CIRCULARLY POLARIZED LUMINESCENCE AND ORGANIC ELECTRONICS ........... 229 12.1 CIRCULARLY POLARIZED LUMINESCENCE ................................................. 229 12.2 ORGANIC ELECTRONICS............................................................................ 236 12.2.1 HELICENES IN OLEDS.......................................................... 236 12.2.2 HELICENES IN TRANSISTORS...................................................... 238 12.2.3 MISCELLANEOUS ..................................................................... 241 REFERENCES....................................................................................................... 244 13 HELICENE ASSEMBLIES..................................................................................... 247 13.1 INTERFACIAL SELF-ASSEMBLY................................................................. 248 13.2 ORGANOGELS......................................................................................... 254 13.3 OTHER ASSEMBLIES.............................................................................. 258 REFERENCES....................................................................................................... 263 APPENDIX: IMPORTANT HELICENE COMPOUNDS ................................................. 267
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author	Chen, Chuan-Feng Shen, Yun 1983-
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id	DE-604.BV044318352
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indexdate	2024-12-20T17:59:44Z
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isbn	3662531666 9783662531662
language	English
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spellingShingle	Chen, Chuan-Feng Shen, Yun 1983- Helicene chemistry from synthesis to applications Chemistry Organic chemistry Physical chemistry Catalysis Optical materials Electronic materials Organic Chemistry Optical and Electronic Materials Physical Chemistry Chemie Helicene (DE-588)4159497-6 gnd
subject_GND	(DE-588)4159497-6
title	Helicene chemistry from synthesis to applications
title_auth	Helicene chemistry from synthesis to applications
title_exact_search	Helicene chemistry from synthesis to applications
title_full	Helicene chemistry from synthesis to applications Chuan-Feng Chen, Yun Shen
title_fullStr	Helicene chemistry from synthesis to applications Chuan-Feng Chen, Yun Shen
title_full_unstemmed	Helicene chemistry from synthesis to applications Chuan-Feng Chen, Yun Shen
title_short	Helicene chemistry
title_sort	helicene chemistry from synthesis to applications
title_sub	from synthesis to applications
topic	Chemistry Organic chemistry Physical chemistry Catalysis Optical materials Electronic materials Organic Chemistry Optical and Electronic Materials Physical Chemistry Chemie Helicene (DE-588)4159497-6 gnd
topic_facet	Chemistry Organic chemistry Physical chemistry Catalysis Optical materials Electronic materials Organic Chemistry Optical and Electronic Materials Physical Chemistry Chemie Helicene
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work_keys_str_mv	AT chenchuanfeng helicenechemistryfromsynthesistoapplications AT shenyun helicenechemistryfromsynthesistoapplications

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