Nanopatterned and nanoparticle-modified electrodes:
Gespeichert in:
Weitere beteiligte Personen: | , , |
---|---|
Format: | Buch |
Sprache: | Englisch |
Veröffentlicht: |
Weinheim
Wiley-VCH Verlag GmbH & Co. KGaA
[2017]
|
Schriftenreihe: | Advances in electrochemical science and engineering
17 |
Schlagwörter: | |
Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029677649&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
Umfang: | XIX, 409 Seiten Illustrationen, Diagramme |
ISBN: | 9783527340927 |
Internformat
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943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-029677649 |
Datensatz im Suchindex
_version_ | 1819257533162848256 |
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adam_text | V
1
1.1
1.2
1.3
1.4
1.4.1
1.4.2
1.5
1.5.1
1.5.2
1.5.3
1.6
1.7
1.7.1
1.7.2
1.8
2
2.1
2.2
2.2.1
2.2.2
2.2.3
2.2.4
Contents
List of Contributors XI
Series Preface XVII
Preface XIX
Surface Electrochemistry with Pt Single-Crystal Electrodes 1
Victor Climerit and Juan M. Fefiu
Introduction 1
Concepts of Surface Crystallography 2
Preparation of Single-Crystal and Well-Oriented Surfaces 9
Understanding the Voltammetry of Platinum 13
CO Charge Displacement Experiment 15
Stepped Surfaces 18
Potential of Zero Charge of Platinum Single Crystals 24
Total Charge Curves in Coulometric Analysis 29
Model for the Estimation of the Potential of Zero Free Charge 32
Applications of Electrocapillary Equation 32
The Laser-Induced Temperature Jump Method and the Potential of
Maximum Entropy 34
Electrocatalytic Studies with Single-Crystal Electrodes 40
Carbon Monoxide on Platinum 40
Oxygen Reduction 43
Concluding Remarks 47
Acknowledgments 49
References 49
Electrochemically Shape-Controlled Nanoparticles 59
Lu Wei, Na Tian, Zhi Y. Zhou, and Shi G. Sun
Introduction 59
Metal Nanoparticles of High-Index Facets and High Surface
Energy 60
NPs of {hkO} High-Index Facets 61
NPs of {hkk} High-Index Facets 66
NPs of {hhl} High-Index Facets 66
NPs of {hkl} High-Index Facets 69
VI
Contents
2.2.5 Electrochemistry-Mediated Shape Evolution 71
2.2.6 Electrochemical Milling and Faceting 72
2.3 Metallic Alloy Nanoparticles of High-Index Facets and High Surface
Energy 73
2.3.1 Pd-Pt Alloy NPs 74
2.3.2 Pt-Rh Alloy NPs 76
2.3.3 Fe-Ni Alloy NPs 77
2.4 Metal Nanoparticles of Low-Index Facets 79
2.4.1 Fe NPs with High Surface Energy 79
2.4.2 Cu NPs 81
2.4.3 Pt NPs 83
2.5 Nanoparticles of Metal Oxides and Chalcogenides 84
2.5.1 Cuprous Oxide 84
2.5.2 Lead Sulfide 89
2.6 Summary and Perspectives 90
Acknowledgment 91
References 91
3 Direct Growth of One-, Two-, and Three-Dimensional Nanostructured
Materials at Electrode Surfaces 97
SapanbirS. Thind and Aicheng Chen
3.1 Introduction 97
3.2 Growth of ID Nanomaterials 98
3.3 Nanowires 98
3.3.1 Formation of Na2Ti6013, H2Ti307, and Ti02 Nanowires 99
3.3.2 Synthesis of Various Nanowires Using Porous Anodic Alumina
(PAA) Templates 104
3.3.3 Ti02 Nanowires through Thermal Oxidation Treatment 106
3.4 Nanorods 108
3.4.1 Effect of Oxygen Source on the Formation of Titanium Oxide
Films 110
3.5 Nanotubes 113
3.5.1 Nanotube Growth Control 116
3.5.1.1 Effect of Fluorine Concentration 116
3.5.1.2 Length and Diameter of Nanotubes 117
3.5.2 Modification of Ti02 Nanotubes 119
3.6 Direct Growth of Two-Dimensional Nanomaterials 121
3.6.1 Nanoplates 121
3.6.2 Graphene Oxide Nanosheets 126
3.7 Growth of Three-Dimensional Nanomaterials 128
3.7.1 Nanodendrites 128
3.7.2 Nanoflowers 130
3.8 Summary 135
Acknowledgments 136
References 136
Contents
Vil
4 One-Dimensional Pt Nanostructures for Polymer Electrolyte
Membrane Fuel Cells 145
Gaixia Zhang and Shuhui Sun
4.1 Introduction 145
4.2 Shape-Controlled Synthesis of ID Pt Nanostructures 146
4.2.1 ID Pt Nanowires/Nanorod and Nanotubes 148
4.2.1.1 Pt Nanowires/Nanorods 148
4.2.1.2 Pt Nanotubes 161
4.2.1.3 Pt Multipods 174
4.3 ID Pt-Based Nanostructures as Electrocatalysts for PEM Fuel
Cells 176
4.3.1 Reaction Mechanisms for PEMFCs 176
4.3.2 Cathode Catalysts for ORR in DHFC 176
4.3.2.1 Comparison of the Electrocatalytic Performance of Supportless Pt
Nanotubes and Pt/C toward ORR 177
4.3.2.2 Comparison of the Electrocatalytic Performance of Star-Like Pt
Nanowires/C and Pt/C toward ORR 179
4.3.3 Anode Catalysts for MOR in DMFC 181
4.3.3.1 Comparison of the Electrocatalytic Performance of Pt
Nanowires/Ti02 and Pt/C toward MOR 181
4.3.3.2 Comparison of the Electrocatalytic Performance of Pt
Nanowires/CNT@SnNW and Pt/C toward MOR 183
4.3.3.3 Comparison of the Electrocatalytic Performance of Pt DNTs, Pt
SNTs, and Pt/C toward MOR 184
4.3.4 Anode Catalysts for FAOR in Direct Formic Acid Fuel Cell
(DFAFC) 185
4.3.4.1 Comparison of the Electrocatalytic Performance of Pt Multipods, Pt
Disks, and Pt Hexagons toward Formic Acid Oxidation 187
4.3.4.2 Comparison of the Electrocatalytic Performance of Pt Y-Junction, Pt
Nanowires (NW), and Pt/C toward Formic Acid Oxidation 188
4.4 Conclusions and Outlook 189
References 190
5
5.1
5.2
5.3
5.4
5.5
5.5.1
5.5.2
5.5.3
Investigations of Capping Agent Adsorption for Metal Nanoparticle
Stabilization and the Formation of Anisotropic Gold
Nanocrystals 199
Ian J. Burgess
Introduction and Scope 199
The Multifunctional Role of Nanoparticle Capping Agents 199
Controlled Growth of Anisotropic Nanoparticle 201
Measuring Capping Agent Adsorption 202
Experimental Techniques 203
Single-Crystal Gold Electrode Preparation 203
Chronocoulometry and the Back-Integration Technique 205
Gibbs Excesses of the Acid/Base Forms of the Capping Agents 205
VIII
Contents
5.5.4
5.6
5.6.1
5.6.2
5.7
5.7.1
5.7.2
5.7.3
5.8
5.8.1
5.8.2
5.8.3
5.8.4
5.8.5
5.8.6
5.9
6
6.1
6.2
6.3
6.4
6.5
6.6
6.7
6.7.1
6.7.2
6.8
6.8.1
6.8.2
6.8.2.1
6.8.2.2
6.8.3
6.9
6.10
6.11
Gibbs Excesses of Co-adsorbed Capping Agents 207
Citrate-Stabilized Nanoparticles 208
Citrate Adsorption on Au(l 11) Electrodes 208
Citrate-Stabilized Gold Nanoparticles 210
Quaternary Ammonium Surfactants as Capping Agents 212
Model Surfactant Adsorption on Gold Single Crystals 212
Halide Co-adsorption on Gold Single Crystals 214
Implications for Nanoparticle Systems 215
Pyridine Derivative Capping Agents 217
4-Dimethylaminopyridine (DMAP)-Stabilized Au
Nanoparticles 217
DM AP Adsorption on Polycrystalline Au 219
Competitive Adsorption Effects 226
DMAP Adsorption on Single-Crystal Au Surfaces 229
Directed Growth Using DMAP as a Capping Agent 231
4-Methoxypyridine (MOP)-Stabilized Au Nanoparticles 235
Conclusions and Perspectives 239
Acknowledgments 239
References 240
Intercalation of Ions into Nanotubes for Energy Storage - A
Theoretical Study 247
Leila Mohammadzadeh, Aleksej Goduljan, Fernanda Juarez, Paola Quaino,
Elizabeth Santos, and Wolfgang Schmickler
Introduction 247
Ionization in Nanotubes 248
Electrostatic Interactions 250
Details of the Investigated Systems 251
Ionic Charges 252
Effect of Ion Insertion on the Band Structure 253
Screening of the Coulomb Potential 255
Potential along the Axis 255
Effective Image Radius 257
Energetics of Ion Insertion 259
Optimum Position 259
Insertion Energies in CNTs 261
Anions in CNTs 261
Cations in CNTs 262
Ions in Gold Nanotubes 262
Capacity of a Narrow Nanotube in Contact with an Ionic
Liquid 264
Other Literature 266
Outlook 267
Acknowledgments 268
References 268
Contents
IX
7 Surface Spectroscopy of Nanomaterials for Detection of Diseases 271
Jean F Masson and Kristy S. McKeating
7.1 An Introduction to Plasmonics 271
7.2 An Overview of Plasmonic Techniques 272
7.2.1 Surface Plasmon Resonance (SPR) 272
7.2.2 Surface-Enhanced Raman Spectroscopy (SERS) 274
7.2.3 Metal-Enhanced Fluorescence (MEF) 276
7.2.4 Electrically Conductive Plasmonic Substrates 278
7.3 Plasmonic Spectroelectrochemistry 279
7.3.1 Electrochemical SPR and LSPR 279
7.3.2 Electrochemical SERS 282
7.3.3 Metal-Enhanced Fluorescence Electrochemistry 284
7.4 Plasmonic Biosensing for the Detection of Diseases 285
7.5 Outlook and Perspectives 287
References 288
8 Raman Spectroscopy at Nanocavity-Patterned Electrodes 295
Philip N. Bartlett
8.1 Introduction 295
8.2 Fabrication Methods 295
8.2.1 Top Down 295
8.2.2 Bottom-Up or Self-Organizing Approaches 299
8.2.3 Metal Evaporation 301
8.2.4 Electrodeposition 304
8.3 Plasmonics 307
8.3.1 Plasmonics of Nanohole Arrays 310
8.3.2 Sphere Segment Void (SSV) Plasmonics 310
8.4 Raman Spectroscopy 314
8.5 Surface-Enhanced Raman Spectroscopy 316
8.6 SERS on Nanohole Arrays 318
8.7 SERS at Sphere Segment Void (SSV) Surfaces 319
8.8 Some Applications in Electrochemical SERS 324
8.9 Other Surface-Enhanced Phenomena 324
8.10 Conclusions 326
Acknowledgment 327
References 327
9 Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy (SHINERS)
of Electrode Surfaces 339
Jian F. Lb Rajapandiyan Panneerselvam, and Zhong Q. Tian
9.1 Introduction 339
9.2 Advantages of Isolated Mode over Contact Mode 342
9.3 3D-FDTD Simulations 343
9.4 Synthesis of SHINs 345
9.5 Characterization of SHINs 348
X
Contents
9.6 Applications of SHINERS in Electrochemistry 350
9.6.1 SHINERS Study of Pyridine Adsorption on Au(hkl) and Pt(M/)
Single-Crystal Electrodes 351
9.6.2 SHINERS for Probing the Benzotriazole Film Formation on Cu(100),
Cu(lll), and Cu(Poly) Electrodes 353
9.6.3 SHINERS Study of Ionic Liquids at Single-Crystal Electrode
Surfaces 354
9.6.4 In Situ Investigation of Electrooxidation Processes at Gold
Single-Crystal Surfaces 357
9.6.5 Quantitative Analysis of Temporal Changes in the Passive Layer at a
Gold Electrode Surface 359
9.7 Summary and Outlook 361
Acknowledgments 362
References 362
10 Plasmonics-Based Electrochemical Current and Impedance
Imaging 373
Xiaonan Shan, Yixian Wang, and Nongjian Tao
10.1 Introduction 373
10.2 Principle of Plasmonics-Based Electrochemical Current Microscopy
(PECM) 374
10.2.1 Electrochemical Reactions 374
10.2.2 Relationship between Current and SPR Signals 375
10.3 Principle of Plasmonics-Based Electrochemical Impedance
Microscopy (PEIM) 377
10.4 Imaging Local Electrochemical Current by PECM 379
10.4.1 Experiment Setup 379
10.4.2 Mapping Local Redox Reactions with PECM 380
10.4.3 Detecting Trace Chemicals 381
10.4.4 Spatial Resolution and Current Detection Limit 383
10.4.5 Imaging Local Square-Wave Voltammetry 386
10.5 Imaging the Electrocatalytic Activity of Single Nanoparticles 389
10.5.1 Experiment 390
10.5.2 Imaging Electrocatalytic Current of Single Pt Nanoparticles 390
10.6 Mapping Local Quantum Capacitance of Graphene with PEIM 393
10.6.1 Experiments 394
10.6.2 Imaging Local Quantum Capacitance of Graphene 394
10.6.3 Quantum Capacitance 396
10.6.4 Local Quantum Capacitance and Charge Impurity Effect 398
10.7 Conclusions 398
References 399
Index 403
|
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id | DE-604.BV044273090 |
illustrated | Illustrated |
indexdate | 2024-12-20T17:58:31Z |
institution | BVB |
isbn | 9783527340927 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-029677649 |
oclc_num | 985531671 |
open_access_boolean | |
owner | DE-355 DE-BY-UBR DE-83 DE-703 |
owner_facet | DE-355 DE-BY-UBR DE-83 DE-703 |
physical | XIX, 409 Seiten Illustrationen, Diagramme |
publishDate | 2017 |
publishDateSearch | 2017 |
publishDateSort | 2017 |
publisher | Wiley-VCH Verlag GmbH & Co. KGaA |
record_format | marc |
series | Advances in electrochemical science and engineering |
series2 | Advances in electrochemical science and engineering |
spellingShingle | Nanopatterned and nanoparticle-modified electrodes Advances in electrochemical science and engineering Nanopartikel (DE-588)4333369-2 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd Elektrode (DE-588)4014247-4 gnd |
subject_GND | (DE-588)4333369-2 (DE-588)4342626-8 (DE-588)4014247-4 |
title | Nanopatterned and nanoparticle-modified electrodes |
title_auth | Nanopatterned and nanoparticle-modified electrodes |
title_exact_search | Nanopatterned and nanoparticle-modified electrodes |
title_full | Nanopatterned and nanoparticle-modified electrodes edited by Richard C. Alkire, Philip N. Bartlett, and Jacek Lipkowski |
title_fullStr | Nanopatterned and nanoparticle-modified electrodes edited by Richard C. Alkire, Philip N. Bartlett, and Jacek Lipkowski |
title_full_unstemmed | Nanopatterned and nanoparticle-modified electrodes edited by Richard C. Alkire, Philip N. Bartlett, and Jacek Lipkowski |
title_short | Nanopatterned and nanoparticle-modified electrodes |
title_sort | nanopatterned and nanoparticle modified electrodes |
topic | Nanopartikel (DE-588)4333369-2 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd Elektrode (DE-588)4014247-4 gnd |
topic_facet | Nanopartikel Nanostrukturiertes Material Elektrode |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029677649&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV004176465 |
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