Nanostructured polymer membranes: Volume 1 Processing and characterization
Gespeichert in:
| Weitere beteiligte Personen: | , |
|---|---|
| Format: | Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
Beverly, Massachusetts
Scrivener Publishing
[2017]
Hoboken, New Jersey Wiley [2017] |
| Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029402032&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029402032&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| Umfang: | xvii, 499 Seiten |
| ISBN: | 9781118831731 |
Internformat
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| 245 | 1 | 0 | |a Nanostructured polymer membranes |n Volume 1 |p Processing and characterization |c edited by Visakh P.M. and Olga Nazarenko |
| 264 | 1 | |a Beverly, Massachusetts |b Scrivener Publishing |c [2017] | |
| 264 | 1 | |a Hoboken, New Jersey |b Wiley |c [2017] | |
| 300 | |a xvii, 499 Seiten | ||
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| 700 | 1 | |a Nazarenko, Olga |4 edt | |
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Datensatz im Suchindex
| _version_ | 1819369292659949568 |
|---|---|
| adam_text | Contents
Preface xv
1 Processing and Characterizations: State-of-the-Art
and New Challenges 1
Visakh. P. M.
1.1 Membrane: Technology and Chemistry 1
1.2 Characterization of Membranes 3
1.3 Ceramic and Inorganic Polymer Membranes:
Preparation, Characterization and Applications 4
1.4 Supramolecular Membranes: Synthesis
and Characterizations 5
1.5 Organic Membranes and Polymers to Remove Pollutants 7
1.6 Membranes for C02 Separation 8
1.7 Polymer Nanomembranes 9
1.8 Liquid Membranes 11
1.9 Recent Progress in Separation Technology Based on
Ionic Liquid Membranes 12
1.10 Membrane Distillation 13
1.11 Alginate-based Films and Membranes: Preparation,
Characterization and Applications 14
References 15
2 Membrane Technology and Chemistry 27
Manuel Patencia, Alexander Córdoba and Myleidi Vera
2.1 Introduction 27
2.2 Membrane Technology: Fundamental Concepts 28
2.2.1 Basic Parameters 31
2.3 Separation Mechanisms 33
2.3.1 Pressure-driven Membrane Methods 34
2.3.2 Liquid Membranes 40
2.3.3 Other Methods 41
v
Vi CONTKNTS
2.4 Chemical Nature of Membrane 41
2.5 Surface Treatment of Membranes 42
2.5.1 Chemical Methods for Membrane Modification 42
2.5.1.1 ChemiealTreatment 42
2.5.1.2 Grafting 43
2.5.1.3 Chemical Initiation Technique 44
2.5.1.4 Photochemical and Radiation Initiation
Techniques 44
2.5.1.5 Plasma Initiation Technique 45
2.5.1.6 Enzymatic Initiation Technique 45
2.5.2 Physical Methods for Membrane Modification 46
2.5.2.1 Coating 46
2.5.2.2 Blending 46
2.5.2.3 Composite 46
2.5.2.4 Combined Methods 47
2.5.3 Current Research about Membrane Modification 47
2.6 Conclusions 48
References 48
3 Characterization of Membranes 55
Derya Y. Koseoglu-lmer, Ismail Koyuttcu,
Reyhan Sengur-Tasdemir, Serkan Guclu,
Recep Kaya, Mehmet Emin Pasaoglu and Turker Turken
3.1 Introduction 56
3.2 Physical Methods for Characterizing Pore Size
of Membrane 56
3.2.1 Microscopy 57
3.2.2 Bubble Pressure and Gas Transport 59
3.2.3 Porosimetry 61
3.2.4 Liquid-vapor Equilibrium 63
3.2.5 Liquid-solid Equilibrium (Thermoporometry) 64
3.2.6 Gas-liquid Equilibrium (Permporometry) 65
3.2.6.1 Capillary Condensation 65
3.3 Membrane Chemical Structure 67
3.3.1 Fourier Transform Infrared Spectroscopy (FTIR) 67
3.3.2 Raman Spectroscopy 68
3.3.3 Energy-dispersive X-ray Spectroscopy (EDS) 70
3.3.3.1 Basics of EDS 70
3.3.3.2 Applications of EDS in Membrane
Characterization 70
3.3.4 X-ray Photoelectron Spectroscopy (XPS) 71
Contents vii
3.3.5 Electron Spectroscopy 73
3.3.5.1 Auger Electron Spectroscopy (AES) 73
3.3.5.2 Electron Energy Loss
Spectroscopy (EELS) 74
3.3.6 Atomic Force Microscopy (AFM) 74
3.3.6.1 Basics of AFM 74
3.3.6.2 Applications of AFM in Membrane
Characterization 76
3.3.7 Secondary Ion Mass Spectrometry (SIMS) 78
3.3.8 Surface Hydrophilicity and Surface Energy 79
3.3.8.1 Determination of Hydropilic/
Hydrophobic Nature of Membranes 79
3.3.8.2 Contact Angle Measurement by
Drop Profile Analysis 80
3.3.8.3 Surface Energy 83
3.4 Conclusions 85
References 85
Ceramic and Inorganic Polymer Membranes:
Preparation, Characterization and Applications 89
Chiam-Wen Liew and S. Ramesh
4.1 Introduction 90
4.1.1 Overview of Polymer Electrolytes 90
4.1.2 Methods to Enhance Ionic Conductivity of
Polymer Electrolytes 90
4.1.3 Ionic Liquids 91
4.1.3.1 Advantages of Ionic Liquids 91
4.1.3.2 Applications of Ionic Liquids 92
4.1.4 Fillers 92
4.1.4.1 Types of Fillers 93
4.1.4.2 Advantages of Addition of Fillers 94
4.1.5 Applications of Nanocomposite Polymer
Electrolytes (NCPEs) 95
4.2 Recent Developments in Filler-doped
Polymer Electrolytes 95
4.2.1 A120, 95
4.2.2 Ti°2 98
4.2.3 Zr02 99
4.2.4 Si02 101
4.2.5 Supercapacitors 103
4.2.5.1 Types of Supercapacitors 103
viii Contents
4.2.5.2 Advantages of Supercapacitors 104
4.2.5.3 Applications of Supercapacitors 104
4.3 Methodology 105
4.3.1 Materials 105
4.3.2 Sample Preparation 105
4.3.3 Sample Characterization 106
4.3.3.1 Ambient Temperature-ionic
Conductivity and Temperature-
dependent Ionic Conductivity Studies 106
4.3.3.2 Differential Scanning
Calorimetry (DSC) 106
4.3.3.3 Linear Sweep Voltammetry (LSV) 107
4.3.4 Electrode Preparation 107
4.3.5 Electrical Double-layer Capacitors
(EDLCs) Fabrication 108
4.3.6 Electrical Double-layer Capacitors (EDLCs)
Characterization 108
4.3.6.1 Cyclic Voltammetry (CV) 108
4.3.6.2 Galvanostatic Charge-discharge
Analysis (GCD) 108
4.4 Results and Discussion 109
4.4.1 Ambient Temperature-ionic Conductivity
Studies 109
4.4.2 Temperature-dependent-ionic
Conductivity Studies 112
4.4.3 Differential Scanning Calorimetry (DSC) 114
4.4.4 Linear Sweep Voltammetry (LSV) 117
4.4.5 Cyclic Voltammetry (CV) 119
4.4.6 Galvanostatic Charge-discharge Analysis (GCD) 124
4.5 Conclusions 127
Acknowledgment 128
References 128
5 Supramolecular Membranes: Synthesis and Characterizations 137
Cher Hon Lau, Matthew Hill and Kristina Konstas
5.1 Overview 138
5.2 Supramolecular Materials 138
5.2.1 Porous Materials 139
5.2.1.1 Metal-organic Frameworks 140
5.2.1.2 Zeolitic Imidazole Frameworks (ZIFs) 146
Contents іх
5.2.2 Porous Organic Materials (POMs) 148
5.2.2.1 Covalent Organic Frameworks (COFs) 149
5.2.3 Cages 153
5.2.4 PAFs 154
5.3 Supramolecular Membranes 157
5.3.1 Concepts of Supramolecular Chemistry in
Polymeric Membranes 157
5.3.1.1 Poly(dialkylacetylenes) 158
5.3.1.2 Polymers with Intrinsic
Microporosity (PIMs) 163
5.3.2 Supramolecular Concepts in Nanocomposite
Membranes 165
5.3.2.1 Metal Organic Frameworks (MOFs)
in Polymer Membranes 166
5.3.2.2 Porous Aromatic Frameworks (PAFs)
in Super-Glassy Polymers 168
5.4 Membrane Fabrication Using Supramolecular Chemistry 170
5.4.1 Molecular Recognition - C02 Affinity 172
5.4.2 Host-guest Chemistry 175
5.4.3 Self-assembled Membranes 178
5.4.4 Self-assembled Polymers as Membranes 179
5.4.5 Self-assembled Molecules and Nanoparticles
as Membran es 181
5.5 Conclusions 184
References 186
6 Organic Membranes and Polymers for the
Removal of Pollutants 203
Bernabé L. Rivas, Julio Sánchez and Manuel Patencia
6.1 Membranes: Fundamental Aspects 204
6.1.1 Membrane Transport Theory 205
6.1.2 Pressure-driven Membrane Methods 208
6.1.3 Hybrid Methods Applied for Removal
of Pollutants 209
6.1.3.1 Membrane Bioreactor (MBR) 209
6.1.3.2 Electro-ultrafiltration 210
6.1.3.3 Ultrafiltration Coupled to Ultrasound 210
6.1.3.4 Flotation Coupled with Microfiltration 210
6.1.3.5 Liquid-phase Polymer-based
Retention (LPR) 211
x Contents
6.1.3.6 Surfactant Liquid Membrane
Coupled with Liquid-phase
Polymer-based Retention
6.1.4 Fouling
6.2 Liquid-phase Polymer-based Retention (LPR)
6.2.1 Theory and Fundamental Aspects
6.3 Applications for Removal of Specific Pollutants
6.3.1 Removal of Inorganic Species by LPR
6.3.1.1 Heavy Metals
6.3.1.2 Inorganic Anions
6.4 Future Perspectives
6.5 Conclusions
Acknowledgments
References
7 Membranes for C02 Separation
AbedalkhaderAlkhouzaam, Khraisheh,
Mert Atilhan, Shaheett A. Al-Muhtaseb and
Syed Javaid Zaidi
7.1 Introduction
7.2 Fundamentals of Membrane Gas Separation
7.2.1 Membrane Gas Permeation Mechanisms
7.2.2 Robeson’s Upper Bound
7.3 Polymeric Membranes for C02 Separation
7.3.1 Polyimides
7.3.2 Polysulfones
7.3.3 Polymer Blends
7.4 Mixed Matrix Membranes
7.5 Supported Ionic Liquid Membranes (SILMs) for C02
Separation
7.5.1 SILM Permeation Properties for C02/N2
and C02/CH4 Separation
7.5.2 SILMs Stability in Gas Separation
7.6 Conclusion
7.7 Overall Comparison and Future Outlook
Abbreviations
References
211
211
212
213
216
217
218
222
228
228
228
228
237
238
239
240
242
245
246
251
253
258
263
268
276
278
279
282
285
Contents xi
8 Polymer Nanomembranes 293
Giuseppe Firpo and Ugo Valbusa
8.1 Introduction 293
8.2 Materials 294
8.2.1 Rubber Polymers 294
8.2.2 Glassy Polymers 295
8.2.3 Mixed Matrix and Nanocomposite 297
8.3 Nanomembrane Fabrication 298
8.3.1 Spin Coating 298
8.3.2 Layer-by-Layer Assembly 300
8.3.3 Chemical Vapor Deposition 301
8.3.4 Other Techniques 302
8.3.5 Surface Treatments 303
8.4 Characterization 304
8.4.1 Gas Permeability and Selectivity 304
8.4.2 Mechanical Properties 307
8.4.3 Long-term Stability 309
8.5 Applications 310
8.5.1 Gas Purification 310
8.5.2 Water Desalination 312
8.5.3 Biomedical Devices 313
8.5.4 Sensors 315
References 316
9 Liquid Membranes 329
Jiangnan Shen, Lijing Zhu, Lixin Xue and Congjie Gao
9.1 Introduction 329
9.2 Most Recent Developments 330
9.3 Liquid Membranes Based Separation Processes 330
9.3.1 Emulsionized Liquid Membranes 330
9.3.2 Immobilized Liquid Membranes 345
9.3.3 Applications of Immobilized Liquid Membranes 348
9.3.4 Molten Salt Membranes 349
9.3.5 Hollow Fiber Liquid Membranes 349
9.3.6 Bulk Hybrid Liquid Membranes 354
9.3.6.1 Instruction 354
9.3.6.2 Theoretical Aspects of Bulk Hybrid
Liquid Membranes 354
9.3.6.3 Pertraction in a Multi-membrane
Hybrid System 356
xii Contents
9.3.6.4 Applications 358
9.3.6.5 Summary 359
9.3.7 Bulk Aqueous Hybrid Liquid Membranes 360
9.3.7.1 Introduction 360
9.3.7.2 Theoretical Aspects of Bulk Aqueous
Hybrid Liquid Membranes 361
9.3.7.3 Applications 363
9.3.7.4 Summary 364
9.3.8 Liquid Membranes in Gas Separation 364
9.3.8.1 Introduction 364
9.3.8.2 Separation Mechanism 365
9.3.8.3 Materials for LM 367
9.3.9 Common Gas Separation Applications 375
9.3.9.1 Carbon Dioxide Separation from
Various Gas Streams 375
9.3.9.2 Sulfur Dioxide Separation from
Various Gas Streams 376
9.3.9.3 Hydrogen Separation from
Various Gas Streams 377
9.3.9.4 Olefin Separation 377
9.3.9.5 Conclusion and Outlook 378
9.4 Conclusion 379
References 379
10 Recent Progress in Separation Technology Based on
Ionic Liquid Membranes 391
M.J. Salar-García, V.M. Ortiz-Martinez,
A. Pérez de los Ríos and F.J. Hernández-Fernández
10.1 Introduction 392
10.2 Ionic Liquid Properties 393
10.3 Bulk Ionic Liquid Membranes 395
10.4 Emulsified Ionic Liquid Membranes 397
10.5 Immobilized Ionic Liquid Membranes 400
10.5.1 Supported Ionic Liquid Membranes 401
10.5.2 Polymer Ionic Liquid Inclusion Membranes 404
10.5.3 Polymeric Ionic Liquid Membranes 406
10.5.4 Membranes Based on Gelation of Ionic Liquids 407
10.5.5 Non-dispersive Solvent Extraction (NDSX)
and Pseudo-emulsion Hollow Fiber Strip
Dispersion (PEHFSD) Based on Ionic Liquids 408
Contents xiii
10.6 Green Aspect of Ionic Liquids 410
10.7 Conclusions 411
Acknowledgments 411
References 412
11 Membrane Distillation 419
Mohammadali Baghbanzadeh, Christopher Q. Lan,
Dipak Rana and Takeshi Matsuura
11.1 Introduction 419
11.2 Applications of Membrane Distillation Technology 420
11.3 Different Kinds of Membrane Distillation
Configurations 422
11.3.1 Direct Contact Membrane
Distillation (DCMD) 422
11.3.2 Air Gap Membrane Distillation (AGMD) 423
11.3.2.1 Memstill and Aquastill 423
11.3.3 Permeate Gap Membrane Distillation (PGMD) 425
11.3.4 Sweep Gas Membrane Distillation (SGMD) 425
11.3.5 Vacuum Membrane Distillation (VMD) 426
11.3.5.1 Vacuum Gap Membrane
Distillation (VGMD) 427
11.3.5.2 Memsys 428
11.3.5.3 Differences between VMD and
Pervaporation (PV) 429
11.4 Distillation Membranes 432
11.4.1 MD Modules 432
11.4.1.1 Plate and Frame 432
11.4.1.2 Hollow Fiber 432
11.4.1.3 Tubular 433
11.4.1.4 Spiral Wound 433
11.4.2 Applicable Membranes for MD 434
11.4.2.1 Nanocomposite Membranes 434
11.4.3 Membrane Characteristics in MD 435
11.4.3.1 Liquid Entry Pressure
(Wetting Pressure) 435
11.4.3.2 Membrane Thickness 436
11.4.3.3 Porosity and Tortuosity 436
11.4.3.4 Mean Pore Size and Pore Size
Distribution 437
11.4.3.5 Thermal Conductivity 437
11.4.3.6 Membrane Fabrication 438
xiv Contents
11.5 Transport Phenomena in MD 439
11.5.1 Mass Transfer in MD 439
11.5.2 Heat Transfer in MD 443
11.5.2.1 Thermal Efficiency and Heat Loss 445
11.5.3 Temperature and Concentration Polarization 447
11.5.4 Fouling 448
11.5.5 Operating Parameters 449
11.5.5.1 Feed Temperature 449
11.5.5.2 Permeate Temperature 449
11.5.5.3 Feed Concentration 449
11.5.5.4 Feed Flow Rate 449
11.5.5.5 Air Gap Thickness 449
11.5.5.6 Membrane Properties 450
11.6 Conclusion 450
References 450
12 Alginate-based Films and Membranes: Preparation,
Characterization and Applications 457
Jiwei Li and Jinmei He
12.1 Introduction 457
12.2 Recent Development 459
12.2.1 Cross-linking 460
12.2.2 Plasticizing 462
12.2.3 Blending 463
12.2.4 Compositing 465
12.2.5 Drying 467
12.3 Applications 468
12.3.1 Pharmaceutical and Medical Applications 468
12.3.2 Packaging Applications 470
12.3.3 Environmental Applications 472
12.4 Conclusion 473
References 474
Index
491
The book is a “one-stop shop” for state-of-the-art investigations on membrane
technology and chemistry and the new challenges facing the field.
Polymer membranes are widely used in many applications in industry and many
different types of polymer-based membranes are available. It is therefore very
desirable to collect the information in one volume so it is accessible and shared
with all interested researchers. Thus, the book brings together the knowledge of
scientists from industry and academia in 11 chapters and presents research on the
processing and characterization of polymer membranes.
Topics include:
• Characterization of membranes
• Current techniques for the processing and characterization of ceramic and
inorganic polymer membranes
• Supramolecular membranes
• Organic membranes and polymers for removal of pollutants
• Membranes for C02 separation
• Polymer nano-membranes
• Liquid membranes
• Separation technology based on ionic liquid membranes
• Membrane distillation
• Alginate-based membranes and films.
Audience
The book is aimed at engineers, scientists and researchers in chemistry, biology,
biomedicine, materials and polymer science, textiles, and electronics who are
involved with membranes and materials. Technologists and product managers
from industry, including those responsible for research and development, building
prototypes and commercial devices, will find this book to be especially valuable.
Visakh P.M. is working as post doc. researcher at Tomsk Polytechnic University,
Russia. He obtained his PhD, MPhil and MSc degrees from the School of
Chemical Sciences, Mahatma Gandhi University, Kottayam, Kerala, India. He has
edited 15 books for a variety of international publishers and has been a visiting
researcher in many countries since 2011. His research interests include polymer
nanocomposites, bio-nanocomposites and rubber based nanocomposites, fire
retardant polymers, liquid crystalline polymers and silicon sensors.
Olga Nazarenko obtained her PhD in Technical Sciences from Tomsk Polytechnic
University, Russia where she is now a Professor in the Ecology and Basic Safety
Department. In 2007 she obtained her DSc. in Processes and Apparatus of
Chemical Technology. She has 170 publications, 3 books and 8 textbooks and 7
patents to her credit. _______ _____ __________________________________
C over design hr Russell Richardson
Front cover image supplied hr Bigstock.com
Wiley Ó/? ®
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WvWV.so fvcnoîpublishinq.com
ISBN 978-1-118-83173-1
Afso available
as an e book
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| id | DE-604.BV043993890 |
| illustrated | Not Illustrated |
| indexdate | 2024-12-20T17:50:43Z |
| institution | BVB |
| isbn | 9781118831731 |
| language | English |
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| record_format | marc |
| spellingShingle | Nanostructured polymer membranes |
| title | Nanostructured polymer membranes |
| title_auth | Nanostructured polymer membranes |
| title_exact_search | Nanostructured polymer membranes |
| title_full | Nanostructured polymer membranes Volume 1 Processing and characterization edited by Visakh P.M. and Olga Nazarenko |
| title_fullStr | Nanostructured polymer membranes Volume 1 Processing and characterization edited by Visakh P.M. and Olga Nazarenko |
| title_full_unstemmed | Nanostructured polymer membranes Volume 1 Processing and characterization edited by Visakh P.M. and Olga Nazarenko |
| title_short | Nanostructured polymer membranes |
| title_sort | nanostructured polymer membranes processing and characterization |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029402032&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029402032&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV043993874 |
| work_keys_str_mv | AT pmvisakh nanostructuredpolymermembranesvolume1 AT nazarenkoolga nanostructuredpolymermembranesvolume1 |