Fatigue and tribological properties of plastics and elastomers:
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Main Author: | |
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Format: | Book |
Language: | English |
Published: |
Amsterdam
William Andrew is an imprint of Elsevier
[2016]
|
Edition: | Third edition |
Series: | Plastics design library
|
Subjects: | |
Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029128320&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029128320&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
Physical Description: | xiii, 355 Seiten Illustrationen |
ISBN: | 0323442013 9780323442015 |
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adam_text | Contents
FI
Foreword..............................................................................................xi
Acknowledgments.......................................................................................xiii
1 Introduction to Fatigue of Plastics and Elastomers....................................................1
1.1 Types of Stress.................................................................................1
1.1.1 Tensile and Compressive Stress.............................................................1
1.1.2 Shear Stress...............................................................................1
1.1.3 Torsional Stress...........................................................................2
1.1.4 Flexural or Bending Stress.................................................................2
1.1.5 Floop Stress...............................................................................3
1.2 Fatigue Testing..................................................................................4
1.2.1 Fatigue Coupons............................................................................4
1.2.2 Tensile Eccentric Fatigue Machine..........................................................5
1.2.3 Flexural Eccentric Fatigue Machine.........................................................7
1.2.4 Cantilevered Beam Eccentric Flexural Fatigue Machine.......................................7
1.2.5 Servohydraulic, Electrohydraulic, or Pulsator Fatigue Testing Machines.....................8
1.2.6 Ultrasonic Fatigue.........................................................................9
1.2.7 Fatigue-Testing Method....................................................................10
1.2.8 Flex Life Machines........................................................................10
1.2.9 Fatigue and Fracture Standards............................................................12
1.3 Understanding Fatigue-Testing Data..............................................................16
1.3.1 Monotonic Stress-Strain Behavior..........................................................16
1.3.2 Cyclic Stress-Strain Behavior.............................................................17
1.3.3 Strain-Life Behavior......................................................................18
1.3.4 Stress-Life Behavior......................................................................20
1.4 Fatigue Process.................................................................................21
1.4.1 Crack Initiation..........................................................................21
1.4.2 Crack Growth or Propagation...............................................................21
1.4.3 Failure...................................................................................22
1.5 Factors That Affect Fatigue Life................................................................23
1.6 Design Against Fatigue..........................................................................24
1.7 Summary.........................................................................................25
References..........................................................................................25
2 Introduction to the Tribology of Plastics and Elastomers.............................................27
2.1 Friction........................................................................................27
2.2 Lubrication.....................................................................................28
2.3 Wear and Erosion................................................................................29
2.3.1 Classification of Wear....................................................................29
2.3.2 Characterizing Wear.......................................................................31
2.3.3 Environmental Conditions and Wear.........................................................34
2.4 Tribology Testing...............................................................................34
2.4.1 Testing for Friction......................................................................34
2.4.2 Wear and Abrasion Tests...................................................................35
v
VI
Contents
2.4.3 Erosion Tests..........................................................................38
2.4.4 Hardness Testing.......................................................................39
2.4.5 Standard Tribology Tests...............................................................41
2.5 Wear-Resistant Additives.....................................................................41
2.6 Summary......................................................................................43
References.........................................................................................43
3 Introduction to Plastics and Polymers..............................................................45
3.1 Polymerization...............................................................................45
3.1.1 Addition Polymerization................................................................45
3.1.2 Condensation Polymerization............................................................45
3.2 Copolymers...................................................................................46
3.3 Linear, Branched, and Cross-Linked Polymers..................................................47
3.4 Polarity.....................................................................................47
3.5 Unsaturation.................................................................................48
3.6 Steric Hindrance.............................................................................49
3.7 Isomers......................................................................................49
3.7.1 Structural Isomers.....................................................................49
3.7.2 Geometric Isomers......................................................................50
3.7.3 Stereoisomers—Syndiotactic, Isotactic, Atactic.........................................50
3.8 Intermolecular and Intramolecular Attractions in Polymers....................................51
3.8.1 Hydrogen Bonding.......................................................................51
3.8.2 van der Waals Forces...................................................................52
3.8.3 Chain Entanglement.....................................................................52
3.9 General Classifications......................................................................52
3.9.1 Molecular Weight.......................................................................52
3.9.2 Thermosets Versus Thermoplastics.......................................................53
3.9.3 Crystalline Versus Amorphous...........................................................54
3.10 Elastomers..................................................................................55
3.11 Plastic Compositions........................................................................55
3.11.1 Fillers, Reinforcement, Composites...................................................56
3.11.2 Combustion Modifiers, Fire, Flame Retardants,
and Smoke Suppressants...............................................................57
3.11.3 Release Agents and Antiblocking Agents..............................................58
3.11.4 Lubricants and Slip Agents, Tribology Additives.....................................58
3.11.5 Catalysts...........................................................................58
3.11.6 Impact Modifiers and Tougheners.....................................................58
3.11.7 UV Stabilizers......................................................................59
3.11.8 Optical Brighteners.................................................................60
3.11.9 Antistatic Agents...................................................................60
3.11.10 Plasticizers.........................................................................61
3.11.11 Pigments, Extenders, Dyes, Mica......................................................61
3.11.12 Coupling Agents......................................................................62
3.11.13 Thermal Stabilizers..................................................................62
3.12 Polymer Nomenclature........................................................................62
References........................................................................................63
Contents vii
4 Styrenic Plastics.................................................................................65
4.1 Polystyrene...................................................................................65
4.1.1 Fatigue Data...........................................................................65
4.2 Acrylonitrile-Styrene-Aery late..............................................................65
4.2.1 Fatigue Data...........................................................................67
4.3 Styrene Acrylonitrile........................................................................68
4.3.1 Fatigue Data...........................................................................68
4.4 Acrylonitrile-Butadiene-Styrene..............................................................68
4.4.1 Grades Available.......................................................................72
4.4.2 Fatigue Data...........................................................................72
4.5 Styrenic Blends..............................................................................76
4.5.1 Fatigue Data...........................................................................77
4.5.2 Tribology Data.........................................................................78
4.6 Other Styrenic Plastics......................................................................78
4.6.1 Methacrylate Acrylonitrile Butadiene Styrene Copolymer.................................78
4.6.2 Styrene Maleic Anhydride...............................................................81
4.6.3 Styrenic Block Copolymers..............................................................84
References........................................................................................84
5 Polyether Plastics................................................................................87
5.1 Acetals—Polyoxymethylene Homopolymer..........................................................87
5.1.1 Fatigue Data............................................................................87
5.1.2 Tribology Data.........................................................................87
5.2 Polyoxymethylene Copolymer (POM-Co or Acetal Copolymer)......................................87
5.2.1 Fatigue Data...........................................................................95
5.2.2 Tribology Data.........................................................................95
5.3 Modified Polyphenylene Ether/Polyphenylene Oxide.............................................95
5.3.1 Fatigue Data..........................................................................111
References.......................................................................................123
6 Polyester Plastics...............................................................................125
6.1 Polycarbonate................................................................................125
6.1.1 Fatigue Data..........................................................................126
6.1.2 Tribology Data........................................................................135
6.2 Polybutylene Terephthalate..................................................................135
6.2.1 Fatigue Data..........................................................................142
6.2.2 Tribology Data........................................................................149
6.3 Polyethylene Terephthalate..................................................................149
6.3.1 Fatigue Data...........................................................................152
6.3.2 Tribology Data........................................................................152
6.4 Liquid Crystalline Polymers.................................................................156
6.4.1 Fatigue Data..........................................................................152
6.4.2 Tribology Data........................................................................157
6.5 Polycyclohexylene-Dimethylene Terephthalate.................................................159
6.5.1 Fatigue Data..........................................................................159
Contents
6.6 Polyphthalate Carbonate...................................................................159
6.6.1 Fatigue Data.........................................................................161
6.7 Polyester Blends and Alloys...............................................................161
6.7.1 Fatigue Data.........................................................................161
References.....................................................................................169
7 Polyimide Plastics.............................................................................171
7.1 Polyetherimide.............................................................................171
7.1.1 Fatigue Data.........................................................................171
7.1.2 Tribology Data.......................................................................171
7.2 Polyamide-Imide...........................................................................171
7.2.1 Fatigue Data.........................................................................182
7.2.2 Tribology Data.......................................................................182
7.3 Polyimide.................................................................................182
7.3.1 Fatigue Data.........................................................................186
7.3.2 Tribology Data.......................................................................186
7.4 Thermoplastic Polyimide...................................................................186
7.4.1 Fatigue Data.........................................................................187
7.4.2 Tribology Data.......................................................................193
7.5 Imide Polymer Blends......................................................................193
References.....................................................................................197
8 Polyamide Plastics (Nylons)....................................................................199
8.1 Nylon 6 (PA 6).............................................................................200
8.1.1 Fatigue Data.........................................................................201
8.1.2 Tribology Data.......................................................................201
8.2 Nylon 11 (PA 11)..........................................................................201
8.2.1 Tribology Data.......................................................................203
8.3 Nylon 12 (PA 12)..........................................................................204
8.3.1 Fatigue Data.........................................................................208
8.3.2 Tribology Data.......................................................................208
8.4 Nylon 46 (PA 46)..........................................................................208
8.4.1 Fatigue Data.........................................................................210
8.4.2 Tribology Data.......................................................................210
8.5 Nylon 66 (PA 66)..........................................................................210
8.5.1 Fatigue Data.........................................................................214
8.5.2 Tribology Data.......................................................................214
8.6 Nylon 610 (PA 610)........................................................................215
8.6.1 Fatigue Data.........................................................................216
8.6.2 Tribology Data.......................................................................216
8.7 Nylon 612 (PA 612)........................................................................216
8.7.1 Fatigue Data.........................................................................218
8.7.2 Tribology Data.......................................................................218
8.8 Nylon 666 or 66/6 (PA 666)................................................................218
8.8.1 Fatigue Data.........................................................................219
8.9 Amorphous Nylon...........................................................................220
8.9.1 Fatigue Data.........................................................................223
Contents
ix
8.10 Polyphthalamide/High-Performance Polyamide.................................................223
8.10.1 Fatigue Data.......................................................................224
8.10.2 Tribology Data.....................................................................225
8.11 Poly ary lamide............................................................................225
8.11.1 Fatigue Data.......................................................................233
8.11.2 Tribology Data.....................................................................233
References.......................................................................................260
9 Polyolefins and Acrylics.........................................................................261
9.1 Polyethylene................................................................................261
9.1.1 Fatigue Data..........................................................................262
9.1.2 Tribology Data........................................................................262
9.2 Cross-Linked Polyethylene...................................................................262
9.3 Polypropylene...............................................................................263
9.3.1 Fatigue Data...........................................................................266
9.4 Ultrahigh-Molecular-Weight Polyethylene.....................................................266
9.4.1 Fatigue Data...........................................................................267
9.4.2 Tribology Data........................................................................268
9.5 Rigid Polyvinyl Chloride....................................................................268
9.5.1 Fatigue Data..........................................................................270
9.6 Polyacrylics................................................................................270
9.6.1 Fatigue Data..........................................................................271
References.......................................................................................277
10 Thermoplastic Elastomers........................................................................279
10.1 Thermoplastic Polyurethane Elastomers.....................................................279
10.1.1 Tribology Data.....................................................................280
10.2 Thermoplastic Copolyester Elastomers......................................................280
10.2.1 Fatigue Data.......................................................................284
10.2.2 Tribology Data.....................................................................284
10.3 Thermoplastic Polyether Block Amide Elastomers............................................284
10.3.1 Fatigue Data.......................................................................286
10.3.2 Tribology Data.....................................................................286
10.4 Olefinic Thermoplastic Elastomer..........................................................287
10.4.1 Tribology Data.....................................................................287
10.5 Other Elastomers......................................................................... 289
10.5.1 Styrenic Block Copolymer Thermoplastic Elastomers..................................289
10.5.2 Elastomeric Alloy-Thermoplastic Vulcanizate........................................289
References......................................................................................289
11 Fluoropolymers...................................................................................
11.1 Poly tetrafluoroethy lene.................................................................291
11.1.1 Fatigue Data.......................................................................293
11.1.2 Tribology Data.....................................................................293
11.2 Polyethylene Chlorotrifluoroethylene......................................................293
11.2.1 Tribology Data.....................................................................294
x Contents
11.3 Polyethylene Tetrafluoroethylene...........................................................296
11.3.1 Fatigue Data........................................................................299
11.3.2 Tribology Data......................................................................299
11.4 Fluorinated Ethylene Propylene.............................................................299
11.4.1 Fatigue Data........................................................................300
11.4.2 Tribology Data......................................................................300
11.5 Perfluoroalkoxy............................................................................300
11.5.1 Fatigue Data........................................................................302
11.5.2 Tribology Data......................................................................303
11.6 Polychlorotrifluoroethylene................................................................303
11.6.1 Fatigue Data........................................................................310
11.7 Polyvinylidene Fluoride....................................................................310
11.7.1 Fatigue Data.......................................................................310
11.7.2 Tribology Data......................................................................310
11.8 Polyvinyl Fluoride.........................................................................311
11.8.1 Fatigue Data........................................................................313
References.......................................................................................314
12 High-Temperature Polymers........................................................................317
12.1 Polyaryletherketones.......................................................................317
12.1.1 Polyetheretherketone................................................................317
12.1.2 Polyaryletherketones (PAEK, PEK, PEKEKK, Blends)....................................317
12.2 Polyethersulfone...........................................................................317
12.2.1 Fatigue Data.......................................................................320
12.2.2 Tribology Data......................................................................320
12.3 Polyphenylene Sulfide......................................................................320
12.3.1 Fatigue Data........................................................................330
12.3.2 Tribology Data......................................................................330
12.4 Polysulfone................................................................................330
12.4.1 Fatigue Data........................................................................333
12.4.2 Tribology Data......................................................................333
12.5 Polybenzimidazole..........................................................................336
12.5.1 Tribology Data......................................................................342
References.......................................................................................344
Subject Index........................................................................................345
A Volume in the Plastics Design Library Series
Fatigue and Tribological Properties of Plastics and Elastomers
Third Edition
Laurence W. McKeen
The definitive databook for engineers and scientists involved in the plastics industry and product design with plastics, covering Fatigue and
Tribology.
Part of a series of data-rich handbooks within the Plastics Design Library, Fatigue and Tribological Properties of Plastics and Elastomers provides
a comprehensive collection of graphical multipoint data and tabular data covering the fatigue and tribological performance of plastics.
The handbook is structured by grouping together plastics of similar polymer types into 12 chapters. Each of these chapters is split into two
sections: Fatigue Properties and Tribological Properties, and together they provide a compendium of several hundred graphs and charts, supplying
the core data needed by engineers and scientists on a day-to-day basis.
The data for this third edition has been updated to cover up to 5 years since the previous edition was published, and also includes an entirely
new chapter covering sustainable and biodegradable polymers. The book also includes an extensive introductory section covering fatigue, what
it is and how it is measured; the fundamentals of tribology; polymer chemistry and plastics composition. These chapters also provide readers
with a full understanding of the data section, and how to put it to use as a hard-working information tool.
ABOUT THE AUTHOR
Larry McKeen has a PhD in Chemistry from the University of Wisconsin and has worked for DuPont Fluoroproducts since 1978-2015. As a Senior
Research Associate Chemist he was responsible for new product development including application technology and product optimization for
particular end-uses, and product testing. He retired from DuPont at the end of 2014 and is currently a consultant.
RELATED TITLES
Permeability Properties of Plastics and Elastomers, 3e, McKeen, September 2011,9781437734690
The Effect of Temperature and Other Factors on Plastics and Elastomers, 3e, McKeen, April 2014,9780323310161
Thermoplastic Material Selection, Larson, May 2015,9780323312998
ISBN 978-0-323-44201 -5
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|
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author | McKeen, Laurence W. |
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series2 | Plastics design library |
spellingShingle | McKeen, Laurence W. Fatigue and tribological properties of plastics and elastomers Plastics / Fatigue Plastics / Fatigue fast Kunststoff (DE-588)4033676-1 gnd Tribologie (DE-588)4060847-5 gnd Materialermüdung (DE-588)4074631-8 gnd |
subject_GND | (DE-588)4033676-1 (DE-588)4060847-5 (DE-588)4074631-8 |
title | Fatigue and tribological properties of plastics and elastomers |
title_auth | Fatigue and tribological properties of plastics and elastomers |
title_exact_search | Fatigue and tribological properties of plastics and elastomers |
title_full | Fatigue and tribological properties of plastics and elastomers Laurence W. McKeen |
title_fullStr | Fatigue and tribological properties of plastics and elastomers Laurence W. McKeen |
title_full_unstemmed | Fatigue and tribological properties of plastics and elastomers Laurence W. McKeen |
title_short | Fatigue and tribological properties of plastics and elastomers |
title_sort | fatigue and tribological properties of plastics and elastomers |
topic | Plastics / Fatigue Plastics / Fatigue fast Kunststoff (DE-588)4033676-1 gnd Tribologie (DE-588)4060847-5 gnd Materialermüdung (DE-588)4074631-8 gnd |
topic_facet | Plastics / Fatigue Kunststoff Tribologie Materialermüdung |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029128320&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029128320&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT mckeenlaurencew fatigueandtribologicalpropertiesofplasticsandelastomers |