Chemical fate and transport in the environment:
Gespeichert in:
Beteiligte Personen: | , |
---|---|
Format: | Buch |
Sprache: | Englisch |
Veröffentlicht: |
Amsterdam [u.a.]
Acad. Press
2015
|
Ausgabe: | 3. ed. |
Schlagwörter: | |
Links: | https://www.gbv.de/dms/tib-ub-hannover/810745240.pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027650505&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
Umfang: | X, 476 S. Ill., graph. Darst., Kt. |
ISBN: | 9780123982568 |
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Datensatz im Suchindex
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adam_text | Titel: Chemical fate and transport in the environment
Autor: Hemond, Harold F
Jahr: 2015
Contents
Preface ix
1. Basic Concepts 1
1.1 Introduction 1
1.2 Chemical Concentration 3
1.3 Mass Balance and Units 6
1.3.1 Mass Balance and the Control Volume 6
1.3.2 Consistency of Units 10
1.4 Physical Transport of Chemicals 12
1.4-1 Quantification of Advective Transport 13
1.4.2 Quantification of Fickian Transport 15
1.5 Mass Balance in an Infinitely Small Control Volume:
The Advection-Dispersion-Reaction Equation 19
1.6 Basic Environmental Chemistry 20
1.6.1 Types of Chemicals and Chemical Bonds 21
1.6.2 Kinetics Versus Equilibrium 26
1.6.3 Gibbs Free Energy 27
1.6.4 Equilibrium 29
1.6.5 Electroneutrality 35
1.6.6 Activity 36
1.6.7 Kinetics of Chemical Reactions 38
1.7 Chemical Distribution Among Phases at Equilibrium 42
1.7.1 Solubility and Vapor Pressure 43
1.7.2 Henry s Law Constants 49
1.7.3 Chemical Partitioning to Solids 50
1.7.4 Equilibrium Partitioning Among Phases: Fugacity 55
1.8 Analytical Chemistry and Measurement Error 57
1.8.1 The Nature of Analytical Chemistry 57
1.8.2 Error in Measurements of Environmental Quantities 61
1.9 Conclusion 66
Exercises 66
References 72
2. Surface Waters 75
2.1 Introduction 75
2.1.1 Nature of Surface Waters 75
2.1.2 Types and Sources of Chemicals Present in Surface Waters 78
V
vi
CONTENTS
2.2 Physical Transport in Surface Waters 80
2.2.1 Rivers 80
2.2.2 Lakes 91
2.2.3 Estuaries 97
2.2.4 Wetlands 100
2.2.5 Oceans 101
2.2.6 Particles in Surface Waters 104
2.3 Air-Water Exchange 116
2.3.1 Thin Film and Surface Renewal Models 118
2.3.2 Estimation of Gas Exchange Coefficients 120
2.3.3 Modeling Concentrations of Volatile Chemicals in Surface Waters 125
2.3.4 Modeling Volatilization from Pure Phase Liquids 125
2.4 Chemical and Biological Characteristics of Surface Waters 129
2.4-1 Acid-Base Chemistry 129
2.4.2 Aquatic Ecosystems 137
2.4.3 Reduction-Oxidation Chemistry: Power for Ecosystems 147
2.5 Dissolved Oxygen Modeling in Surface Waters 158
2.6 Biotransformation and Biodegradation 163
2.6.1 Aerobic Biodegradation 165
2.6.2 Anaerobic Biodegradation of Organic Compounds 167
2.6.3 Modeling Biodegradation 169
2.6.4 Bioconcentration and Bioaccumulation in Aquatic Organisms 177
2.7 Abiotic Chemical Transformations 181
2.7.1 Degradation of Chemicals by Light 181
2.7.2 Degradation of Chemicals by Water 190
2.8 Conclusion 196
Exercises 197
References 215
3. The Subsurface Environment 219
3.1 Introduction 219
3.1.1 Nature of the Subsurface Environment 219
3.1.2 Sources of Pollutant Chemicals to the Subsurface Environment 223
3.2 Physics of Groundwater Movement 225
3.2.1 Darcy s Law 226
3.2.2 Flow Nets 231
3.2.3 Groundwater Wells 235
3.2.4 Unsteady (Transient) Flow and Aquifer Storage 246
3.2.5 Dispersion 251
3.3 Flow in the Unsaturated (Vadose) Zone 261
3.3.1 The Nature of the Unsaturated Zone 261
3.3.2 Water Transport in the Unsaturated Zone 263
3.4 The Flow of Nonaqueous Phase Liquids 268
3.5 Retardation 271
3.5.1 Chemical Sorption by Organic Carbon 274
3.5.2 Chemical Sorption by Black Carbon 275
CONTENTS
vii
3.5.3 Sorption by Ion Exchange 276
3.5.4 Surface Complexation 278
3.5.5 Nonideality in Retardation 279
3.6 Biodegradation in the Subsurface Environment 279
3.7 Subsurface Remediation 285
3.7.1 Physical Removal of Contaminants 286
3.7.2 Immobilization of Contaminants 287
3.7.3 In Situ Transformation of Contaminants 287
3.8 Conclusion 290
Exercises 291
References 308
4. The Atmosphere 311
4-1 Introduction 311
4.1.1 N ature of the Atmosphere 311
4.1.2 Sources of Pollutant Chemicals to the Atmosphere 319
4.2 Atmospheric Stability 327
4.2.1 The Dry Adiabatic Lapse Rate 327
4.2.2 The Wet Adiabatic Lapse Rate 331
4.2.3 Mixing Height 334
4.3 Circulation of the Atmosphere 337
4.3.1 Global Air Circulation 338
4.3.2 Synoptic-Scale Air Circulation 343
4.3.3 The Synoptic Weather Map 350
4.3.4 Local Effects 353
4.4 Transport of Chemicals in the Atmosphere 356
4-4-1 Indoor Air Pollution 357
4.4-2 Local-Scale Outdoor Air Pollution 362
4-4-3 Urban-Scale Air Pollution 376
4-4-4 Long-Range Transport Models 378
4.4-5 Global-Scale Transport of Chemicals 381
4.5 Physical Removal of Chemicals From the Atmosphere 383
4.5.1 Dry Deposition 384
4.5.2 Wet Deposition 390
4.6 Atmospheric Chemical Reactions 395
4.6.1 Oxidants in the Troposphere 396
4.6.2 Photochemical Smog and Organic Aerosol Production 399
4.6.3 Acid Deposition 406
4.6.4 Stratospheric Ozone Chemistry 411
4.7 The Greenhouse Effect and Global Climate Change 416
4.7.1 Radiation Balance of Earth 416
4.7.2 Greenhouse Gases 418
4.8 Conclusion 433
Exercises 434
References 449
viii
CONTENTS
Appendix: Dimensions and Units for Environmental
Quantities 455
A.l Fundamental Dimensions and Common Units of Measurement 455
A.2 Derived Dimensions and Common Units 457
Index 463
|
any_adam_object | 1 |
author | Hemond, Harold F. Fechner, Elizabeth J. |
author_GND | (DE-588)1089282745 (DE-588)1066893608 |
author_facet | Hemond, Harold F. Fechner, Elizabeth J. |
author_role | aut aut |
author_sort | Hemond, Harold F. |
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bvnumber | BV042211835 |
classification_rvk | AR 25000 RB 10915 VN 9350 WI 2500 |
ctrlnum | (OCoLC)891532642 (DE-599)BVBBV042211835 |
discipline | Chemie / Pharmazie Allgemeines Biologie Geographie |
edition | 3. ed. |
format | Book |
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id | DE-604.BV042211835 |
illustrated | Illustrated |
indexdate | 2024-12-20T17:04:55Z |
institution | BVB |
isbn | 9780123982568 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027650505 |
oclc_num | 891532642 |
open_access_boolean | |
owner | DE-703 DE-11 |
owner_facet | DE-703 DE-11 |
physical | X, 476 S. Ill., graph. Darst., Kt. |
publishDate | 2015 |
publishDateSearch | 2015 |
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publisher | Acad. Press |
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spellingShingle | Hemond, Harold F. Fechner, Elizabeth J. Chemical fate and transport in the environment Stoffübertragung (DE-588)4057696-6 gnd Schadstoff (DE-588)4051933-8 gnd Chemikalie (DE-588)4009833-3 gnd Transport (DE-588)4060680-6 gnd Umwelt (DE-588)4061616-2 gnd Biosphäre (DE-588)4140407-5 gnd Ökologische Chemie (DE-588)4135167-8 gnd Schadstofftransport (DE-588)4296576-7 gnd |
subject_GND | (DE-588)4057696-6 (DE-588)4051933-8 (DE-588)4009833-3 (DE-588)4060680-6 (DE-588)4061616-2 (DE-588)4140407-5 (DE-588)4135167-8 (DE-588)4296576-7 |
title | Chemical fate and transport in the environment |
title_auth | Chemical fate and transport in the environment |
title_exact_search | Chemical fate and transport in the environment |
title_full | Chemical fate and transport in the environment by Harold F. Hemond ; Elizabeth J. Fechner |
title_fullStr | Chemical fate and transport in the environment by Harold F. Hemond ; Elizabeth J. Fechner |
title_full_unstemmed | Chemical fate and transport in the environment by Harold F. Hemond ; Elizabeth J. Fechner |
title_short | Chemical fate and transport in the environment |
title_sort | chemical fate and transport in the environment |
topic | Stoffübertragung (DE-588)4057696-6 gnd Schadstoff (DE-588)4051933-8 gnd Chemikalie (DE-588)4009833-3 gnd Transport (DE-588)4060680-6 gnd Umwelt (DE-588)4061616-2 gnd Biosphäre (DE-588)4140407-5 gnd Ökologische Chemie (DE-588)4135167-8 gnd Schadstofftransport (DE-588)4296576-7 gnd |
topic_facet | Stoffübertragung Schadstoff Chemikalie Transport Umwelt Biosphäre Ökologische Chemie Schadstofftransport |
url | https://www.gbv.de/dms/tib-ub-hannover/810745240.pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027650505&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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