Verfügbarkeit: The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts

The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts:

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Bibliographische Detailangaben
Beteilige Person:	Wirth, Andreas S. (VerfasserIn)
Format:	Hochschulschrift/Dissertation Buch
Sprache:	Englisch
Veröffentlicht:	München Verl. Dr. Hut 2014
Ausgabe:	1. Aufl.
Schriftenreihe:	Anorganische Chemie
Schlagwörter:	Katalyse Palladiumverbindungen Kupplungsreaktion Hochschulschrift
Links:	http://deposit.dnb.de/cgi-bin/dokserv?id=4788844&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027577212&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Umfang:	109 S. Ill., graph. Darst. 210 mm x 148 mm, 292 g
ISBN:	9783843917285 3843917280

Internformat

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Datensatz im Suchindex

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adam_text	TABLE OF CONTENTS 1. INTRODUCTION 1 1.1. PALLADIUM-CATALYZED COUPLING REACTIONS 3 1.1.1. OVERVIEW 4 1.1.2. MECHANISTIC CONSIDERATIONS 8 1.2. LEACHING 11 1.2.1. SIGNIFICANCE OFLEACHING IN C-C CROSS-COUPLING REACTIONS 11 1.2.2. DISTINCTION BETWEEN HOMOGENEOUS AND HETEROGENEOUS REACTION PATHWAYS... 13 1.2.3. CONSEQUENCES FOR MECHANISTIC STUDIES 16 1.3. MOTIVATION AND AIM OF THE PRESENT WORK 18 2. CHARACTERISTICS AND FEATURES OF THE PALLADIUM CATALYSTS APPLIED 21 2.1. PALLADIUM ON ACTIVATED CARBON 22 2.2. CATALYSTS PREPARED BY CONTROLLED PRECIPITATION OF PALLADIUM ONTO SILICA 24 3. PALLADIUM NANOPARTICLES AS CATALYSTS FOR THE SUZUKI REACTION 27 3.1. STUDIES IN BIPHASIC REACTION MIXTURES 28 3.2. PD-NANOPARTICLES IN SOLUTION AND SUPPORTED ON SILICA 36 3.3. CONCLUSIONS: THE ACTIVE SPECIES IN THE SUZUKI REACTION . . 40 4. CONTINUOUS GAS FLOW REACTOR FOR THE HECK COUPLING REACTION 43 4.1. CONSTRUCTION OF THE FIXED BED REACTOR 44 4.2. ADVANTAGES AND CONSTRICTIONS 47 4.2.1. SCOPE OF APPLICATIONS 47 4.2.2. MODIFICATIONS 49 4.2.3. LIMITATIONS 52 HTTP://D-NB.INFO/1059096277 5. THE CONTRIBUTION OF SOLID PALLADIUM SURFACES DURING HECK REACTIONS 55 5.1. WORKING HYPOTHESIS 56 5.2. INFLUENCES OF THE REACTION PARAMETERS ON HECK COUPLING, DEHALOGENATION AND LEACHING 58 5.2.1. ROLE OF ADDITIVES 59 5.2.2. ROLE OF THE OXIDATION STATE OF PALLADIUM 60 5.2.3. ROLE OF THE PALLADIUM DISPERSION 61 5.2.4. ROLE OF THE BASE 63 5.2.5. INFLUENCE OF REDUCTIVE ENVIRONMENT 64 5.3. HECK REACTIONS IN THE GASEOUS PHASE 69 5.4. DISCUSSION OF THE REACTION MECHANISM 73 5.5. CONCLUSIONS: THE ACTIVE SPECIES IN THE HECK REACTION 77 6. SUMMARY 79 7. ZUSAMMENFASSUNG 85 8. EXPERIMENTAL SECTION 91 8.1. GENERAL REMARKS 92 8.1.1. CHEMICALS 92 8.1.2. ANALYTIC METHODS 92 8.1.3. APPARATUS 95 8.2. CATALYST PREPARATION 96 8.3. CATALYTIC EXPERIMENTS 98 8.3.1. SUZUKI COUPLING 98 8.3.2. HECK COUPLING 100 9. APPENDIX 101 10. REFERENCES 105
any_adam_object	1
author	Wirth, Andreas S.
author_facet	Wirth, Andreas S.
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author_sort	Wirth, Andreas S.
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dewey-ones	546 - Inorganic chemistry
dewey-raw	546.6362
dewey-search	546.6362
dewey-sort	3546.6362
dewey-tens	540 - Chemistry and allied sciences
discipline	Chemie / Pharmazie
edition	1. Aufl.
format	Thesis Book
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isbn	9783843917285 3843917280
language	English
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physical	109 S. Ill., graph. Darst. 210 mm x 148 mm, 292 g
publishDate	2014
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publisher	Verl. Dr. Hut
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series2	Anorganische Chemie
spellingShingle	Wirth, Andreas S. The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts Katalyse (DE-588)4029921-1 gnd Palladiumverbindungen (DE-588)4173148-7 gnd Kupplungsreaktion (DE-588)4166199-0 gnd
subject_GND	(DE-588)4029921-1 (DE-588)4173148-7 (DE-588)4166199-0 (DE-588)4113937-9
title	The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts
title_auth	The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts
title_exact_search	The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts
title_full	The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts Andreas Sebastian Wirth
title_fullStr	The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts Andreas Sebastian Wirth
title_full_unstemmed	The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts Andreas Sebastian Wirth
title_short	The nature of the active palladium-species in C-C coupling reactions with supported Pd-catalysts
title_sort	the nature of the active palladium species in c c coupling reactions with supported pd catalysts
topic	Katalyse (DE-588)4029921-1 gnd Palladiumverbindungen (DE-588)4173148-7 gnd Kupplungsreaktion (DE-588)4166199-0 gnd
topic_facet	Katalyse Palladiumverbindungen Kupplungsreaktion Hochschulschrift
url	http://deposit.dnb.de/cgi-bin/dokserv?id=4788844&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027577212&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT wirthandreass thenatureoftheactivepalladiumspeciesincccouplingreactionswithsupportedpdcatalysts

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