Environmental and low temperature geochemistry:
Gespeichert in:
Beteilige Person: | |
---|---|
Format: | Buch |
Sprache: | Englisch |
Veröffentlicht: |
Chichester
Wiley Blackwell
2014
|
Schlagwörter: | |
Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027379348&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
Beschreibung: | Includes bibliographical references and index |
Umfang: | XI, 402 S. |
ISBN: | 9781118867358 9781405186124 |
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adam_text | Titel: Environmental and low temperature geochemistry
Autor: Ryan, Peter Crowley
Jahr: 2014
Contents
Acknowledgements, xii
About the Companion Website, xiii
1 BACKGROUND AND BASIC
CHEMICAL PRINCIPLES: ELEMENTS,
IONS, BONDING, REACTIONS, 1
1.1 An overview of environmental
geochemistry - history, scope,
questions, approaches, challenges
for the future, 1
1.2 The naturally occurring elements -
origins and abundances, 2
1.3 Atoms and isotopes: a brief
review, 6
1.4 Measuring concentrations, 8
1.4.1 Mass-based concentrations, 8
1.4.2 Molar concentrations, 9
1.4.3 Concentrations
of gases, 10
1.4.4 Notes on precision and
accuracy, significant figures
and scientific notation, 10
1.5 Periodic table, 11
1.6 Ions, molecules, valence, bonding,
chemical reactions, 14
1.6.1 Ionic bond strength, 14
1.6.2 Covalent bonds, 16
1.6.3 Electronegativity, 17
1.6.4 Metallic bonds, hydrogen
bonds and van der Waals
forces, 18
1.7 Acid-base equilibria, pH, K values, 19
1.8 Fundamentals of redox chemistry and
chemical reactions, 21
1.9 Chemical reactions, 23
1.10 Equilibrium, thermodynamics and
driving forces for reactions: systems,
gibbs energies, enthalpy and heat
capacity, entropy, volume. 23
1.10.1 Systems, species, phases and
components, 24
1.10.2 First law of
thermodynamics, 26
1.10.3 Second law of
thermodynamics, 27
1.10.4 Enthalpy, 27
1.10.5 Heat capacity, 29
1.10.6 Gibbs free energy, 30
1.10.7 Gibbs free energy and the
equilibrium constant, 31
1.11 Kinetics and reaction rates: distance
from equilibrium, activation energy,
metastability, 33
1.11.1 Reaction rate, reaction
order, 34
1.11.2 Temperature and the
Arrhenius equation, 36
Review questions, 37
References, 37
2 SURFICIAL AND ENVIRONMENTAL
MINERALOGY, 39
2.1 Introduction to minerals and unit
cells, 40
2.2 Ion coordination, Pauling s rules and
ionic substitution, 42
2.2.1 Coordination and radius
ratio, 42
vi
Contents
2.2.2 Bond-strength
considerations, 45
2.2.3 Pauling s and Goldschmidt s
rules of ionic solids, 45
2.3 Silicates, 48
2.3.1 Nesosilicates, 49
2.3.2 Inosilicates, 50
2.3.3 Phyllosilicates, 52
2.3.4 Tectosilicates, 58
2.4 Clay minerals (T-0 minerals, T-O-T
minerals, interstratified clays), 58
2.4.1 Smectite, 59
2.4.2 Smectites with tetrahedrally
derived layer charge, 60
2.4.3 Smectites with octahedrally
derived layer charge, 60
2.4.4 Vermiculite, 62
2.4.5 Illite, 62
2.4.6 Chlorite and Berthierine, 63
2.4.7 Kaolin (kaolinite and
halloysite), 63
2.4.8 Interstratified clay
minerals, 64
2.4.9 Trace metals and metalloids in
clay minerals, 64
2.5 Crystal chemistry of adsorption and
cation exchange, 64
2.5.1 Cation exchange, 66
2.5.2 Double-layer
complexes, 68
2.6 Low-temperature non-silicate
minerals: carbonates, oxides and
hydroxides, sulfides, sulfates,
salts, 70
2.6.1 Carbonates, 70
2.6.2 Oxides and hydroxides, 71
2.6.3 Sulfides and sulfates, 72
2.6.4 Halide and nitrate salts, 74
2.7 Mineral growth and dissolution, 74
2.8 Biomineralization, 78
Review questions, 79
References, 80
3 ORGANIC COMPOUNDS IN THE
ENVIRONMENT, 82
3.1 Introduction to organic chemistry:
chains and rings, single, double,
and triple bonds, functional
groups, classes of organic
compounds, organic
nomenclature, 82
3.1.1 Definition of organic
compounds, 82
3.1.2 Hybridization of carbon atoms
in organic compounds, 83
3.1.3 Alkanes, 84
3.1.4 Alkenes, 86
3.1.5 Functional groups, 86
3.1.6 Aromatic hydrocarbons
and related compounds, 88
3.1.7 Nitrogen, phosphorus and
sulfur in organic
compounds, 92
3.1.8 Pharmaceutical
compounds, 93
3.2 Natural organic compounds
at the earth surface, 94
3.2.1 Fossil fuels, 95
3.3 Fate and transport of organic
pollutants, controls on bioavailability,
behavior of DNAPLs and LNAPLs,
biodegradation, remediation
schemes, 96
3.3.1 Solid-liquid-gas phase
considerations, 96
3.3.2 Solubility considerations, 97
3.3.3 Interactions of organic
compounds and
organisms, 98
3.3.4 Adsorption of organic
compounds, 99
3.3.5 Non-aqueous phase liquids
(NAPLs) in the
environment, 103
3.3.6 Biodegradation, 104
Contents vii
3.3.7 Remediation, 105
3.4 Summary, 106
Questions, 106
References, 106
4 AQUEOUS SYSTEMS - CONTROLS ON
WATER CHEMISTRY, 108
4.1 Introduction to the geochemistry of
natural waters, 108
4.1.1 Geochemistry and the
hydrologic cycle, 108
4.2 The structure of water - geometry,
polarity and consequences, 113
4.3 Dissolved versus particulate: examples
of solutions and suspensions, 114
4.3.1 Dissolved vs. particulate vs.
colloidal, 115
4.4 Speciation: simple ions, polyatomic
ions and aqueous complexes, 116
4.5 Controls on the solubility of inorganic
elements and ions, 117
4.5.1 The ratio ofionic charge: ionic
radius and its effect on
solubility, 119
4.5.2 Reduction-oxidation
reactions, 120
4.5.3 Half-cell reactions, 120
4.5.4 Redox reactions in the
environment, 122
4.5.5 pH and acid-base
consideration, 123
4.5.6 Ligands and elemental
mobility, 124
4.6 Ion activities, ionic strength, TDS, 125
4.6.1 Ion activity product, 126
4.6.2 Ionic strength, 126
4.6.3 Total dissolved solids, 126
4.7 Solubility products, saturation, 127
4.8 Co-precipitation, 128
4.9 Behavior of selected elements in
aqueous systems, 129
4.9.1 Examples of heavy metals and
metalloids, 129
4.9.2 Eh-pH diagrams, 132
4,9.3 Silicon in solutions, 136
4.10 Effect of adsorption and ion exchange
on water chemistry, 137
4.10.1 Ionic potential, hydration
radius and adsorption, 138
4.10.2 Law of mass action and
adsorption, 138
4.10.3 Adsorption edges, 140
4.10.4 Adsorption isotherms, 142
4.11 Other graphical representations of
aqueous systems: piper and stiff
diagrams, 143
4.12 Summary, 146
Questions, 147
References, 147
5 CARBONATE GEOCHEMISTRY AND
THE CARBON CYCLE, 149
5.1 Carbonate geochemistry: inorganic
carbon in the atmosphere and
hydrosphere, 149
5.1.1 Atmospheric C02, carbonate
species and the pH of rain, 150
5.1.2 Speciation in the carbonate
system as a function
of pH, 151
5.1.3 Alkalinity, 152
5.1.4 Carbonate solubility and
saturation, 155
5.1.5 The effect of C02 partial
pressure on stability of
carbonate minerals, 157
5.1.6 The effect of mineral
composition on
stability of carbonate
minerals, 157
5.2 The carbon cycle, 158
5.2.1 Oxidation states of carbon, 158
5.2.2 Global-scale reservoirs and
fluxes of carbon, 159
5.2.3 Fixation of carbon into the
crust, 161
5.2.4 Rates of flux to and from the
crust, 164
viii Contents
5.2.5 The ocean reservoir, 166
5.2.6 Fixation of C into oceans, 166
5.2.7 Long-term viability of oceans
as C sink, 168
5.2.8 The atmospheric
reservoir, 171
5.2.9 Sequestration, 174
Questions, 175
References, 176
6 BIOGEOCHEMICAL CYCLES -
N, P, S, 177
6.1 The nitrogen cycle, 180
6.1.1 Nitrogen valence, nitrogen
species, 181
6.1.2 Processes operating within the
nitrogen cycle, 182
6.1.3 Global scale reservoirs and
fluxes of nitrogen, 184
6.1.4 Human perturbation of
the nitrogen cycle and
resulting environmental
impacts, 186
6.2 The phosphorus cycle, 190
6.2.1 P cycling in soils, 191
6.2.2 The global phosphorus
cycle, 193
6.2.3 Phosphorus and
eutrophication, 194
6.3 Comparison of N and P, 195
6.4 The sulfur cycle, 196
6.4.1 Sulfur valence, sulfur
species, 196
6.4.2 The global S cycle, 197
6.4.3 The marine S cycle, 198
6.4.4 Soils and biota, 200
6.4.5 Atmosphere, 200
6.4.6 River flux, 201
6.5 Integrating the C, N, P and
S cycles, 202
Questions, 203
References, 203
7 THE GLOBAL ATMOSPHERE:
COMPOSITION, EVOLUTION AND
ANTHROPOGENIC CHANGE, 206
7.1 Atmospheric structure, circulation
and composition, 206
7.1.1 Structure and layering of the
atmosphere, 207
7.1.2 Geological record of
atmospheric composition, 208
7.1.3 Climate proxies, 209
7.1.4 Orbital control on C, 210
7.1.5 Composition of the current
atmosphere, 213
7.1.6 Air circulation, 214
7.2 Evaporation, distillation, C02
dissolution and the composition of
natural precipitation, 218
7.3 The electromagnetic spectrum,
greenhouse gases and climate, 219
7.3.1 Electromagnetic
spectrum, 219
7.3.2 Re-radiation from earth
surface, 219
7.3.3 Greenhouse effect and heat
trapping, 222
7.4 Greenhouse gases: structures, sources,
sinks and effects on climate, 223
7.4.1 Molecular structures and
vibrations of greenhouse
gases, 223
7.4.2 Greenhouse gases, radiative
forcing, GWPs, 224
7.4.3 Global warming, 227
Questions, 228
References, 228
8 URBAN AND REGIONAL AIR
POLLUTION, 230
8.1 Oxygen and its impact on atmospheric
chemistry, 231
8.2 Free radicals, 232
8.3 Sulfur dioxide, 234
Contents ix
8.4 Nitrogen oxides, 237
8.5 Carbon monoxide, 238
8.6 Particulate matter, 240
8.7 Lead (Pb), 242
8.8 Hydrocarbons and air quality:
tropospheric ozone and
photochemical smog, 242
8.9 Stratospheric ozone chemistry, 245
8.10 Sulfur and nitrogen gases and acid
deposition, 249
8.11 Trace elements in atmospheric
deposition: organochlorine pesticides,
mercury and other trace
elements, 252
8.11.1 Pesticides in air, 252
8.11.2 Hg in air, 253
8.11.3 As, Cd and Ni, 254
Questions. 255
References, 256
9 CHEMICAL WEATHERING AND
SOILS, 258
9.1 Primary minerals, mineral instability,
chemical weathering mechanisms
and reactions, soil-forming factors,
and products of chemical
weathering, 258
9.1.1 Goldich stability
sequence, 259
9.1.2 Weathering rates, 260
9.1.3 Chemical weathering, 261
9.1.4 Consequences of chemical
weathering: dissolved species
and secondary minerals, 264
9.1.5 Geochemical quantification of
elemental mobility in soil, 265
9.1.6 Quantifying chemical
weathering: CIA, 267
9.1.7 Soil profile, 268
9.1.8 Soil-forming factors, 268
9.1.9 Soil classification - soil orders
and geochemical controls, 273
9.2 Secondary minerals, controls on their
formation, and mineral stability
diagrams, 275
9.2.1 Factors controlling soil
mineralogy, 275
9.2.2 Mineral stability
diagrams, 276
9.3 Soils and the geochemistry of
paleoclimate analysis, 281
9.4 Effects of acid deposition on soils and
aquatic ecosystems, 282
9.4.1 Increased solubility of A1 in
acidic soil solution, 283
9.4.2 Displacement of adsorbed
nutrient cations, 284
9.4.3 Leaching of base cations
enhanced by increased NO3
and S04, 285
9.4.4 Decrease of soil buffering
capacity and base
saturation, 286
9.4.5 Acid deposition and heavy
metals, 287
9.5 Soils and plant nutrients, 287
9.6 Saline and sodic soils, 289
9.7 Toxic metals and metalloids, 290
9.8 Organic soil pollutants and
remediation (fuels, insecticides,
solvents), 294
Questions, 295
References, 296
10 STABLE ISOTOPE
GEOCHEMISTRY, 299
10.1 Stable isotopes - mass
differences and the concept of
fractionation, 299
10.2 Delta (5) notation, 302
10.3 Fractionation: vibrational
frequencies, temperature
dependence, 304
10.3.1 Stable isotopes and
chemical bond
strength, 305
10.3.2 Temperature-dependent
stable-isotope
fractionation, 305
x Contents
10.3.3 Equilibrium and
non-equilibrium isotope
fractionation, 307
10.4 51S0 and 6D, 309
10.4.1 Paleotemperature analysis
using oxygen and hydrogen
isotopes, 314
10.4.2 Oxygen and hydrogen
isotopes as tracers in the
hydrologic cycle, 314
10.4.3 Application of oxygen and
hydrogen isotopes to
paleosol climate
records, 316
10.5 515N, 316
10.6 613C, 318
10.6.1 Carbon isotope analysis of
paleoenvironment, 320
10.6.2 Carbon isotopes in
hydrology and chemical
weathering, 321
10.7 834S, 321
10.7.1 Fraction of sulfur
isotopes, 322
10.8 Non-traditional stable isotopes, 324
10.8.1 S65/63Cu, 325
10.8.2 S5f,/54Fe, 326
10.8.3 8202/198Hg, 326
10.8.4 826Mg and S44/42Ca, 328
10.8.5 837/35Cl, 330
10.9 Summary, 330
Questions, 331
References, 331
11 RADIOACTIVE AND RADIOGENIC
ISOTOPE GEOCHEMISTRY, 335
11.1 Radioactive decay, 335
11.1.1 Decay mechanisms and
products, 336
11.1.2 Half-lives, decay rates and
decay constants, 337
11.2 Radionuclides as tracers in
environmental geochemistry, 341
11.2.1 206Pb/207Pb, 341
11.2.2 87Sr/86Sr, 342
11.3 Radionuclides as environmental
contaminants, 342
11.3.1 Controls on U, Th and their
decay products, 342
11.3.2 Refined uranium ores and
associated nuclear
wastes, 346
11.3.3 Geological disposal of
high-level radioactive
wastes, 349
11.4 Geochronology, 350
11.4.1 14C, cosmogenic
radionuclides and
earth-surface dating
techniques, 350
11.4.2 Common radioactive decay
methods of dating sediments
and minerals, 359
11.4.3 234U/238U and 234U
disequilibrium, 364
Questions, 367
References, 367
APPENDIX I CASE STUDY ON THE
RELATIONSHIP OF VOLATILE ORGANIC
COMPOUNDS (VOCs), MICROBIAL
ACTIVITY, REDOX REACTIONS,
REMEDIATION AND ARSENIC MOBILITY
IN GROUNDWATER, 371
1.1 Site information, contaminant
delineation, 371
1.2 Remediation efforts, 372
1.3 Sources of PCE and As, 374
1.4 Mobilization of arsenic, 374
References, 377
APPENDIX II INSTRUMENTAL
ANALYSIS, 378
II. 1 Analysis of minerals and crystal
chemistry, 378
Contents xi
II. 1.1 Electron microscopy (SEM,
TEM and many other
acronyms), 378
11.1.2 X-ray diffraction, 379
11.1.3 FTIR, 382
II. 1.4 Elements in solution by
ICP-AES, ICP-MS, AAS, 384
11.1.5 XRF, 385
II. 1.6 X-ray absorption spectroscopy
(XAS) techniques (EXAFS,
XANES), 385
II. 1.7 Isotopic analysis: mass
spectrometry, 387
II. 1.8 Chromatography, 389
References, 389
APPENDIX III TABLE OF
THERMODYNAMIC DATA OF SELECTED
SPECIES AT 1 ATM AND 25 °C, 390
Index, 394
|
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id | DE-604.BV041936187 |
illustrated | Not Illustrated |
indexdate | 2024-12-20T16:58:16Z |
institution | BVB |
isbn | 9781118867358 9781405186124 |
language | English |
lccn | 013050119 |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027379348 |
oclc_num | 881367797 |
open_access_boolean | |
owner | DE-29 DE-83 DE-91 DE-BY-TUM DE-703 |
owner_facet | DE-29 DE-83 DE-91 DE-BY-TUM DE-703 |
physical | XI, 402 S. |
publishDate | 2014 |
publishDateSearch | 2014 |
publishDateSort | 2014 |
publisher | Wiley Blackwell |
record_format | marc |
spellingShingle | Ryan, Peter Crowley 1966- Environmental and low temperature geochemistry Environmental geochemistry Niedrigtemperatur (DE-588)4417434-2 gnd Geochemie (DE-588)4020198-3 gnd Umweltgeochemie (DE-588)4404136-6 gnd |
subject_GND | (DE-588)4417434-2 (DE-588)4020198-3 (DE-588)4404136-6 |
title | Environmental and low temperature geochemistry |
title_auth | Environmental and low temperature geochemistry |
title_exact_search | Environmental and low temperature geochemistry |
title_full | Environmental and low temperature geochemistry Peter Crowley Ryan |
title_fullStr | Environmental and low temperature geochemistry Peter Crowley Ryan |
title_full_unstemmed | Environmental and low temperature geochemistry Peter Crowley Ryan |
title_short | Environmental and low temperature geochemistry |
title_sort | environmental and low temperature geochemistry |
topic | Environmental geochemistry Niedrigtemperatur (DE-588)4417434-2 gnd Geochemie (DE-588)4020198-3 gnd Umweltgeochemie (DE-588)4404136-6 gnd |
topic_facet | Environmental geochemistry Niedrigtemperatur Geochemie Umweltgeochemie |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027379348&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT ryanpetercrowley environmentalandlowtemperaturegeochemistry |
Inhaltsverzeichnis
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Paper/Kapitel scannen lassen
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0003 GEO 430f 2014 L 826 Lageplan |
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0004 GEO 430f 2014 A 5166 Lageplan |
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Exemplar 1 | Nicht ausleihbar Am Standort |