From waste to fine chemicals: new radical reactions for the recovery of nitrogen monoxide
Gespeichert in:
| Beteilige Person: | |
|---|---|
| Format: | Hochschulschrift/Dissertation Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
München
Verl. Dr. Hut
2014
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Pharmazeutische Chemie
|
| Schlagwörter: | |
| Links: | http://deposit.dnb.de/cgi-bin/dokserv?id=4608957&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027258904&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| Umfang: | 197 S. Ill., graph. Darst. 210 mm x 148 mm, 319 g |
| ISBN: | 9783843914482 3843914486 |
Internformat
MARC
| LEADER | 00000nam a22000008c 4500 | ||
|---|---|---|---|
| 001 | BV041813577 | ||
| 003 | DE-604 | ||
| 005 | 20140508 | ||
| 007 | t| | ||
| 008 | 140423s2014 gw ad|| m||| 00||| eng d | ||
| 015 | |a 14,N11 |2 dnb | ||
| 020 | |a 9783843914482 |c Pb. : EUR 45.00 (DE), EUR 46.30 (AT), sfr 59.90 (freier Pr.) |9 978-3-8439-1448-2 | ||
| 020 | |a 3843914486 |9 3-8439-1448-6 | ||
| 024 | 3 | |a 9783843914482 | |
| 035 | |a (OCoLC)879577551 | ||
| 035 | |a (DE-599)BVBBV041813577 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 044 | |a gw |c XA-DE-BY | ||
| 049 | |a DE-19 |a DE-12 | ||
| 084 | |a 610 |2 sdnb | ||
| 100 | 1 | |a Salas, Cristina de |d 1987- |e Verfasser |0 (DE-588)1050233247 |4 aut | |
| 245 | 1 | 0 | |a From waste to fine chemicals |b new radical reactions for the recovery of nitrogen monoxide |c Cristina de Salas |
| 250 | |a 1. Aufl. | ||
| 264 | 1 | |a München |b Verl. Dr. Hut |c 2014 | |
| 300 | |a 197 S. |b Ill., graph. Darst. |c 210 mm x 148 mm, 319 g | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Pharmazeutische Chemie | |
| 502 | |a Zugl.: Erlangen-Nürnberg, Univ., Diss., 2014 | ||
| 650 | 0 | 7 | |a Chemische Reaktion |0 (DE-588)4009853-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Stickstoffmonoxidradikal |0 (DE-588)4491230-4 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Stickstoffmonoxid |0 (DE-588)4183282-6 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Stickstoffmonoxidradikal |0 (DE-588)4491230-4 |D s |
| 689 | 0 | 1 | |a Chemische Reaktion |0 (DE-588)4009853-9 |D s |
| 689 | 0 | |8 1\p |5 DE-604 | |
| 689 | 1 | 0 | |a Stickstoffmonoxid |0 (DE-588)4183282-6 |D s |
| 689 | 1 | 1 | |a Chemische Reaktion |0 (DE-588)4009853-9 |D s |
| 689 | 1 | |8 2\p |5 DE-604 | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |t From waste to fine chemicals: New radical reactions for the recovery of nitrogen monoxide |
| 856 | 4 | 2 | |m X:MVB |q text/html |u http://deposit.dnb.de/cgi-bin/dokserv?id=4608957&prov=M&dok_var=1&dok_ext=htm |3 Inhaltstext |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027258904&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 883 | 1 | |8 1\p |a cgwrk |d 20201028 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | |
| 883 | 1 | |8 2\p |a cgwrk |d 20201028 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-027258904 | |
Datensatz im Suchindex
| _version_ | 1819325292775211008 |
|---|---|
| adam_text | FROM WASTE TO FINE CHEMICALS:
NEW RADICAL REACTIONS FOR
THE RECOVERY OF NITROGEN
MONOXIDE
NATURWISSENTSCHAFLICHEN FAKULTAT
DER FRIEDRICH-ALEXANDER-UNIVERSITAT ERLANGEN-NUMBERG
ZUR
DOKTORGRADES DR. RER.
NAT.
VORGELEGT VON
CRISTINA DE SALAS
AUS BARCELONA, SPANIEN
HTTP://D-NB.INFO/1053634943
TABLE OF CONTENTS
TABLE OF CONTENTS
1. INTRODUCTION............................. .... ..... ..... .......
............. 1
1.1 NO, EMISSION: DANGERS AND
REGULATIONS.................................................................
2
1.2 DENITRIFICATION
PROCESSES..........................................................................................
4
13 NITROGEN-CENTERED RADICALS AND NITROGEN-CENTERED RADICAL SCAVENGERS
19
8
1.4 NO AND NO2 IN ORGANIC
REACTIONS..........................................................................
10
2. OBJECTIVES OF THE
THESIS............................................................................................
13
3. RESULTS AND
DISCUSSION..............................................................................................
15
3.1 CARBONITROSATION REACTIONS IS
3.1.1 SYNTHESIS OF OXIMES 16
3.1.2 MICRO-REACTOR: REACTIONS IN A
FLOW SYSTEM 35
3.1.3 TRAPPING OF NITROGEN MONOXIDE 38
3.1.4 RECYCLING EXPERIMENTS 47
3.1.5 APPLICATIONS OF OXIMES 53
3.1.6 CONCLUSION 64
3.2 IRON(II)-EDTA
COMPLEX.........................................................................................
65
3.2.1 ORGANOCOBALT REACTIONS WITH IRON(II)-EDTA-NO COMPLEX 66
3.2.2 CONCLUSION 71
33 OXIDATIVE NITRATION REACTIONS 73
3.3.1 OXIDATIVE NITRATION REACTIONS 74
3.3.2 OXIDATIVE NITRATION OF STYRENE AND STYRENE DERIVATIVES 75
3.3.3 FURTHER PROSPECTIVE: APPLICATIONS OF
NITROKETONES AND NITROALCOHOLS 90
3.3.4 CONCLUSION 91
TABLE OF CONTENTS
4. SUMMARY ..... 93
5.
ZUSAMMENFASSUNG....................................................................................................
97
6. EXPERIMENTAL
PART..................................................................................................
101
6.1 GENERAL REMARKS................
.............................*..............................................
101
6.2 CARBONITROSATION REACTIONS 103
6.2.1 SYNTHESIS OF DIAZONIUM TETRAFLUOROBOIATE SALTS
(GENERAL PROCEDURE 1, GP1).. 103
6.2.2 GENERAL PROCEDURES FOR THE SYNTHESIS OF
OXIMES 109
6.2.3 CHARACTERIZATION OF THE OXIMES 111
6.2.4 GENERAL PROCEDURE
FOR THE MEASUREMENTS OF NITROGEN MONOXIDE
TRAPPING (GP6)
141
6.2.5 GENERAL PROCEDURE FOR THE REDUCTION OF OXIMES
(GP7) AND CHARACTERISATION OF THE
AMINES
80
1
146
6.2.6 RESOLUTION RACEMIZATION PROCEDURE FOR
(R)-73 (GP8) 151
6.2.7 GENERAL PROCEDURE
FOR THE BENZYLATION OF OXIMES (GP9) AND CHARACTERISATION
OF
THE BENZILATED OXIMES
911
152
6.2.8 RADICAL ALKYLATION USING PHOTOINITIATION OR
TITANIUM(III) CHLORIDE 155
6.2.9 IONIC ALLYLATION AND ALKYLATION 158
6 J ORGANOCOBALT COMPLEXES.... ...............................
.........................*....... 161
6.3.1 SYNTHESES OF ORGANOCOBALT
COMPLEXES 161
6.3.2 SYNTHESIS OF OXIMES 164
6.4 NITRATION OF STYRENE WITH NITROGEN MONOXIDE .......................
........... 166
6.4.1 GENERAL PROCEDURE FOR THE SYNTHESIS OF
NITROKETONES AND NITROALCOHOLS 166
6.4.2 CHARACTERIZATION OF COMPOUNDS 102-105 168
6.4.3 VARIATION CONDITIONS FOR THE NITRO OXIDATIVE REACTION OF STYRENE
AND 4-
CHLOROSTYRENE 170
6.4.4 OXIDATIVE NITRATION
USING A MICRO-FLOW SYSTEM 176
TABLE OF CONTENTS
7. LIST OF ABBREVIATIONS 181
8. REFERENCES 189
|
| any_adam_object | 1 |
| author | Salas, Cristina de 1987- |
| author_GND | (DE-588)1050233247 |
| author_facet | Salas, Cristina de 1987- |
| author_role | aut |
| author_sort | Salas, Cristina de 1987- |
| author_variant | c d s cd cds |
| building | Verbundindex |
| bvnumber | BV041813577 |
| ctrlnum | (OCoLC)879577551 (DE-599)BVBBV041813577 |
| discipline | Medizin |
| edition | 1. Aufl. |
| format | Thesis Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>02426nam a22005298c 4500</leader><controlfield tag="001">BV041813577</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20140508 </controlfield><controlfield tag="007">t|</controlfield><controlfield tag="008">140423s2014 gw ad|| m||| 00||| eng d</controlfield><datafield tag="015" ind1=" " ind2=" "><subfield code="a">14,N11</subfield><subfield code="2">dnb</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">9783843914482</subfield><subfield code="c">Pb. : EUR 45.00 (DE), EUR 46.30 (AT), sfr 59.90 (freier Pr.)</subfield><subfield code="9">978-3-8439-1448-2</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">3843914486</subfield><subfield code="9">3-8439-1448-6</subfield></datafield><datafield tag="024" ind1="3" ind2=" "><subfield code="a">9783843914482</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)879577551</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV041813577</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="044" ind1=" " ind2=" "><subfield code="a">gw</subfield><subfield code="c">XA-DE-BY</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-19</subfield><subfield code="a">DE-12</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">610</subfield><subfield code="2">sdnb</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Salas, Cristina de</subfield><subfield code="d">1987-</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)1050233247</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">From waste to fine chemicals</subfield><subfield code="b">new radical reactions for the recovery of nitrogen monoxide</subfield><subfield code="c">Cristina de Salas</subfield></datafield><datafield tag="250" ind1=" " ind2=" "><subfield code="a">1. Aufl.</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">München</subfield><subfield code="b">Verl. Dr. Hut</subfield><subfield code="c">2014</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">197 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield><subfield code="c">210 mm x 148 mm, 319 g</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="490" ind1="0" ind2=" "><subfield code="a">Pharmazeutische Chemie</subfield></datafield><datafield tag="502" ind1=" " ind2=" "><subfield code="a">Zugl.: Erlangen-Nürnberg, Univ., Diss., 2014</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Chemische Reaktion</subfield><subfield code="0">(DE-588)4009853-9</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Stickstoffmonoxidradikal</subfield><subfield code="0">(DE-588)4491230-4</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Stickstoffmonoxid</subfield><subfield code="0">(DE-588)4183282-6</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="0">(DE-588)4113937-9</subfield><subfield code="a">Hochschulschrift</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Stickstoffmonoxidradikal</subfield><subfield code="0">(DE-588)4491230-4</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Chemische Reaktion</subfield><subfield code="0">(DE-588)4009853-9</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="8">1\p</subfield><subfield code="5">DE-604</subfield></datafield><datafield tag="689" ind1="1" ind2="0"><subfield code="a">Stickstoffmonoxid</subfield><subfield code="0">(DE-588)4183282-6</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="1" ind2="1"><subfield code="a">Chemische Reaktion</subfield><subfield code="0">(DE-588)4009853-9</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="1" ind2=" "><subfield code="8">2\p</subfield><subfield code="5">DE-604</subfield></datafield><datafield tag="776" ind1="0" ind2="8"><subfield code="i">Erscheint auch als</subfield><subfield code="n">Online-Ausgabe</subfield><subfield code="t">From waste to fine chemicals: New radical reactions for the recovery of nitrogen monoxide</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">X:MVB</subfield><subfield code="q">text/html</subfield><subfield code="u">http://deposit.dnb.de/cgi-bin/dokserv?id=4608957&prov=M&dok_var=1&dok_ext=htm</subfield><subfield code="3">Inhaltstext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">DNB Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027258904&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="883" ind1="1" ind2=" "><subfield code="8">1\p</subfield><subfield code="a">cgwrk</subfield><subfield code="d">20201028</subfield><subfield code="q">DE-101</subfield><subfield code="u">https://d-nb.info/provenance/plan#cgwrk</subfield></datafield><datafield tag="883" ind1="1" ind2=" "><subfield code="8">2\p</subfield><subfield code="a">cgwrk</subfield><subfield code="d">20201028</subfield><subfield code="q">DE-101</subfield><subfield code="u">https://d-nb.info/provenance/plan#cgwrk</subfield></datafield><datafield tag="943" ind1="1" ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-027258904</subfield></datafield></record></collection> |
| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV041813577 |
| illustrated | Illustrated |
| indexdate | 2024-12-20T16:55:36Z |
| institution | BVB |
| isbn | 9783843914482 3843914486 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027258904 |
| oclc_num | 879577551 |
| open_access_boolean | |
| owner | DE-19 DE-BY-UBM DE-12 |
| owner_facet | DE-19 DE-BY-UBM DE-12 |
| physical | 197 S. Ill., graph. Darst. 210 mm x 148 mm, 319 g |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Verl. Dr. Hut |
| record_format | marc |
| series2 | Pharmazeutische Chemie |
| spellingShingle | Salas, Cristina de 1987- From waste to fine chemicals new radical reactions for the recovery of nitrogen monoxide Chemische Reaktion (DE-588)4009853-9 gnd Stickstoffmonoxidradikal (DE-588)4491230-4 gnd Stickstoffmonoxid (DE-588)4183282-6 gnd |
| subject_GND | (DE-588)4009853-9 (DE-588)4491230-4 (DE-588)4183282-6 (DE-588)4113937-9 |
| title | From waste to fine chemicals new radical reactions for the recovery of nitrogen monoxide |
| title_auth | From waste to fine chemicals new radical reactions for the recovery of nitrogen monoxide |
| title_exact_search | From waste to fine chemicals new radical reactions for the recovery of nitrogen monoxide |
| title_full | From waste to fine chemicals new radical reactions for the recovery of nitrogen monoxide Cristina de Salas |
| title_fullStr | From waste to fine chemicals new radical reactions for the recovery of nitrogen monoxide Cristina de Salas |
| title_full_unstemmed | From waste to fine chemicals new radical reactions for the recovery of nitrogen monoxide Cristina de Salas |
| title_short | From waste to fine chemicals |
| title_sort | from waste to fine chemicals new radical reactions for the recovery of nitrogen monoxide |
| title_sub | new radical reactions for the recovery of nitrogen monoxide |
| topic | Chemische Reaktion (DE-588)4009853-9 gnd Stickstoffmonoxidradikal (DE-588)4491230-4 gnd Stickstoffmonoxid (DE-588)4183282-6 gnd |
| topic_facet | Chemische Reaktion Stickstoffmonoxidradikal Stickstoffmonoxid Hochschulschrift |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4608957&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027258904&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT salascristinade fromwastetofinechemicalsnewradicalreactionsfortherecoveryofnitrogenmonoxide |