Soft fibrillar materials: fabrication and applications
Gespeichert in:
Beteilige Person: | |
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Format: | Buch |
Sprache: | Englisch |
Veröffentlicht: |
Weinheim
Wiley-VCH
2013
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Schlagwörter: | |
Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026884202&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
Umfang: | XVIII, 302 S. Ill., graph. Darst. |
ISBN: | 352733162X 9783527331628 9783527648047 9783527648054 9783527648061 |
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adam_text | IMAGE 1
CONTENTS
PREFACE XI LIST OF CONTRIBUTORS XV
SECTION I SMALL MOLECULE CELS 1
1 MOLECULAR CELS AND THEIR FIBRILLAR NETWORKS 3
KEVIN L. CARAN, DONG-CHAN LEE, AND RICHARD G. WEISS 1.1 INTRODUCTION 3
1.2 ADVANCES AND PERSPECTIVES FOR DESIGN OF GELATORS 6 1.2.1 ANALYSES OF
STRUCTURE PACKING VIA X-RAY, SYNCHROTRON, AND OTHER TECHNIQUES,
INCLUDING SPECTROSCOPIC TOOLS 6
1.2.2 CHIRALITY AS A TOOL - COMPARISONS BETWEEN OPTICALLY PURE AND
RACEMIC GELATORS AND OPTICALLY PURE AND RACEMIC LIQUIDS 17 1.2.3 LIQUIDS
AND THEIR INFLUENCE ON GELATOR NETWORKS 25 1.3 STIMULATION OF GELATION
BY PERTURBATIONS OTHER THAN
TEMPERATURE 33
1.3.1 ENZYMATIC IN SITU FORMATION OF GELATORS AND GELS-POTENTIAL
BIOLOGICAL APPLICATIONS 33 1.3.2 ULTRASOUND - CONFORMATIONAL AND
AGGREGATION/DE-AGGREGATION EFFECTS 40
1.3.3 RADIATION-INDUCED GELATION AND DEGELATION 47 1.4 KINETIC MODELS
FOR FOLLOWING ONE-DIMENSIONAL GROWTH AND GELATION 50 1.5 ADVANCES AND
PERSPECTIVES FOR A PRIORI DESIGN OF GELATORS 59 1.6 SOME FINAL THOUGHTS
66
ACKNOWLEDGMENTS 67 REFERENCES 67
2 ENGINEERING OF SMALL-MOLECULE GELS BASED ON THE THERMODYNAMICS AND
KINETICS OF FIBER FORMATION 77 JING-LIANG LI AND XIANG YANG LIU 2.1
INTRODUCTION 77
HTTP://D-NB.INFO/1033857734
IMAGE 2
VI1 CONTENTS
2.2 FIBER NETWORKS OF SMGS 78
2.2.1 NUCLEATION AND GROWTH MECHANISM OF FIBER NETWORK FORMATION 78
2.2.2 SINGLE AND MULTI-DOMAIN FIBER NETWORKS 78 2.2.3 FIBER BRANCHING 82
2.2.4 STRUCTURAL CHARACTERISTICS OF FIBER NETWORKS 82 2.3
CRYSTALLIZATION OF NANOFIBERS 84
2.3.1 THERMODYNAMIC DRIVING FORCE 84 2.3.2 HOMOGENEOUS AND HETEROGENEOUS
NUCLEATION 85 2.3.3 CRYSTALLOGRAPHIC MISMATCH NUCLEATION INDUCED FIBER
BRANCHING 87
2.3.3.1 FIBER TIP BRANCHING 89 2.3.3.2 FIBER SIDE BRANCHING 89 2.3.4
GROWTH AND BRANCHING KINETICS OF NANOFIBERS 90
2.4 STRATEGIES FOR ENGINEERING THE MICRO/NANO STRUCTURE OF FIBER
NETWORKS 94 2.4.1 ENGINEERING OF SINGLE FIBER NETWORKS 94 2.4.1.1
EFFECTS OF SUPERSATURATION/SUPER COOLING ON FIBER BRANCHING 94
2.4.1.2 ADDITIVE-MEDIATED FIBER BRANCHING 95 2.4.2 ENGINEERING OF
MULTI-DOMAIN FIBER NETWORKS 98 2.4.2.1 MANIPULATING FIBER NETWORK BY
CONTROLLING PRIMARY NUCLEATION 99 . 2.4.2.2 SWITCHING BETWEEN
MULTI-DOMAIN FIBER NETWORKS AND
INTERCONNECTING FIBER NETWORKS 102 2.4.2.3 KINETICALLY CONTROLLED
HOMOGENIZATION OF FIBER NETWORKS 105 2.4.2.4 ENGINEERING MULTI-DOMAIN
FIBER NETWORKS BY VOLUME CONFINEMENT 107
2.5 ENGINEERING THE MACROSCOPIC PROPERTIES OF GELS BY DESIGN OF FIBER
NETWORKS 107 2.5.1 IMPROVING THE ELASTICITY OF A MATERIAL BY CONTROLLING
THE PRIMARY NUCLEATION OF THE GELATOR 108 2.5.2 IMPROVING THE ELASTICITY
OF A MATERIAL BY ENHANCING FIBER
BRANCHING 109
2.5.3 IMPROVING THE ELASTICITY OF A MATERIAL BY CONVERTING ITS
MULTI-DOMAIN NETWORK INTO AN INTERCONNECTING ( SINGLE ) FIBER NETWORK
110 2.6 CONCLUSIONS 111
REFERENCES 111
3 APPLICATIONS OF SMALL-MOLECULE GELS - DRUG DELIVERY 115 LIFENG KANG,
HAN HUI CHEONG, SUI YUNG CHAN AND PERRY FUNG CHYE LIM 3.1 INTRODUCTION
115
3.2 HYDROGELS IN PHARMACEUTICAL APPLICATIONS 117 3.2.1 DRUG CARRIERS 117
3.2.2 DRUG-DERIVATIZED SMALL-MOLECULAR HYDROGELATORS 118 3.2.3
DRUG-GELATOR CONJUGATES 118 3.3 ORGANOGELS IN PHARMACEUTICAL
APPLICATIONS 119
IMAGE 3
CONTENTS I VII
3.3.1 DERMAL AND TRANSDERMAL FORMULATION 120
3.3.2 PARENTERAL DEPOT FORMULATION 121 3.3.3 ORAL FORMULATION 122
3.4 ORGANOGEL DELIVERY OF BIOACTIVE FACTORS IN REGENERATIVE MEDICINE 123
3.5 FUTURE DIRECTIONS: HYBRID ORGANOGELS 123 3.6 CONCLUSION 125
REFERENCES 125
4 MOLECULAR CELS FOR TISSUE ENGINEERING 129
JUN YAN, BIN SHENG WONG, AND LIFENG KANG 4.1 INTRODUCTION 129
4.2 LOW-MOLECULAR-WEIGHT GELATORS AND MOLECULAR GELS 12 9 4.3
SELF-ASSEMBLY AND GEL STRUCTURES 131
4.4 APPLICATIONS OF HYDROGELS IN TISSUE ENGINEERING 133 4.4.1
PEPTIDE-BASED MOLECULAR GELS 136 4.4.1.1 SELF-COMPLEMENTARY ALTERNATING
AMPHIPHILIC PEPTIDES 137 4.4.1.2 PEPTIDE AMPHIPHILES 138
4.4.2 SACCHARIDE-BASED MOLECULAR GELS 140 4.4.3 LIPID-BASED MOLECULAR
GELS 142 4.4.4 NUCLEOBASE-BASED MOLECULAR GELS 146 4.4.4.1 NUCLEOBASES
AND HYBRID BIOMOLECULES CONTAINING
NUDEOBASES 147
4.4.4.2 NUCLEIC ACID CHAINS 150 4.5 SUMMARY 155
LIST OF ABBREVIATIONS 15 6 APPENDIX: GELATORS AND THEIR POTENTIAL USE
AND APPLICATIONS 157 REFERENCES 159
5 MOLECULAR GELS FOR CONTROLLED FORMATION OF MICRO-/NANO-STRUCTURES 163
JING-LIANG LI AND XIANG YANG LIU 5.1 INTRODUCTION 163
5.2 STRUCTURE OF METAL/TRANSITION METAL OXIDE AND SULFATE 164 5.2.1
SILICA NANOFIBERS AND NANOTUBES 164 5.2.2 SILICA NANOPARTICLES 166
5.2.3 NANOFIBERS/TUBES OF METAL/TRANSITION METAL OXIDE AND SULFATE 167
5.3 METALLIC NANOSTRUCTURES 170
5.3.1 SILVER AND GOLD NANOPARTICLES 170 5.3.2 SILVER AND GOLD NANOWIRES
172 5.4 CONTROLLED FORMATION OF ORGANIC AND COMPOSITE STRUCTURES 175 5.5
CONTROLLING CRYSTAL GROWTH OF PHARMACEUTICAL SUBSTANCES 176
5.6 CONCLUSIONS AND PERSPECTIVES 177
REFERENCES 179
IMAGE 4
VIM I CONTENTS
SECTION II NATURAL SILK FIBROUS MATERIALS 183
6 SPIDER SILK: STRUCTURE, ENGINEERING, AND APPLICATIONS 185 NING DU AND
XIANG YANG LIU 6.1 INTRODUCTION 185
6.2 MECHANICAL DESIGN OF SPIDER SILK 187
6.2.1 HIERARCHICAL STRUCTURE OF SPIDER SILK 187 6.2.2 STRAIN HARDENING
OF SPIDER DRAGLINE SILK 189 6.2.3 ENVIRONMENTAL EFFECTS ON THE
MECHANICAL PROPERTIES OF SPIDER SILK 193
6.2.3.1 SUPERCONTRACTION OF SPIDER DRAGLINES 193 6.2.3.2 TOUGH SILK AT
LOW TEMPERATURE 193 6.3 MIMICKING SPIDER SILK 194
6.3.1 GENETIC ENGINEERING 194
6.3.1.1 SILK PROTEINS FROM MAMMALIAN CELLS 195 6.3.1.2 HARVESTING
SPIDER SILK FROM SILKWORMS 195 6.3.2 MODIFICATION OF SPINNING
CONDITIONS 195 6.3.2.1 CRYSTALLITE SIZE 196
6.3.2.2 ORIENTATION DISTRIBUTION 197 6.3.2.3 INTERCRYSTALLITE DISTANCE
198 6.3.3 TOUGHER SILK THAN NATURAL SPIDER SILK 200 6.4 APPLICATIONS 201
6.4.1 TISSUE ENGINEERING 201
6.4.2 DRUG DELIVERY 202
6.4.3 TECHNICAL APPLICATIONS 202 REFERENCES 204
7 FUNCTIONALIZATION OF COLORED/FLUORESCENT SILKWORM SILK FIBROUS
MATERIALS 209 NAIBO LIN, XIANG YANG LIU, HONGYAO XU, GUOYANG WILLIAM
TOH, AND JING-LIANG LI 7.1 INTRODUCTION 209
7.2 LEGEND AND HISTORY OF SILKWORM SILK 210
7.3 THE STRUCTURE OF SILKWORM SILK 211
7.4 FUNCTIONALIZATION OF SILKWORM SILK 215 7.4.1 COLORED/FLUORESCENT
SILKWORM SILK 216 7.4.1.1 GENETIC ENGINEERING 216 7.4.1.2 NANOPARTICLES
217
7.4.1.3 DIETING 218
7.4.2 OPTICAL LIMITING SILKWORM SILK FILMS 220 7.4.3 TWO-PHOTON
FLUORESCENT SILKWORM SILK FIBERS 220 7.4.3.1 TWO-PHOTON ABSORPTION
CROSS-SECTION OF DESIGNED ORGANIC MOLECULES 222
7.4.3.2 TWO-PHOTON FLUORESCENCE QUANTUM YIELD OF DESIGNED ORGANIC
MOLECULES 223
IMAGE 5
CONTENTS | IX
7.4.3.3 TWO-PHOTON FLUORESCENCE SILK IN APPLICATION OF BIO-IMAGING 224
7.4.4 NANO- AND MICRO-PATTERNING OF SILK FIBROIN FILMS FOR BIOMEDICAL
OPTICAL APPLICATIONS 224 7.4.5 CONSTRUCTION OF STRUCTURAL COLOR TO SILK
FABRICS 225 7.5 SUMMARY AND OUTLOOK 227
REFERENCES 227
SECTION III SMART FIBERS 233
8 FLEXIBLE NANOGENERATOR AND NANO-PRESSURE SENSOR BASED ON NANOFIBER WEB
OF PVDF AND ITS COPOLYMERS 235 CHUNYE XU AND KAP JIN KIM 8.1
INTRODUCTION 235
8.2 ELECTROSPINNING MECHANISM AND SET-UP 236 8.3 NANOFIBER WEB 237
8.3.1 PREPARATION AND CHARACTERIZATION OF PVDF NANOFIBER FABRIC UNDER
VARIED CONDITIONS 237 YONGRONG WANG AND CHUNYE XU
8.3.1.1 MORPHOLOGY AND DIAMETER DISTRIBUTION OF PVDF NANOFIBER 237
8.3.1.2 CRYSTALLINE STRUCTURE OF PVDF NANOFIBERS 238 8.3.2 NANOFIBER WEB
OF PVDF WITH CACL2 AND CARBON NANOTUBE 240 SUN YOON AND KAP JIN KIM
8.3.3 NANOFIBER OF COPOLYMER P(VDF-TRFE) 243 GUANGYI REN AND CHUNYE XU
8.4 PIEZOELECTRIC PROPERTIES OF ELECTROSPUN WEB OF PVDF AND ITS
COPOLYMER 245 8.4.1 PIEZOELECTRICITY OF PVDF WEB UNDER DIFFERENT
ELECTROSPINNING
CONDITIONS 245 YONGRONG WANG AND CHUNYE XU 8.4.2 ORIGIN OF
PIEZOELECTRICITY IN ELECTROSPUN NANOFIBER WEB 246 DIPANKAR MANDAL, SUN
YOON, AND KAP JIN KIM 8.5 FLEXIBLE DEVICES 255
8.5.1 PVDF WEB-BASED SENSOR 255 DIPANKAR MANDAL, SUN YOON, AND KAP JIN
KIM 8.5.2 TOUCH SENSOR BASED ON A PVDF ELECTROSPUN WEB WITH CACL2 AND
CNTS 256
SUN YOON AND KAP JIN KIM 8.5.3 FORCE SENSORS BASED ON COPOLYMER
P(VDF-TRFE) WITH DIFFERENT VDF CONTENTS N 258 GUANGYI REN, BAOZHANG LI,
AND CHUNYE XU
8.5.4 NANOGENERATOR BASED ON ELECTROSPUN PVDF NANOFIBER WEB 259 KAP JIN
KIM 8.6 CONCLUSION 261
REFERENCES 263 *
IMAGE 6
X | CONTENTS
9 ELECTROSPUN NANOFIBERS FOR REGENERATIVE MEDICINE 265
WENYING LIU, STAVROS THOMOPOULOS, AND YOUNAN XIA 9.1 INTRODUCTION 265
9.2 ELECTROSPINNING OF NANOFIBERS 267
9.2.1 SETUP AND PRINCIPLE 267
9.2.2 MATERIALS CONSIDERATION 269 9.2.3 INCORPORATION OF BIOACTIVE
MOLECULES 269 9.2.4 DEGRADATION CHARACTERISTICS 270 9.2.5 MECHANICAL
PROPERTIES 271
9.2.6 CELL INFILTRATION 272
9.3 CONTROLLING THE ALIGNMENT OF NANOFIBERS 273 9.3.1 ALIGNMENT CAUSED
BY MECHANICAL FORCES 274 9.3.2 ALIGNMENT CAUSED BY ELECTROSTATIC FORCES
275 9.3.3 ALIGNMENT CAUSED BY MAGNETIC FORCES 277
9.4 NANOFIBER SCAFFOLDS WITH COMPLEX ARCHITECTURES 277 9.4.1 STACKED
ARRAYS OF NANOFIBERS 278 9.4.2 CONDUITS ASSEMBLED FROM NANOFIBERS 278
9.5 APPLICATIONS IN REGENERATIVE MEDICINE 280
9.5.1 NERVE INJURY REPAIR 280
9.5.2 DURA MATER REPAIR 283
9.5.3 TENDON/LIGAMENT REPAIR 284 9.5.4 TENDON-TO-BONE INSERTION SITE
REPAIR 287 9.6 CONCLUDING REMARKS 290
ACKNOWLEDGMENTS 291 REFERENCES 291
INDEX 297
|
any_adam_object | 1 |
author | Liu, Xiang Yang |
author_GND | (DE-588)173604528 |
author_facet | Liu, Xiang Yang |
author_role | aut |
author_sort | Liu, Xiang Yang |
author_variant | x y l xy xyl |
building | Verbundindex |
bvnumber | BV041437367 |
classification_rvk | UQ 8320 ZM 7090 |
ctrlnum | (OCoLC)859568036 (DE-599)DNB1033857734 |
dewey-full | 541.2254 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 541 - Physical chemistry |
dewey-raw | 541.2254 |
dewey-search | 541.2254 |
dewey-sort | 3541.2254 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften / Fertigungstechnik |
format | Book |
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genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
genre_facet | Aufsatzsammlung |
id | DE-604.BV041437367 |
illustrated | Illustrated |
indexdate | 2024-12-20T16:47:19Z |
institution | BVB |
isbn | 352733162X 9783527331628 9783527648047 9783527648054 9783527648061 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-026884202 |
oclc_num | 859568036 |
open_access_boolean | |
owner | DE-703 DE-92 |
owner_facet | DE-703 DE-92 |
physical | XVIII, 302 S. Ill., graph. Darst. |
publishDate | 2013 |
publishDateSearch | 2013 |
publishDateSort | 2013 |
publisher | Wiley-VCH |
record_format | marc |
spellingShingle | Liu, Xiang Yang Soft fibrillar materials fabrication and applications Seide (DE-588)4054289-0 gnd Intelligenter Werkstoff (DE-588)4274825-2 gnd Weiche Materie (DE-588)4609142-7 gnd Spinnen (DE-588)4132662-3 gnd Faserstruktur (DE-588)4153762-2 gnd Polymeres Netzwerk (DE-588)4307122-3 gnd Faser (DE-588)4127566-4 gnd Faserstoff (DE-588)4016502-4 gnd Naturfaser (DE-588)4127568-8 gnd Gel (DE-588)4019868-6 gnd |
subject_GND | (DE-588)4054289-0 (DE-588)4274825-2 (DE-588)4609142-7 (DE-588)4132662-3 (DE-588)4153762-2 (DE-588)4307122-3 (DE-588)4127566-4 (DE-588)4016502-4 (DE-588)4127568-8 (DE-588)4019868-6 (DE-588)4143413-4 |
title | Soft fibrillar materials fabrication and applications |
title_auth | Soft fibrillar materials fabrication and applications |
title_exact_search | Soft fibrillar materials fabrication and applications |
title_full | Soft fibrillar materials fabrication and applications ed. by Xiang Yang Liu ... |
title_fullStr | Soft fibrillar materials fabrication and applications ed. by Xiang Yang Liu ... |
title_full_unstemmed | Soft fibrillar materials fabrication and applications ed. by Xiang Yang Liu ... |
title_short | Soft fibrillar materials |
title_sort | soft fibrillar materials fabrication and applications |
title_sub | fabrication and applications |
topic | Seide (DE-588)4054289-0 gnd Intelligenter Werkstoff (DE-588)4274825-2 gnd Weiche Materie (DE-588)4609142-7 gnd Spinnen (DE-588)4132662-3 gnd Faserstruktur (DE-588)4153762-2 gnd Polymeres Netzwerk (DE-588)4307122-3 gnd Faser (DE-588)4127566-4 gnd Faserstoff (DE-588)4016502-4 gnd Naturfaser (DE-588)4127568-8 gnd Gel (DE-588)4019868-6 gnd |
topic_facet | Seide Intelligenter Werkstoff Weiche Materie Spinnen Faserstruktur Polymeres Netzwerk Faser Faserstoff Naturfaser Gel Aufsatzsammlung |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=026884202&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT liuxiangyang softfibrillarmaterialsfabricationandapplications |