Verfügbarkeit: Applied homogeneous catalysis | Technische Universität München

Applied homogeneous catalysis:

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Bibliographische Detailangaben
Beteiligte Personen:	Behr, Arno 1952- (VerfasserIn), Neubert, Peter 1981- (VerfasserIn)
Format:	Buch
Sprache:	Englisch
Veröffentlicht:	Weinheim Wiley-VCH 2012
Schlagwörter:	Angewandte Chemie Homogene Katalyse Technische Chemie
Links:	http://deposit.dnb.de/cgi-bin/dokserv?id=3718058&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022643829&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Umfang:	XXVIII, 688 S. Ill., graph. Darst.
ISBN:	9783527326334 3527326332 9783527326419

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MARC


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Datensatz im Suchindex

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adam_text	IMAGE 1 VII CONTENTS FOREWORD V PREFACE X I X ABBREVIATIONS X X I I I PART I CHEMICAL BASICS 1 1 DEFINITION, OPTIONS, A N D EXAMPLES: WHAT ACTUALLY IS CATALYSIS? 3 1.1 DEFINITION O F CATALYSIS 3 1.2 T H E DIFFERENT VARIETIES O F CATALYSIS 5 1.3 T H E DIRECTING EFFECT O F T H E CATALYST 8 1.4 CATALYSIS-AS A PART O F G R E E N CHEMISTRY 10 1.5 SOURCES O F INFORMATION ABOUT CATALYSIS 10 LITERATURE 14 2 A BRIEF HISTORY: H O M O G E N E O U S TRANSITION METAL CATALYSIS: A YOUNG SCIENCE 17 2.1 A BRIEF HISTORY 17 2.1.1 PHASE I: INORGANIC BASIC CHEMICALS (1898-1918) 18 2.1.2 PHASE II: REFINERY PROCESSES: SYNTHESIS GAS A N D ACETYLENE C H E M I S T R Y (1919-1945) 18 2.1.3 PHASE III: PETROCHEMICAL INDUSTRIAL PRODUCTS (1946-1970) 19 2.1.4 PHASE IV: FINE CHEMICALS A N D SPECIALTY PRODUCTS (1971 TO DATE) 21 LITERATURE 2 5 3 INDUSTRIAL H O M O G E N E O U S CATALYSIS: W H A T IS T H E ECONOMIC IMPORTANCE? 2 7 3.1 APPLICATION AREAS O F CATALYSIS 2 7 3.2 IMPORTANT H O M O G E N E O U S CATALYZED PROCESSES 2 7 3.3 SYNTHESIS O F FINE CHEMICALS BY H O M O G E N E O U S CATALYSIS 2 8 LITERATURE 3 2 4 4.1 4.2 DEFINITIONS O F IMPORTANT TERMS: SELECTIVITY, STY, TON, TOF, A N D M O R E . . . 3 5 CONVERSION 3 5 YIELD 36 HTTP://D-NB.INFO/1011200244 IMAGE 2 VIII CONTENTS 4.2.1 PLANT YIELD (OVERALL YIELD) 3 7 4.3 SELECTIVITY 3 7 4.3.1 CHEMOSELECTIVITY 3 7 4.3.2 REGIOSELECTIVITY 3 8 4.3.3 DIASTEREOSELECTIVITY 38 4.3.4 ENANTIOSELECTIVITY 3 9 4.4 OTHER I M P O R T A N T TARGET VALUES 4 0 4.4.1 SPACE-TIME YIELD (STY) 4 0 4.4.2 CATALYST LIFETIME 4 0 4.4.3 TURNOVER N U M B E R 4 1 4.4.4 TURNOVER FREQUENCY 4 2 4.4.5 PRODUCTIVITY 4 2 4.5 T H E CHOICE IS YOURS! 43 LITERATURE 46 5 BONDS, ELEMENTAL STEPS, A N D CATALYST CYCLES: BASICS O F ORGARIOMETALLIC CHEMISTRY 4 7 5.1 LIGANDS 4 7 5.2 C H A N G E I N OXIDATION STATE 5 0 5.3 C H A N G I N G O F COORDINATION N U M B E R (CN) A N D COORDINATION G E O M E T R Y 5 0 5.4 T H E ELEMENTARY STEPS 51 5.4.1 ASSOCIATION/DISSOCIATION 5 2 5.4.2 OXIDATIVE ADDITION/REDUCTIVE ELIMINATION 53 5.4.3 INSERTION/EXTRUSION 5 3 5.4.4 OXIDATIVE COUPLING (CYCLOADDITION)/REDUCTIVE CLEAVAGE (RETROCYCLOADDITION) 5 5 5.4.5 FURTHER ELEMENTARY STEPS 5 6 5.4.6 A REVIEW O F T H E ELEMENTARY STEPS 5 6 5.5 CATALYTIC CYCLES 5 7 LITERATURE 60 6 TRANSITION METAL COMPLEXES: THE CAPTAINS O F H O M O G E N E O U S CATALYSIS 63 6.1 G R O U P IIIB METALS A N D LANTHANIDES 63 6.2 METALS O F G R O U P IVB 64 6.3 METALS O F G R O U P S VB TO VIIB 64 6.4 T H E IRON METALS O F G R O U P VIII 6 5 6.5 T H E NOBLE METALS F R O M G R O U P VIII 6 5 6.5.1 R U T H E N I U M 66 6.5.2 O S M I U M 6 7 6.5.3 R H O D I U M 6 7 6.5.4 I R I D I U M 70 6.5.5 PALLADIUM 7 0 6.5.6 P L A T I N U M 72 6.6 GOLD: A NOBLE METAL F R O M G R O U P IB 72 6.7 T H E COST O F CATALYST METALS 72 IMAGE 3 CONTENTS IX 6.8 T H E AVAILABILITY O F TRANSITION METAL CATALYSTS 74- 6.9 A TYPICAL EXPERIMENT: SYNTHESIS O F PD(ACAC) 2 7 5 LITERATURE 76 7 THE COMPLEX LIGANDS: THE MATES O F H O M O G E N E O U S CATALYSIS 79 7.1 MONODENTATE LIGAND OR CHELATE? 79 7.2 BASICITY O F LIGANDS 8 2 7.3 CONE ANGLE ( TOLMAN C O N E ANGLE ) 83 . 7.4 T H E BITE ANGLE 8 8 7.5 COSTS A N D ACCESSIBILITY O F LIGANDS 91 7.6 A TYPICAL EXPERIMENT: T H E SYNTHESIS O F BIPHEPHOS 93 7.7 STABILITY O F LIGANDS 95 LITERATURE 98 8 THE SOLVENTS: T H E REACTION MEDIUM 101 8.1 CRITERIA FOR CHOOSING SOLVENTS 102 8.1.1 T H E DIELECTRIC CONSTANT (PERMITTIVITY) 102 8.1.2 DIPOLE M O M E N T 104 8.2 MISCIBILITY O F SOLVENTS 106 8.3 SOLVENTS AS ACTIVATORS 107 8.4 SOLVENTS AS DEACTIVATORS 108 8.5 AVAILABILITY A N D PURITY O F SOLVENTS 109 8.5.1 SOLVENT AVAILABILITY 109 8.5.2 SOLVENT PURITY 110 8.6 SPECIAL SOLVENTS 111 LITERATURE 112 9 ASYMMETRIC CATALYSIS: THE SPECIAL CASE 115 9.1 A GLOSSARY O F A S Y M M E T R I C CATALYSIS 115 9.1.1 PRELIMINARY INFORMATION 115 9.2 A Q U I C K LOOK BACK 119 9.3 MECHANISTIC CONSIDERATIONS 121 9.4 CHIRAL LIGANDS 125 9.5 OVERVIEW O N H O M O G E N E O U S CATALYZED A S Y M M E T R I C SYNTHESES 127 9.6 INDUSTRIAL APPLICATIONS 127 LITERATURE 131 10 THERMODYNAMICS O F H O M O G E N E O U S CATALYSIS: WHEN DOES A CHEMICAL REACTION RUN? 133 10.1 GIBBS ENERGY A N D ENERGY PLOT 133 10.2 CALCULATION O R A S S E S S M E N T O F T H E FREE REACTION ENTHALPY 135 10.3 T H E R M O D Y N A M I C ANALYSIS O F COMPLEX REACTION SYSTEMS 136 LITERATURE 139 * IMAGE 4 X CONTENTS 11 KINETICS O F H O M O G E N E O U S CATALYSIS: H O W DOES T H E REACTION PROCEED? 141 11.1 FREQUENTLY OCCURRING KINETICS 141 11.2 T H E ENERGY D I A G R A M FOR EXPLAINING REGIOSELECTIVITY 145 11.3 T H E ENERGY D I A G R A M FOR EXPLAINING ENANTIOSELECTIVITY 146 11.4 EXECUTION O F KINETIC M E A S U R E M E N T S 146 11.5 A CONCRETE EXAMPLE: T H E (ISOMERIZING) HYDROFORMYLATION O F OCTENES 147 11.6 POSSIBLE FAILURES I N KINETIC M E A S U R E M E N T S 149 LITERATURE 151 12 OVERVIEW O N SPECTROSCOPIC METHODS: CAN WE SEE INTO H O M O G E N E O U S CATALYSIS? 153 12.1 UV/VISIBLE SPECTROSCOPY 153 12.2 IR SPECTROSCOPY 155 12.3 N M R SPECTROSCOPY 157 12.3.1 N M R SPECTROSCOPY 157 12.3.2 N M R SPECTROSCOPY WITH PARA H Y D R O G E N 158 12.3.3 3 1 P N M R SPECTROSCOPY 159 12.4 MASS SPECTROSCOPY 162 12.5 EXTENDED X-RAY ABSORPTION FINE STRUCTURE ANALYSIS 163 12.6 INDUCTIVELY COUPLED PLASMA OPTICAL EMISSION SPECTROSCOPY (ICP-OES) 164 LITERATURE 166 PART II PROCESS ENGINEERING FUNDAMENTALS 169 13 REACTOR TYPES: WHERE DOES CATALYSIS OCCUR? 171 13.1 REACTIONS I N H O M O G E N E O U S LIQUID PHASE 171 13.1.1 STIRRED-TANK REACTOR 171 13.1.2 TUBULAR REACTOR 173 13.2 FLUID-FLUID SYSTEMS 174 13.2.1 SPARGED STIRRED-TANK REACTOR 174 13.2.2 BUBBLE C O L U M N REACTOR 175 13.2.3 LOOP REACTORS 175 13.2.4 JET TUBE REACTOR 175 13.2.5 REACTORS FOR GASEOUS PRODUCT STREAMS 176 13.2.6 FALLING FILM REACTOR 176 13.2.7 JET SCRUBBER 177 13.2.8 LIQUID RING P U M P A N D SPARGED TUBULAR REACTOR 177 13.3 T H E EMBARRAS D E RICHESSES 177 13.4 PRESSURE REACTORS 180 13.5 N E W TRENDS 182 LITERATURE 185 14 OVERVIEW O N CATALYST RECYCLING METHODS: IS MY CATALYST ECONOMICAL? 189 14.1 T H E PRINCIPLES O F SEPARATION 189 14.2 PRECIPITATION 193 IMAGE 5 . 2 . 1 . 2 . 2 .2.3 .2.4 .2.5 .2.6 .3 .4 . 1 .1.1 . 1 . 2 .2 . 2 . 1 . 2 . 2 .2.3 .3 .4 .1 . 2 .3 .1 .2 . 2 . 1 . 2 . 2 .2.3 .3 .4 . 1 . 2 .3 .4 CONTENTS XI C H E M I C A L PRECIPITATION 193 ADDITION O F A SOLVENT 194 REMOVAL O F A SOLVENT 194 ADDITION O F SPECIFIC PRECIPITANTS 194 T H E R M A L DEPOSITION O F A METAL CATALYST 195 TAGS 195 CRYSTALLIZATION 196 ADSORPTION 196 LITERATURE 199 THERMAL SEPARATION: THE SIMPLEST REMOVAL O F VOLATILE PRODUCTS 203 T H E BASICS 203 SEPARATION BY DISTILLATION O F T H E P R O D U C T 203 T H E R M A L DECOMPOSITION O F T H E CATALYST 203 EXAMPLE: HYDROFORMYLATION 204 T H E TRIAD PROCESS 204 T H E GAS RECYCLE PROCESS 205 T H E LIQUID RECYCLE PROCESS 206 EXAMPLE: OXIDATION O F ETHENE TO ACETALDEHYDE 207 EXAMPLE: CARBONYLATION O F METHANOL TO ACETIC ACID 2 0 9 LITERATURE 212 IMMOBILIZATION O N SOLID SUPPORTS: FRORIHOMOGENEOUS TO HETEROGENEOUS 213 T H E BASIC PRINCIPLE 213 ORGANIC SUPPORTS 2 I 4 INORGANIC ^TFGPBRTS 21S LITERATURE 21 LIQUID-LIQUID MULTIPHASE SYSTEMS: T H E SMART APPROACH T O CATALYST SEPARATION 223 VARIANTS OF LIQUID-LIQUID BIPHASIC (LLB) SYSTEMS 224 REACTION A N D SEPARATION 225 ORGANIC/ORGANIC BIPHASIC SYSTEMS 226 ORGANIC/AQUEOUS BIPHASIC SYSTEMS 2 2 7 MICELLAR CATALYSIS 232 REACTIONS WITH IN-SITU EXTRACTION 234 REACTIONS WITH POST EXTRACTION 235 LITERATURE 238 THERMOMORPHIC SOLVENT SYSTEMS: CLEVER ENHANCEMENTS 243 T H E R M O R E G U L A T E D PHASE-TRANSFER CATALYSIS 243 T H E R M O R E G U L A T E D MICROEMULSIONS 245 T H E R M O R E G U L A T E D FLUOROUS SOLVENT SYSTEMS 246 T H E R M O R E G U L A T E D POLYMER-BOUND CATALYSTS 248 IMAGE 6 XII CONTENTS 18.5 T H E R M O M O R P H I C M U L T I C O M P O N E N T SOLVENT SYSTEMS 251 18.5.1 FINDING A SUITABLE TMS SYSTEM 252 18.6 A RETROSPECTIVE LOOK AT CATALYST RECYCLING METHODS 2 5 3 LITERATURE 256 PART III HOMOGENEOUS CATALYZED REACTION TYPES 259 19 AN OVERVIEW O F C-C-BONDING REACTIONS: A GUIDE THROUGH T H E JUNGLE 263 LITERATURE 270 20 HYDROFORMYLATIONS: T H E INDUSTRIAL ROUTE T O ALDEHYDES A N D ALCOHOLS 273 20.1 SUBSTRATES 274 20.2 CATALYSTS 2 7 5 20.3 M E C H A N I S M S 2 7 7 20.4 , INDUSTRIAL PROCESSES 278 20.4.1 FIRST-GENERATION CATALYSTS (FROM ~ 1 9 5 0 ) 279 20.4.2 SECOND-GENERATION CATALYSTS (FROM ~ 1 9 6 0 ) 279 20.4.3 THIRD-GENERATION CATALYSTS (FROM ~1974) 2 8 0 20.4.4 FOURTH-GENERATION CATALYSTS (FROM ~ 1 9 8 4 ) 281 20.5 ASYMMETRIC HYDROFORMYLATION 281 20.6 A TYPICAL EXPERIMENT: HYDROFORMYLATION O F 1-OCTENE 2 8 2 LITERATURE 284 21 CARBONYLATIONS: THE VERSATILE INSERTIONS O F CARBON MONOXIDE 291 21.1 REACTIONS BETWEEN C O A N D H Y D R O G E N 291 21.2 REACTIONS O F C O WITH ALKENES A N D VINYL ARENES 2 9 2 21.3 REACTIONS O F C O WITH DIENES 293 21.4 REACTIONS O F C O WITH ALKYNES 2 9 5 21.5 REACTIONS O F C O W I T H ALCOHOLS 296 21.5.1 CARBONYLATION REACTIONS 2 9 7 21.5.2 HOMOLOGATION REACTIONS 298 21.6 A TYPICAL EXPERIMENT 298 LITERATURE 3 0 0 22 OLIGOMERIZATION A N D CYCLOOLIGOMERIZATION: THE CONVERSION O F UNSATURATED ALIPHATICS INTO SHORT CHAINS OR MEDIUM-SIZED RINGS 303 22.1 OLIGOMERIZATION O F ALKENES 3 0 3 22.1.1 ETHENE 303 22.1.2 PROPENE 308 22.1.3 O T H E R M O N O E N E S 3 1 0 22.2 DIENES 311 22.3 ALKYNES 313 22.4 COOLIGOMERIZATIONS 314 22.4.1 ETHENE A N D BUTADIENE 314 IMAGE 7 .4.2 .4.3 .5 .1 .2 .3 .1 .2 .3 .4 .5 .6 .7 .8 .9 .1 . 2 .2.1 .2.2 .2.3 .2.4 .2.5 .3 .4 .5 .1 .2 .3 .4 .5 .6 * 7 CONTENTS XIII E T H E N E A N D STYRENE (HYDROVINYLATION) 315 COOLIGOMERIZATIONS WITH ALKYNES 316 A TYPICAL EXPERIMENT 316 LITERATURE 318 METATHESIS: A CHANGE-YOUR-PARTNERS DANCE 323 MECHANISM A N D CATALYSTS 3 2 5 INDUSTRIAL APPLICATIONS 3 3 0 A TYPICAL EXPERIMENT: SELF METATHESIS O F 1-OCTENE 3 3 2 LITERATURE 334 POLYMERIZATIONS: THE PURPOSEFUL ASSEMBLY O F MACROMOLECULES 337 POLYETHYLENE A N D ZIEGLER CATALYSTS 337 POLYPROPYLENE A N D METALLOCENE CATALYSIS 341 FURTHER POLYOLEFINS 346 POLYDIENES 3 4 7 POLYKETONES 348 POLYALKYNES 349 POST-METALLOCENES 3 5 0 C U R R E N T TOPICS I N POLYMER RESEARCH 351 A TYPICAL EXPERIMENT 3 5 2 LITERATURE 354 TELOMERIZATIONS: THE CONSTRUCTION O F C 8 A N D C10 C H A I N S 359 REACTIONS, MECHANISMS, A N D CATALYSTS 359 BUTADIENE TELOMERIZATIONS 3 6 2 BUTADIENE A N D OXYGEN NUCLEOPHILES 363 BUTADIENE A N D NITROGEN NUCLEOPHILES 3 6 7 BUTADIENE A N D C A R B O N NUCLEOPHILES 368 CARBOXY TELOMERIZATION 368 CYCLIC TELOMERES 369 TELOMERIZATIONS WITH ISOPRENE 371 TELOMERIZATIONS I N LIQUID-LIQUID BIPHASIC SYSTEMS 3 7 2 A TYPICAL EXPERIMENT 3 74 LITERATURE 376 REACTIONS WITH CARBON DIOXIDE: THE ACTIVATION O F A N INACTIVE MOLECULE 381 CARBON DIOXIDE A N D ALKANES 3 8 2 CARBON DIOXIDE A N D ALKENES 383 CARBON DIOXIDE A N D DIENES 3 8 4 CARBON DIOXIDE A N D ALKYNES 387 CARBON DIOXIDE A N D AROMATICS 388 CARBON DIOXIDE A N D H Y D R O G E N 3 8 8 CARBON DIOXIDE A N D EPOXIDES 3 9 2 IMAGE 8 XIV CONTENTS 26.8 C A R B O N DIOXIDE A N D A M I N E S 393 26.9 C A R B O N DIOXIDE-CONTAINING POLYMERS 3 9 4 26.9.1 ALIPHATIC POLYCARBONATES CONTAINING C 0 2 A N D EPOXIDES 394 26.9.2 POLYPYRONES F R O M C 0 2 A N D DIYNES 394 26.9.3 C 0 2 - C O N T A I N I N G POLYESTERS O F DIYNES A N D DIHALIDES 395 26.9.4 AROMATIC POLYCARBONATES BASED O N C 0 2 3 9 5 26.10 A TYPICAL EXPERIMENT 396 LITERATURE 3 9 8 27 CARBON-CARBON COUPLING WITH AROMATICS: NEW N A M E REACTIONS 403 27.1 M I Z O R O K I - H E C K REACTIONS 404 27.2 S O N O G A S H I R A - H A G I H A R A REACTIONS 406 27.3 SUZUKI-MIYAURA REACTION 4 0 7 27.4 CROSS :COUPLINGS W I T H METAL ORGANYLES 4 0 9 27.5 A TYPICAL EXPERIMENT 411 LITERATURE 413 28 HYDROGENATIONS: C - H BOND FORMATION 419 28.1 CATALYSTS A N D M E C H A N I S M S 419 28.2 ASYMMETRIC HYDROGENATION 4 2 0 28.3 HYDROGENATION O F VARIOUS FUNCTIONAL G R O U P S 4 2 2 28.3.1 C - C MULTIPLE BONDS 4 2 2 28.3.2 C = 0 DOUBLE BONDS 4 2 4 28.3.3 C = N DOUBLE BONDS 426 28.4 TECHNICAL APPLICATIONS 426 28.4.1 (S)-METOLACHLOR 4 2 7 28.4.2 L D O P A 4 2 8 28.4.3 ASPARTAME 428 28.4.4 NAPROXEN 428 28.4.5 INDINAVIR 429 28.4.6 C A R B A P E N E M 429 28.4.7 BIOTIN 429 28.4.8 PRODUCTION O F CYCLOHEXANE 429 28.5 A TYPICAL EXPERIMENT 431 LITERATURE 432 29 OXIDATIONS: FORMATION O F C - O BONDS 4 3 7 29.1 WACKER OXIDATIONS 4 3 7 29.2 EPOXIDATIONS 4 4 0 29.3 ASYMMETRIC DIHYDROXYLATIONS 444 29.4 OXIDATIVE CLEAVAGE O F C = C DOUBLE BONDS 4 4 4 29.5 OXIDATIONS O F ALKYL AROMATICS 446 29.6 A TYPICAL EXPERIMENT 448 LITERATURE 449 IMAGE 9 30 30.1 30.2 30.3 30.4 30.5 30.6 30.7 31 31.1 31.1.1 31.1.2 31.2 31.3 31.4 PART IV 32 32.1 32.2 32.3 32.3.1 32.3.2 32.3.3 32.3.4 32.3.4.1 32.3.4.2 32.3.4.3 32.4 33 33.1 33.2 33.3 CONTENTS XV AMINATIONS: FORMATION O F C - N BONDS 4 5 5 ANIMATION O F ARYL HALIDES 4 5 5 HYDROAMINATION O F ALKENES 458 HYDROAMINATIONS O F DIENES 461 HYDROAMINATION O F ALKYNES 462 AMINATION O F FUNCTIONAL G R O U P S 4 6 2 .. .SOME MORE A M I N A T I O N S 4 6 3 A TYPICAL EXPERIMENT 464 LITERATURE 466 ISOMERIZATIONS: MIGRATION O F DOUBLE BONDS A N D REARRANGEMENT O F T H E CARBON BACKBONE 473 ISOMERIZATION O F ALKENES 4 7 3 T H E ALKYL M E C H A N I S M 474 T H E ALLYLIC M E C H A N I S M 4 7 4 ISOMERIZATION O F SUBSTITUTED ALKENES 4 7 5 R E A R R A N G E M E N T O F T H E BACKBONE 478 A TYPICAL EXPERIMENT 4 7 9 LITERATURE 4 8 0 NEW TRENDS 485 TANDEM REACTIONS: MULTIPLE SYNTHESIS STEPS IN O N E POT 4 8 7 MULTICOMPONENT REACTIONS 488 MULTIFUNCTIONAL CATALYSIS 489 T A N D E M A N D RELATED REACTIONS 491 ONE-POT REACTIONS 4 9 2 D O M I N O REACTIONS 493 CASCADE O R Z I P REACTIONS 493 T A N D E M REACTIONS 4 9 4 ORTHOGONAL T A N D E M CATALYSIS 4 9 4 AUTO-TANDEM REACTIONS 4 9 5 ASSISTED T A N D E M CATALYSIS 4 9 6 A TYPICAL EXPERIMENT 4 9 7 LITERATURE 5 0 0 COMBINATORIAL CHEMISTRY A N D HIGH-THROUGHPUT CATALYST SCREENING: THE FAST WAY T O O P T I M U M RESULTS 5 0 7 BASICS A N D DEFINITIONS 5 0 7 PARALLEL REACTOR SYSTEMS 5 0 9 SEQUENTIAL REACTOR SYSTEMS 514 LITERATURE 517 34 34.1 34.2 GREEN SOLVENTS: WORKING WITH ECO-FRIENDLY SOLVENTS 521 IONIC LIQUIDS 521 SUPERCRITICAL FLUIDS 526 IMAGE 10 XVI CONTENTS 34.3 FLUOROUS SOLVENTS 5 2 9 34.4 POLYETHERS 530 34.5 CONCLUSIONS 531 LITERATURE 533 35 ALKANE ACTIVATIONS: ACQUISITIONS O F NEW FEEDSTOCKS 541 35.1 MECHANISTIC CONSIDERATIONS 5 4 2 35.2 ALKANE OXIDATIONS 543 35.3 ALKANE CARBONYLATIONS 545 35.4 ALKANE METATHESIS 545 35.5 ALKANE HYDROGENOLYSIS 546 35.6 ALKANE BORYLATION 546 35.7 ALKANE SULFONATION 547 35.8 A LOOK BACK 547 LITERATURE 548 36 MORE EFFICIENT LIGANDS: THE BEST IS T H E ENEMY O F T H E GOOD 553 36.1 NITROGEN-CONTAINING LIGANDS 554 36.2 U N U S U A L P H O S P H O R U S LIGANDS 556 36.3 LIGANDS CONTAINING ELEMENTS F R O M G R O U P VIA 5 5 7 36.4 LIGANDS CONTAINING ELEMENTS F R O M G R O U P IVA 559 LITERATURE 5 6 2 37 NANOCATALYSIS: BETWEEN H O M O G E N E O U S A N D HETEROGENEOUS CATALYSIS 569 37.1 SYNTHESIS A N D PROPERTIES O F NANOCATALYSTS 5 6 9 37.2 STABILIZATION O F NANOPARTICLES 571 37.3 HETEROGENIZATION O F NANOPARTICLES O N SOLID SUPPORTS 574 37.4 CATALYSIS INVOLVING METAL NANOPARTICLES 574 LITERATURE 576 38 H O M O G E N E O U S CATALYSIS WITH RENEWABLES: USING NATURE S TREASURES 583 38.1 CATALYTIC CONVERSION O F FATTY C O M P O U N D S 585 38.1.1 CATALYTIC FUNCTIONALIZATION O F UNSATURATED FATTY C O M P O U N D S 586 38.1.1.1 SELECTIVE HYDROGENATIONS 586 38.1.1.2 HYDROFORMYLATION 586 38.1.1.3 HYDROAMINOMETHYLATION 5 8 7 38.1.2 CATALYTIC OLIGOMERIZATION O F U N S A T U R A T E D FATS 587 38.1.3 CATALYTIC OXIDATION O F U N S A T U R A T E D FATTY C O M P O U N D S 588 38.1.4 CATALYTIC METATHESIS O F U N S A T U R A T E D FATTY C O M P O U N D S 589 38.1.5 CATALYTIC DERIVATIZATION O F GLYCEROL 591 38.2 CATALYTIC REACTIONS O F CARBOHYDRATES 593 38.3 CATALYTIC REACTIONS O F TERPENES 594 LITERATURE 5 9 7 IMAGE 11 CONTENTS XVII 39 ELECTROCATALYSIS/SONOCATALYSIS/PHOTOCATALYSIS/MICROWAVE/EXTREME PRESSURE: ALTERNATIVE METHODS O F ACTIVATION 603 39.1 ELECTROCATALYSIS 603 39.2 PHOTOCATALYSIS 605 39.3 SONOCATALYSIS 606 39.4 MICROWAVE CATALYSIS 608 39.5 EXTREME HIGH-PRESSURE CATALYSIS 611 LITERATURE 613 40 PROCESS DEVELOPMENT IN MINIPLANTS: FROM LABORATORY T O PRODUCTION 621 40.1 MINIPLANT WITH CONTINUOUSLY STIRRED-TANK REACTOR (MINIPLANT I) 622 40.2 MINIPLANT WITH LOOP REACTOR A N D PHASE SEPARATOR (MINIPLANT II) 623 40.3 MINIPLANT WITH JETLOOP REACTOR A N D PHASE SEPARATOR (MINIPLANT III) 626 40.4 MINIPLANT WITH A MIXER-SETTLER BATTERY (MINIPLANT IV) 628 LITERATURE 631 41 THE FUTURE O F H O M O G E N E O U S CATALYSIS: A LOOK AHEAD 633 41.1 N E W RESOURCES 633 41.1.1 CARBON DIOXIDE 634 41.1.2 RENEWABLE RESOURCES 635 41.1.3 FATS A N D OILS 635 41.1.4 CARBOHYDRATES 637 41.1.5 BIOREFINERIES 6 3 7 41.2 N E W REACTIONS 638 41.2.1 SELECTIVE OXIDATIONS 639 41.2.2 ASYMMETRIC REACTIONS 639 41.2.3 T A N D E M REACTIONS 640 41.2.4 POLYMERIZATIONS 640 41.2.5 N E W CATALYTIC REACTIONS 641 41.2.6 ENVIRONMENT-FRIENDLY PROCESSES 641 41.3 N E W CATALYSTS 641 41.4 N E W METHODS 643 LITERATURE 644 ANSWERS T O T H E QUICKIES 645 INDEX 669
any_adam_object	1
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id	DE-604.BV037492546
illustrated	Illustrated
indexdate	2024-12-20T15:18:05Z
institution	BVB
isbn	9783527326334 3527326332 9783527326419
language	English
oai_aleph_id	oai:aleph.bib-bvb.de:BVB01-022643829
oclc_num	725141718
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owner	DE-29T DE-634 DE-703 DE-11 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-355 DE-BY-UBR DE-83
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physical	XXVIII, 688 S. Ill., graph. Darst.
publishDate	2012
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publisher	Wiley-VCH
record_format	marc
spellingShingle	Behr, Arno 1952- Neubert, Peter 1981- Applied homogeneous catalysis Angewandte Chemie (DE-588)4216597-0 gnd Homogene Katalyse (DE-588)4160579-2 gnd Technische Chemie (DE-588)4078178-1 gnd
subject_GND	(DE-588)4216597-0 (DE-588)4160579-2 (DE-588)4078178-1
title	Applied homogeneous catalysis
title_auth	Applied homogeneous catalysis
title_exact_search	Applied homogeneous catalysis
title_full	Applied homogeneous catalysis Arno Behr and Peter Neubert
title_fullStr	Applied homogeneous catalysis Arno Behr and Peter Neubert
title_full_unstemmed	Applied homogeneous catalysis Arno Behr and Peter Neubert
title_short	Applied homogeneous catalysis
title_sort	applied homogeneous catalysis
topic	Angewandte Chemie (DE-588)4216597-0 gnd Homogene Katalyse (DE-588)4160579-2 gnd Technische Chemie (DE-588)4078178-1 gnd
topic_facet	Angewandte Chemie Homogene Katalyse Technische Chemie
url	http://deposit.dnb.de/cgi-bin/dokserv?id=3718058&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022643829&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT behrarno appliedhomogeneouscatalysis AT neubertpeter appliedhomogeneouscatalysis

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