Cold aqueous planetary geochemistry with FREZCHEM: from modeling to the search for life at the limits ; with 33 tables
Gespeichert in:
Beteiligte Personen: | , |
---|---|
Format: | Buch |
Sprache: | Englisch |
Veröffentlicht: |
Berlin ; Heidelberg
Springer
2008
|
Schriftenreihe: | Advances in astrobiology and biogeophysics
|
Schlagwörter: | |
Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018956973&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
Beschreibung: | Literaturverz. S. 223 - 245 |
Umfang: | X, 251 S. Ill., graph. Darst. 24 cm |
ISBN: | 9783540756781 3540756787 |
Internformat
MARC
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245 | 1 | 0 | |a Cold aqueous planetary geochemistry with FREZCHEM |b from modeling to the search for life at the limits ; with 33 tables |c Giles M. Marion ; Jeffrey S. Kargel |
264 | 1 | |a Berlin ; Heidelberg |b Springer |c 2008 | |
300 | |a X, 251 S. |b Ill., graph. Darst. |c 24 cm | ||
336 | |b txt |2 rdacontent | ||
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Datensatz im Suchindex
_version_ | 1819327338219831296 |
---|---|
adam_text | Contents
1
Introduction
.............................................. 1
2
Aqueous Chemistry
....................................... 3
2.1
Basic Principles
........................................ 3
2.1.1
Definitions
...................................... 3
2.1.2
The First and Second Laws of Thermodynamics
...... 4
2.1.3
Activities, Chemical Potentials and Equilibrium
Constants
....................................... 7
2.2
Pitzer Approach
........................................ 10
2.2.1
The Osmotic Coefficient and Activity Coefficients
.... 10
2.2.2
Temperature and Pressure Dependencies
............ 15
3
The FREZCHEM Model
................................. 19
3.1
Historical Development
.................................. 19
3.2
Basic Structure
........................................ 21
3.2.1
Chemical Equilibrium
............................. 21
3.2.2
Mass Balances
................................... 22
3.2.3
Reaction Pathways
............................... 22
3.3
Chemistries and Their Temperature and Pressure Dependence
24
3.3.1
Water Ice/Liquid Water/Water Vapor Equilibria
..... 24
3.3.2
Salt Equilibria
................................... 29
3.3.3
Gas/Solution Phase Equilibria
..................... 37
3.3.4
Gas Hydrate Equilibria
........................... 42
3.4
Mathematical Algorithms
................................ 49
3.4.1
The Sequential Approach
.......................... 49
3.4.2
Gibbs Energy Minimization
........................ 50
3.4.3
Other Mathematical Techniques
.................... 52
3.5
Validation
............................................. 56
3.6
Limitations
............................................ 67
3.6.1
Pitzer-Equation Parameterization Limitations
........ 68
3.6.2
Modeling Limitations
............................. 75
4
Limits for Life
............................................ 79
4.1
Temperature
........................................... 84
4.2
Salinity
............................................... 86
X
Contents
4.3
Acidity
................................................ 88
4.4
Desiccation
............................................ 89
4.5
Radiation
............................................. 89
4.6
Pressure
............................................... 90
4.7
Time
................................................. 97
5
Biogeochemical Applications to Solar System Bodies
.....101
5.1
Earth
.................................................102
5.1.1
Seawater Freezing
................................102
5.1.2
Aqueous Saline Environments
......................110
5.1.3
Snowball Earth-Hothouse Earth
....................113
5.1.4
Why Are Clouds not Green?
.......................120
5.1.5
Other Earth Applications
.........................123
5.2
Mars
..................................................125
5.2.1
Surficial Aqueous Geochemical Evolution
............125
5.2.2
Early Mars Oceans
...............................135
5.2.3
A Cold, Intermittently Wet Mars
...................135
5.2.4
Hydrate Deposits and Thermal Stratification
........139
5.3 Europa................................................141
5.3.1
Ocean Compositions
..............................142
5.3.2
Ice Compositions
.................................148
5.4
Application Limitations
.................................150
6
The Search for and Future of Life in the Universe
........155
6.1
A Search Strategy for Life in the Universe
.................155
6.2 Entropie
Death?
........................................158
6.3
Solar System Life
.......................................162
6.4
To the Stars or Bust?
...................................169
A FREZCHEM Program Guide
.............................175
A.I Model Input Limitations
................................175
A.2 Model Inputs
..........................................176
A.3 Model Outputs
.........................................177
A.
3.1
Seawater Freezing
................................177
A.3.2 Strong Acid
.....................................178
A.3.3 Gas Hydrates
....................................178
A.
3.4
Pressure Application
..............................179
В
Parameter Tables
.........................................193
References
....................................................223
Index
.........................................................247
|
any_adam_object | 1 |
author | Marion, Giles M. Kargel, Jeffrey S. |
author_GND | (DE-588)1219875902 |
author_facet | Marion, Giles M. Kargel, Jeffrey S. |
author_role | aut aut |
author_sort | Marion, Giles M. |
author_variant | g m m gm gmm j s k js jsk |
building | Verbundindex |
bvnumber | BV036065591 |
classification_rvk | VE 9600 |
ctrlnum | (OCoLC)633942152 (DE-599)DNB986030090 |
discipline | Chemie / Pharmazie Biologie |
format | Book |
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id | DE-604.BV036065591 |
illustrated | Illustrated |
indexdate | 2024-12-20T14:06:01Z |
institution | BVB |
isbn | 9783540756781 3540756787 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-018956973 |
oclc_num | 633942152 |
open_access_boolean | |
owner | DE-355 DE-BY-UBR |
owner_facet | DE-355 DE-BY-UBR |
physical | X, 251 S. Ill., graph. Darst. 24 cm |
publishDate | 2008 |
publishDateSearch | 2008 |
publishDateSort | 2008 |
publisher | Springer |
record_format | marc |
series2 | Advances in astrobiology and biogeophysics |
spellingShingle | Marion, Giles M. Kargel, Jeffrey S. Cold aqueous planetary geochemistry with FREZCHEM from modeling to the search for life at the limits ; with 33 tables Außerirdisches Leben (DE-588)4003864-6 gnd Geochemie (DE-588)4020198-3 gnd Elektrochemisches System (DE-588)4151771-4 gnd Aquatisches Ökosystem (DE-588)4293663-9 gnd Tieftemperatur (DE-588)4134801-1 gnd Mathematisches Modell (DE-588)4114528-8 gnd |
subject_GND | (DE-588)4003864-6 (DE-588)4020198-3 (DE-588)4151771-4 (DE-588)4293663-9 (DE-588)4134801-1 (DE-588)4114528-8 |
title | Cold aqueous planetary geochemistry with FREZCHEM from modeling to the search for life at the limits ; with 33 tables |
title_auth | Cold aqueous planetary geochemistry with FREZCHEM from modeling to the search for life at the limits ; with 33 tables |
title_exact_search | Cold aqueous planetary geochemistry with FREZCHEM from modeling to the search for life at the limits ; with 33 tables |
title_full | Cold aqueous planetary geochemistry with FREZCHEM from modeling to the search for life at the limits ; with 33 tables Giles M. Marion ; Jeffrey S. Kargel |
title_fullStr | Cold aqueous planetary geochemistry with FREZCHEM from modeling to the search for life at the limits ; with 33 tables Giles M. Marion ; Jeffrey S. Kargel |
title_full_unstemmed | Cold aqueous planetary geochemistry with FREZCHEM from modeling to the search for life at the limits ; with 33 tables Giles M. Marion ; Jeffrey S. Kargel |
title_short | Cold aqueous planetary geochemistry with FREZCHEM |
title_sort | cold aqueous planetary geochemistry with frezchem from modeling to the search for life at the limits with 33 tables |
title_sub | from modeling to the search for life at the limits ; with 33 tables |
topic | Außerirdisches Leben (DE-588)4003864-6 gnd Geochemie (DE-588)4020198-3 gnd Elektrochemisches System (DE-588)4151771-4 gnd Aquatisches Ökosystem (DE-588)4293663-9 gnd Tieftemperatur (DE-588)4134801-1 gnd Mathematisches Modell (DE-588)4114528-8 gnd |
topic_facet | Außerirdisches Leben Geochemie Elektrochemisches System Aquatisches Ökosystem Tieftemperatur Mathematisches Modell |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018956973&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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