Verfügbarkeit: Biophysical chemistry | Technische Universität München

Biophysical chemistry:

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Bibliographische Detailangaben
Beteilige Person:	Allen, James P. (VerfasserIn)
Format:	Buch
Sprache:	Englisch
Veröffentlicht:	Oxford [u.a.] Wiley-Blackwell 2008
Ausgabe:	1. ed.
Schlagwörter:	Biochemistry Biophysics Chemistry, Physical Physical biochemistry Biophysikalische Chemie Lehrbuch
Links:	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016274848&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016274848&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA
Umfang:	XVI, 492 S. Ill., graph. Darst.
ISBN:	9781405124362

Internformat

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245	1	0	\|a Biophysical chemistry \|c James P. Allen
250			\|a 1. ed.
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300			\|a XVI, 492 S. \|b Ill., graph. Darst.
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520	1		\|a "Biophysical Chemistry presents physical chemistry through the use of biological and biochemical topics, examples, and applications to biochemistry. It presents a rigorous, up-to-date treatment of the material without presuming a strong prior knowledge of math theory. Necessary calculus models are laid out in a step-by-step fashion for students less confident in their math abilities. The format of the text allows teachers ample flexibility in deciding which derivations to present in class. Students are guided through an in-depth understanding of fundamental concepts. Every chapter features important recent advances in biochemistry, an examination of current research problems, math and derivation boxes to guide the students, and examples of both numerical and concept-based problems."--BOOK JACKET.
650		4	\|a Biochemistry
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Datensatz im Suchindex

DE-BY-TUM_call_number	0302 CHE 802f 2010 A 828
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adam_text	Contents Preface xv 1 Basic thermodynamic and biochemical concepts I Fundamental thermodynamic concepts 2 States of matter 2 Pressure 2 Temperature 5 Volume, mass, and number 6 Properties of gases 6 The ideal gas laws 6 Gas mixtures 8 Kinetic energy of gases 9 Real gases 9 Derivation box 1.1 Relationship between the average velocity and pressure 10 Liquifying gases for low-temperature spectroscopy 12 Molecular basis for life 13 Cell membranes 14 Amino acids 15 Classification of amino acids by their side chains 15 DNA and RNA 18 Problems 20 Part 1: Thermodynamics and kinetics 21 2 First law of thermodynamics 23 Systems 23 State functions 25 First law of thermodynamics 26 Research direction: drug design I 27 Work 29 Specific heat 31 Internal energy for an ideal gas 31 Enthalpy 33 VIU CONTENTS Dependence of specific heat on internal energy and enthalpy 34 Derivation box 2.1 State functions described using partial derivatives 34 Enthalpy changes of biochemical reactions 38 Research direction: global climate change 40 References 44 Problems 45 3 Second law of thermodynamics 46 Entropy 47 Entropy changes for reversible and irreversible processes 49 The second law of thermodynamics 51 Interpretation of entropy 52 Third law of thermodynamics 53 Gibbs energy 54 Relationship between the Gibbs energy and the equilibrium constant 55 Research direction: drug design Π 56 Gibbs energy for an ideal gas 58 Using the Gibbs energy 59 Carnot cycle and hybrid cars 60 Derivation box 3.1 Entropy as a state function 63 Research direction: nitrogen fixation 66 References 69 Problems 69 4 Phase diagrams, mixtures, and chemical potential 71 Substances may exist in different phases 71 Phase diagrams and transitions 72 Chemical potential 73 Properties of lipids described using the chemical potential 74 Lipid and detergent formation into micelles and bilayers 75 Research direction: lipid rafts 77 Determination of micelle formation using surface tension 79 Mixtures 82 Raoult s law 85 Osmosis 88 Research direction: protein crystallization 88 References 92 Problems 92 5 Equilibria and reactions involving protons 94 Gibbs energy minimum 94 Derivation box 5.1 Relationship between the Gibbs energy and equilibrium constant 95 Response of the equilibrium constant to condition changes 98 Acid-base equilibria 99 Protonation states of amino acid residues 105 CONTENTS ÍX Buffers 106 Buffering in the cardiovascuiar system 108 Research direction: proton-coupled electron transfer and pathways 108 References 111 Problems 112 Oxidation/reduction reactions and bioenergetics 114 Oxidation/reduction reactions 114 Electrochemical cells 115 The Nernst equation 116 Midpoint potentials 117 Gibbs energy of formation and activity 120 Ionic strength 122 Adenosine triphosphate 123 Chemiosmotic hypothesis 124 Research direction: respiratory chain 126 Research direction: ATP synthase 128 References 131 Problems 132 Kinetics and enzymes 134 The rate of a chemical reaction 134 Parallel first-order reactions 137 Sequential first-order reactions 139 Second-order reactions 140 The order of a reaction 141 Reactions that approach equilibrium 142 Activation energy 143 Research direction: electron transfer I: energetics 144 Derivation box 7.1 Derivation of the Marcus relationship 146 Enzymes 147 Enzymes lower the activation energy 148 Enzyme mechanisms 150 Research direction: dynamics in enzyme mechanism 150 Michaelis-Menten mechanism 151 Lineweaver-Burk equation 155 Enzyme activity 155 Research direction: the RNA world 158 References 160 Problems 161 The Boltzmann distribution and statistical thermodynamics 163 Probability 163 Boltzmann distribution 165 Partition function 166 CONTENTS Statistical thermodynamics 167 Research direction: protein folding and prions 168 Prions 169 References 171 Problems 171 Part 2: Quantum mechanics and spectroscopy 173 9 Quantum theory: introduction and principles 175 Classical concepts 175 Experimental failures of classical physics 177 Blackbody radiation 177 Photoelectric effect 180 Atomic spectra 180 Principles of quantum theory 182 Wave-particle duality 182 Schrödinger s equation 184 Born interpretation 188 General approach for solving Schrödinger s equation 190 Interpretation of quantum mechanics 191 Heisenberg Uncertainty Principle 192 A quantum-mechanical world 193 Research direction: Schrödinger s cat 194 References 195 Problems 196 10 Particle in a box and tunneling 198 One-dimensional particle in a box 198 Properties of the solutions 200 Energy and wavefunction 200 Symmetry 201 Wavelength 202 Probability 202 Orthogonality 203 Average or expectation value 203 Transitions 204 Research direction: carotenoids 205 Two-dimensional particle in a box 207 Tunneling 209 Research direction: probing biological membranes 211 Research direction: electron transfer II: distance dependence 215 References 218 Problems 218 CONTENTS Xi 11 Vibrational motion and infrared spectroscopy 221 Simple harmonic oscillator: classical theory 221 Potential energy for the simple harmonic oscillator 223 Simple harmonic oscillator: quantum theory 223 Derivation box 11.1 Solving Schrödinger s equation for the simple harmonic oscillator 224 Properties of the solutions 225 Forbidden region 228 Transitions 229 Vibrational spectra 230 Research direction: hydrogenase 232 References 235 Problems 235 12 Atomic structure: hydrogen atom and multi-electron atoms 238 Schrödinger s equation for the hydrogen atom 238 Derivation box 12.1 Solving Schrödinger s equation for the hydrogen atom 239 Separation of variables 239 Angular solution 240 Radial solution 243 Properties of the general solution 244 Angular momentum 246 Orbitals 247 s Orbitals 247 ρ Orbitals 251 d Orbitals 252 Transitions 253 Research direction: hydrogen economy 254 Spin 257 Derivation box 12.2 Relativistic equations 258 Multi-electron atoms 260 Empirical constants 260 Self-consistent field theory (Hartree-Fock) 261 Helium atom 262 Spin-orbital coupling 264 Periodic table 265 References 267 Problems 267 13 Chemical bonds and protein interactions 270 Schrödinger s equation for a hydrogen molecule 270 Valence bonds 275 The Hückel model 276 Interactions in proteins 276 ХИ CONTENTS Peptide bonds 278 Steric effects 278 Hydrogen bonds 279 Electrostatic interactions 280 Hydrophobie effects 280 Secondary structure 282 Determination of secondary structure using circular dichroism 284 Research direction: modeling protein structures and folding 284 References 289 Problems 289 14 Electronic transitions and optical spectroscopy 291 The nature of light 291 The Beer-Lambert law 293 Measuring absorption 294 Transitions 296 Derivation box 14.1 Relationship between the Einstein coefficient and electronic states 298 Lasers 300 Selection rules 301 The Franck-Condon principle 302 The relationship between emission and absorption spectra 303 The yield of fluorescence 305 Fluorescence resonance energy transfer 306 Measuring fluorescence 306 Phosphorescence 307 Research direction: probing energy transfer using two-dimensional optical spectroscopy 307 Research direction: single-molecule spectroscopy 310 Holliday junctions 312 References 315 Problems 315 15 X-ray diffraction and extended X-ray absorption fine structure 317 Bragg s law 319 Bravais lattices 320 Protein crystals 322 Diffraction from crystals 323 Derivation box 15.1 Phases of complex numbers 325 Phase determination 328 Molecular replacement 328 Isomorphous replacement 329 Anomalous dispersion 329 Model building 33 j Experimental measurement of X-ray diffraction 332 CONTENTS Xl« Examples of protein structures 335 Research direction: nitrogenase 336 Extended X-ray absorption fine structure 339 References 342 Problems 342 16 Magnetic resonance 344 NMR 344 Chemical shifts 347 Spin-spin interactions 348 Pulse techniques 349 Two-dimensional NMR: nuclear Overhauser effect 351 NMR spectra of amino acids 352 Research direction: development of new NMR techniques 352 Détermination of macromolecular structures 357 Research direction: spinal muscular atrophy 357 MRI 360 Electron spin resonance 362 Hyperfine structure 365 Electron nuclear double resonance 365 Spin probes 366 Research direction: heme proteins 367 Research direction: ribonucleotide reducíase 369 References and further reading 370 Problems 371 Part 3: Understanding biological systems using physical chemistry 373 17 Signal transduction 375 Biochemical pathway for visual response 375 Spectroscopic studies of rhodopsin 377 Bacteriorhodopsin 378 Structural studies 380 Comparison of rhodopsins from different organisms 384 Rhodopsin proteins in visual response 387 References and further reading 387 Problems 388 18 Membrane potentials, transporters, and channels 390 Membrane potentials 390 Energetics of transport across membranes 391 Transporters 394 Ion channels 397 References and further reading 402 Problems 403 XIV CONTENTS 19 Molecular imaging 405 Imaging in cells and bodies 405 Green fluorescent protein 405 Mechanism of chromophore formation 408 Fluorescence resonance energy transfer 410 Imaging of GFP in cells 412 Imaging in organisms 414 Radioactive decay 415 PET 416 Parkinson s disease 418 References and further reading 419 Problems 419 20 Photosynthesis 421 Energy transfer and light-harvesting complexes 423 Electron transfer, bacterial reaction centers, and photosystem I 425 Water oxidation 430 References and further reading 436 Problems 437 Answers to problems 439 Index 488 Fundamental constants 493 Conversion factors for energy units 493 The periodic table 494 Short contents Preface xv 1 Basic thermodynamic and biochemical concepts 1 Part 1: Thermodynamics and kinetics 21 2 First law of thermodynamics 23 3 Second law of thermodynamics 46 4 Phase diagrams, mixtures, and chemical potential 71 5 Equilibria and reactions involving protons 94 6 Oxidation/reduction reactions and bioenergetics 114 7 Kinetics and enzymes 134 8 The Boltzmann distribution and statistical thermodynamics 163 Part 2: Quantum mechanics and spectroscopy 173 9 Quantum theory: introduction and principles 175 10 Particle in a box and tunneling 198 11 Vibrational motion and infrared spectroscopy 221 12 Atomic structure: hydrogen atom and multi-electron atoms 238 13 Chemical bonds and protein interactions 270 14 Electronic transitions and optical spectroscopy 291 15 X-ray diffraction and extended X-ray absorption fine structure 317 16 Magnetic resonance 344 Part 3: Understanding biological systems using physical chemistry 373 17 Signal transduction 375 18 Membrane potentials, transporters, and channels 390 19 Molecular imaging 405 20 Photosynthesis 421 Answers to problems 439 Index 488 Fundamental constants 49 3 Conversion factors for energy units 493 The periodic table 494
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spellingShingle	Allen, James P. Biophysical chemistry Biochemistry Biophysics Chemistry, Physical Physical biochemistry Biophysikalische Chemie (DE-588)4291844-3 gnd
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title	Biophysical chemistry
title_auth	Biophysical chemistry
title_exact_search	Biophysical chemistry
title_full	Biophysical chemistry James P. Allen
title_fullStr	Biophysical chemistry James P. Allen
title_full_unstemmed	Biophysical chemistry James P. Allen
title_short	Biophysical chemistry
title_sort	biophysical chemistry
topic	Biochemistry Biophysics Chemistry, Physical Physical biochemistry Biophysikalische Chemie (DE-588)4291844-3 gnd
topic_facet	Biochemistry Biophysics Chemistry, Physical Physical biochemistry Biophysikalische Chemie Lehrbuch
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