Biophysical chemistry:
Gespeichert in:
Beteilige Person: | |
---|---|
Format: | Buch |
Sprache: | Englisch |
Veröffentlicht: |
Oxford [u.a.]
Wiley-Blackwell
2008
|
Ausgabe: | 1. ed. |
Schlagwörter: | |
Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016274848&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016274848&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
Umfang: | XVI, 492 S. Ill., graph. Darst. |
ISBN: | 9781405124362 |
Internformat
MARC
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100 | 1 | |a Allen, James P. |e Verfasser |4 aut | |
245 | 1 | 0 | |a Biophysical chemistry |c James P. Allen |
250 | |a 1. ed. | ||
264 | 1 | |a Oxford [u.a.] |b Wiley-Blackwell |c 2008 | |
300 | |a XVI, 492 S. |b Ill., graph. Darst. | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
520 | 1 | |a "Biophysical Chemistry presents physical chemistry through the use of biological and biochemical topics, examples, and applications to biochemistry. It presents a rigorous, up-to-date treatment of the material without presuming a strong prior knowledge of math theory. Necessary calculus models are laid out in a step-by-step fashion for students less confident in their math abilities. The format of the text allows teachers ample flexibility in deciding which derivations to present in class. Students are guided through an in-depth understanding of fundamental concepts. Every chapter features important recent advances in biochemistry, an examination of current research problems, math and derivation boxes to guide the students, and examples of both numerical and concept-based problems."--BOOK JACKET. | |
650 | 4 | |a Biochemistry | |
650 | 4 | |a Biophysics | |
650 | 4 | |a Chemistry, Physical | |
650 | 4 | |a Physical biochemistry | |
650 | 0 | 7 | |a Biophysikalische Chemie |0 (DE-588)4291844-3 |2 gnd |9 rswk-swf |
655 | 7 | |0 (DE-588)4123623-3 |a Lehrbuch |2 gnd-content | |
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943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-016274848 |
Datensatz im Suchindex
DE-BY-TUM_call_number | 0302 CHE 802f 2010 A 828 |
---|---|
DE-BY-TUM_katkey | 1716886 |
DE-BY-TUM_location | 03 |
DE-BY-TUM_media_number | 040030234263 |
_version_ | 1821933806132658176 |
adam_text | Contents
Preface
xv
1
Basic thermodynamic
and biochemical concepts I
Fundamental thermodynamic
concepts
2
States
of matter
2
Pressure
2
Temperature
5
Volume,
mass, and number
6
Properties of gases
6
The ideal gas laws
6
Gas mixtures
8
Kinetic energy of gases
9
Real gases
9
Derivation box
1.1
Relationship between the average velocity and pressure
10
Liquifying gases for low-temperature spectroscopy
12
Molecular basis for life
13
Cell membranes
14
Amino
acids
15
Classification of
amino
acids by their side chains
15
DNA
and
RNA
18
Problems
20
Part
1:
Thermodynamics and kinetics
21
2
First law of thermodynamics
23
Systems
23
State functions
25
First law of thermodynamics
26
Research direction: drug design I
27
Work
29
Specific heat
31
Internal energy for an ideal gas
31
Enthalpy
33
VIU
CONTENTS
Dependence of specific heat on internal energy and enthalpy
34
Derivation box
2.1
State functions described using partial derivatives
34
Enthalpy changes of biochemical reactions
38
Research direction: global climate change
40
References
44
Problems
45
3
Second law of thermodynamics
46
Entropy
47
Entropy changes for reversible and irreversible processes
49
The second law of thermodynamics
51
Interpretation of entropy
52
Third law of thermodynamics
53
Gibbs energy
54
Relationship between the Gibbs energy and the equilibrium constant
55
Research direction: drug design
Π
56
Gibbs energy for an ideal gas
58
Using the Gibbs energy
59
Carnot cycle and hybrid cars
60
Derivation box
3.1
Entropy as a state function
63
Research direction: nitrogen fixation
66
References
69
Problems
69
4
Phase diagrams, mixtures, and chemical potential
71
Substances may exist in different phases
71
Phase diagrams and transitions
72
Chemical potential
73
Properties of lipids described using the chemical potential
74
Lipid
and detergent formation into micelles and bilayers
75
Research direction:
lipid
rafts
77
Determination of micelle formation using surface tension
79
Mixtures
82
Raoult s law
85
Osmosis
88
Research direction: protein crystallization
88
References
92
Problems
92
5
Equilibria and reactions involving protons
94
Gibbs energy minimum
94
Derivation box
5.1
Relationship between the Gibbs energy and equilibrium constant
95
Response of the equilibrium constant to condition changes
98
Acid-base equilibria
99
Protonation
states of
amino
acid residues
105
CONTENTS
ÍX
Buffers
106
Buffering in the cardiovascuiar system
108
Research direction: proton-coupled electron transfer and pathways
108
References 111
Problems
112
Oxidation/reduction reactions and bioenergetics
114
Oxidation/reduction reactions
114
Electrochemical cells
115
The Nernst equation
116
Midpoint potentials
117
Gibbs energy of formation and activity
120
Ionic strength
122
Adenosine triphosphate
123
Chemiosmotic hypothesis
124
Research direction: respiratory chain
126
Research direction: ATP synthase
128
References
131
Problems
132
Kinetics and enzymes
134
The rate of a chemical reaction
134
Parallel first-order reactions
137
Sequential first-order reactions
139
Second-order reactions
140
The order of a reaction
141
Reactions that approach equilibrium
142
Activation energy
143
Research direction: electron transfer I: energetics
144
Derivation box
7.1
Derivation of the Marcus relationship
146
Enzymes
147
Enzymes lower the activation energy
148
Enzyme mechanisms
150
Research direction: dynamics in enzyme mechanism
150
Michaelis-Menten mechanism
151
Lineweaver-Burk equation
155
Enzyme activity
155
Research direction: the
RNA
world
158
References
160
Problems
161
The Boltzmann distribution and statistical thermodynamics
163
Probability
163
Boltzmann distribution
165
Partition function
166
CONTENTS
Statistical thermodynamics
167
Research direction: protein folding and
prions
168
Prions
169
References
171
Problems
171
Part
2:
Quantum mechanics and spectroscopy
173
9
Quantum theory: introduction and principles
175
Classical concepts
175
Experimental failures of classical physics
177
Blackbody
radiation
177
Photoelectric effect
180
Atomic spectra
180
Principles of quantum theory
182
Wave-particle duality
182
Schrödinger s
equation
184
Born interpretation
188
General approach for solving
Schrödinger s
equation
190
Interpretation of quantum mechanics
191
Heisenberg
Uncertainty Principle
192
A quantum-mechanical world
193
Research direction:
Schrödinger s
cat
194
References
195
Problems
196
10
Particle in a box and tunneling
198
One-dimensional particle in a box
198
Properties of the solutions
200
Energy and wavefunction
200
Symmetry
201
Wavelength
202
Probability
202
Orthogonality
203
Average or expectation value
203
Transitions
204
Research direction: carotenoids
205
Two-dimensional particle in a box
207
Tunneling
209
Research direction: probing biological membranes
211
Research direction: electron transfer II: distance dependence
215
References
218
Problems
218
CONTENTS Xi
11 Vibrational
motion
and infrared spectroscopy
221
Simple harmonic oscillator: classical theory
221
Potential energy for the simple harmonic oscillator
223
Simple harmonic oscillator: quantum theory
223
Derivation box
11.1
Solving
Schrödinger s
equation for the simple
harmonic oscillator
224
Properties of the solutions
225
Forbidden region
228
Transitions
229
Vibrational spectra
230
Research direction: hydrogenase
232
References
235
Problems
235
12
Atomic structure: hydrogen atom and multi-electron atoms
238
Schrödinger s
equation for the hydrogen atom
238
Derivation box
12.1
Solving
Schrödinger s
equation for the hydrogen atom
239
Separation of variables
239
Angular solution
240
Radial solution
243
Properties of the general solution
244
Angular momentum
246
Orbitals 247
s
Orbitals 247
ρ
Orbitals 251
d
Orbitals 252
Transitions
253
Research direction:
hydrogen economy
254
Spin
257
Derivation box
12.2
Relativistic equations
258
Multi-electron atoms
260
Empirical constants
260
Self-consistent field theory (Hartree-Fock)
261
Helium atom
262
Spin-orbital coupling
264
Periodic table
265
References
267
Problems
267
13
Chemical bonds and protein interactions
270
Schrödinger s
equation for a hydrogen molecule
270
Valence bonds
275
The
Hückel
model
276
Interactions in proteins
276
ХИ
CONTENTS
Peptide
bonds
278
Steric effects
278
Hydrogen bonds
279
Electrostatic interactions
280
Hydrophobie
effects
280
Secondary structure
282
Determination of secondary structure using circular dichroism
284
Research direction: modeling protein structures and folding
284
References
289
Problems
289
14
Electronic transitions and optical spectroscopy
291
The nature of light
291
The Beer-Lambert law
293
Measuring absorption
294
Transitions
296
Derivation box
14.1
Relationship between the Einstein coefficient and
electronic states
298
Lasers
300
Selection rules
301
The Franck-Condon principle
302
The relationship between emission and absorption spectra
303
The yield of fluorescence
305
Fluorescence resonance energy transfer
306
Measuring fluorescence
306
Phosphorescence
307
Research direction: probing energy transfer using two-dimensional
optical spectroscopy
307
Research direction: single-molecule spectroscopy
310
Holliday junctions
312
References
315
Problems
315
15
X-ray diffraction and extended X-ray absorption fine structure
317
Bragg s law
319
Bravais
lattices
320
Protein crystals
322
Diffraction from crystals
323
Derivation box
15.1
Phases of complex numbers
325
Phase determination
328
Molecular replacement
328
Isomorphous replacement
329
Anomalous dispersion
329
Model building
33
j
Experimental measurement of X-ray diffraction
332
CONTENTS
Xl«
Examples of protein structures
335
Research direction: nitrogenase
336
Extended X-ray absorption fine structure
339
References
342
Problems
342
16
Magnetic resonance
344
NMR
344
Chemical shifts
347
Spin-spin interactions
348
Pulse techniques
349
Two-dimensional NMR: nuclear Overhauser effect
351
NMR spectra of
amino
acids
352
Research direction: development of new NMR techniques
352
Détermination
of macromolecular structures
357
Research direction: spinal muscular atrophy
357
MRI
360
Electron spin resonance
362
Hyperfine structure
365
Electron nuclear double resonance
365
Spin probes
366
Research direction:
heme
proteins
367
Research direction: ribonucleotide
reducíase
369
References and further reading
370
Problems
371
Part
3:
Understanding biological systems using physical chemistry
373
17
Signal transduction
375
Biochemical pathway for visual response
375
Spectroscopic studies of rhodopsin
377
Bacteriorhodopsin
378
Structural studies
380
Comparison of rhodopsins from different organisms
384
Rhodopsin proteins in visual response
387
References and further reading
387
Problems
388
18
Membrane potentials, transporters, and channels
390
Membrane potentials
390
Energetics of transport across membranes
391
Transporters
394
Ion channels
397
References and further reading
402
Problems
403
XIV
CONTENTS
19
Molecular imaging
405
Imaging in cells and bodies
405
Green fluorescent protein
405
Mechanism of chromophore formation
408
Fluorescence resonance energy transfer
410
Imaging of GFP in cells
412
Imaging in organisms
414
Radioactive decay
415
PET
416
Parkinson s disease
418
References and further reading
419
Problems
419
20
Photosynthesis
421
Energy transfer and light-harvesting complexes
423
Electron transfer, bacterial reaction centers, and photosystem I
425
Water oxidation
430
References and further reading
436
Problems
437
Answers to problems
439
Index
488
Fundamental constants
493
Conversion factors for energy units
493
The periodic table
494
Short
contents
Preface
xv
1
Basic thermodynamic and biochemical concepts
1
Part
1:
Thermodynamics and kinetics
21
2
First law of thermodynamics
23
3
Second law of thermodynamics
46
4
Phase diagrams, mixtures, and chemical potential
71
5
Equilibria and reactions involving protons
94
6
Oxidation/reduction reactions and bioenergetics
114
7
Kinetics and enzymes
134
8
The Boltzmann distribution and statistical thermodynamics
163
Part
2:
Quantum mechanics and spectroscopy
173
9
Quantum theory: introduction and principles
175
10
Particle in a box and tunneling
198
11
Vibrational motion and infrared spectroscopy
221
12
Atomic structure: hydrogen atom and multi-electron atoms
238
13
Chemical bonds and protein interactions
270
14
Electronic transitions and optical spectroscopy
291
15
X-ray diffraction and extended X-ray absorption fine structure
317
16
Magnetic resonance
344
Part
3:
Understanding biological systems using physical chemistry
373
17
Signal transduction
375
18
Membrane potentials, transporters, and channels
390
19
Molecular imaging
405
20
Photosynthesis
421
Answers to problems
439
Index
488
Fundamental constants
49 3
Conversion factors for energy units
493
The periodic table
494
|
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callnumber-sort | QD 3476.2 |
callnumber-subject | QD - Chemistry |
classification_rvk | WD 2000 WD 2200 |
classification_tum | CHE 802f |
ctrlnum | (OCoLC)173201752 (DE-599)GBV545977894 |
dewey-full | 572/.43 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 572 - Biochemistry |
dewey-raw | 572/.43 |
dewey-search | 572/.43 |
dewey-sort | 3572 243 |
dewey-tens | 570 - Biology |
discipline | Chemie / Pharmazie Biologie |
edition | 1. ed. |
format | Book |
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genre | (DE-588)4123623-3 Lehrbuch gnd-content |
genre_facet | Lehrbuch |
id | DE-604.BV023071706 |
illustrated | Illustrated |
indexdate | 2024-12-20T13:07:59Z |
institution | BVB |
isbn | 9781405124362 |
language | English |
lccn | 2007038528 |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016274848 |
oclc_num | 173201752 |
open_access_boolean | |
owner | DE-703 DE-19 DE-BY-UBM DE-355 DE-BY-UBR DE-29T DE-526 DE-83 DE-91G DE-BY-TUM DE-11 |
owner_facet | DE-703 DE-19 DE-BY-UBM DE-355 DE-BY-UBR DE-29T DE-526 DE-83 DE-91G DE-BY-TUM DE-11 |
physical | XVI, 492 S. Ill., graph. Darst. |
publishDate | 2008 |
publishDateSearch | 2008 |
publishDateSort | 2008 |
publisher | Wiley-Blackwell |
record_format | marc |
spellingShingle | Allen, James P. Biophysical chemistry Biochemistry Biophysics Chemistry, Physical Physical biochemistry Biophysikalische Chemie (DE-588)4291844-3 gnd |
subject_GND | (DE-588)4291844-3 (DE-588)4123623-3 |
title | Biophysical chemistry |
title_auth | Biophysical chemistry |
title_exact_search | Biophysical chemistry |
title_full | Biophysical chemistry James P. Allen |
title_fullStr | Biophysical chemistry James P. Allen |
title_full_unstemmed | Biophysical chemistry James P. Allen |
title_short | Biophysical chemistry |
title_sort | biophysical chemistry |
topic | Biochemistry Biophysics Chemistry, Physical Physical biochemistry Biophysikalische Chemie (DE-588)4291844-3 gnd |
topic_facet | Biochemistry Biophysics Chemistry, Physical Physical biochemistry Biophysikalische Chemie Lehrbuch |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016274848&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016274848&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT allenjamesp biophysicalchemistry |
Inhaltsverzeichnis
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Teilbibliothek Chemie
Signatur: |
0302 CHE 802f 2010 A 828
Lageplan |
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Exemplar 1 | Ausleihbar Am Standort |