Single molecule chemistry and physics: an introduction
Gespeichert in:
| Beteiligte Personen: | , |
|---|---|
| Format: | Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2006
|
| Schriftenreihe: | NanoScience and Technology
|
| Schlagwörter: | |
| Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=013313214&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| Umfang: | XI, 303 S. Ill., graph. Darst. |
| ISBN: | 3540253696 9783540253693 |
Internformat
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| 100 | 1 | |a Wang, Chen |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Single molecule chemistry and physics |b an introduction |c C. Wang ; C. Bai |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 2006 | |
| 300 | |a XI, 303 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 700 | 1 | |a Bai, Chunli |e Verfasser |4 aut | |
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Datensatz im Suchindex
| _version_ | 1819286858441424896 |
|---|---|
| adam_text | Contents
1 Introduction to Single Molecule Chemistry and Physics . . 1
2 Basics of Electron Tunneling Processes
and Scanning Tunneling Microscopy 5
2.1 Principles of Tunneling Processes 5
2.1.1 Elastic Tunneling Process 5
2.1.2 Inelastic Tunneling Process 8
2.1.3 Two Step Tunneling Process 14
2.1.4 Resonant Tunneling Effect 14
2.2 Introduction to Scanning Tunneling Microscopy (STM) 15
2.2.1 Introduction to STM 15
2.2.2 STM Contrast Mechanisms 20
2.2.3 Scanning Tunneling Spectroscopy (STS) 22
2.2.4 Measurement of Apparent Tunneling
Barrier Height 24
3 Single Molecule Structural Characterization 29
3.1 Molecular Imaging Mechanisms of STM 30
3.1.1 Molecular Orbital Model 31
3.1.2 HOMO Ionization Potential Model 33
3.1.3 Work Function Model 34
3.2 Single Diatomic Molecules on Metal Surfaces 36
3.2.1 CO 37
3.2.2 O2 Molecules 40
3.3 Aromatic Molecules and Macrocyclic Molecules 42
3.3.1 Single Benzene Molecules Observed by STM 42
3.3.2 Phthalocyanines (Pc) 46
3.3.3 Porphyrin 48
3.3.4 Heterocyclic Molecules 51
3.3.5 Fullerene 53
3.3.6 Other Molecules 54
3.4 Single Hydrocarbon Molecules 55
3.5 Single Molecules Immobilized by Molecular Matrix 57
3.5.1 Hydrogen Bonded Networks
and Single Molecule Inclusions 57
VIII Contents
3.5.2 Molecular Networks Stabilized
by van der Waals Interaction 59
3.6 Single Molecule Adsorption on Organic Substrates 60
3.6.1 Simple Alkane Lamella 61
3.6.2 Alkylated Amino Acid Molecular Templates 63
3.6.3 Tridodecyl Amine (TDA) Templates 64
3.7 Electron Spin Resonance Study
of Single Molecules 66
4 Single Molecule Diffusion and Chemical Reactions 69
4.1 Molecular Diffusion on Surfaces 69
4.1.1 Thermal Activated Single Molecule Diffusion 69
4.1.2 Laser Activated Single Molecule Diffusion 71
4.1.3 Field Induced Diffusion of Single Atoms 71
4.2 Single Atom and Molecule Manipulations 74
4.2.1 Controlled Manipulation of Single Xe Atoms 74
4.2.2 Si Atoms 75
4.2.3 Gold Atoms 76
4.2.4 CO Molecules 76
4.2.5 C60 Molecules 77
4.3 Single Molecule Chemical Reactions on Metal Surfaces 78
4.3.1 Single Molecule Oxidative Reaction
on Metal Surfaces 79
4.3.2 Dissociative Adsorption of H2 82
4.3.3 Dissociative Adsorption of NO 83
4.3.4 Dissociation of NH3 84
4.3.5 CO Oxidation 85
4.3.6 Dehydrogenation of Single Molecules 86
4.3.7 Tip Induced Reactions of Single Iodobenzene
on Cu(lll) 88
4.3.8 Formation of Metal Ligand Complexes 89
4.3.9 Other Reaction Model Systems 91
4.4 Single Molecules on Semiconductor Surfaces 93
4.4.1 Single H2 Molecules on Si(100) 93
4.4.2 Single NH3 Molecules on Si Surfaces 94
4.4.3 Single O2 on Ge(lll), Si(100) and Si(lll) 95
4.4.4 Other Molecules on Si Surfaces 96
4.5 Single Molecule Reactions on Metal Oxide Surfaces 97
4.5.1 TiO2 98
4.5.2 CO on RuO2(110) 102
4.5.3 Fe Oxide Surfaces 103
4.5.4 Other Oxide Surfaces 105
Contents IX
5 Molecular Scale Analysis
Using Scanning Force Microscopy 107
5.1 Basic Principles of Atomic Force Microscopy (AFM) 107
5.1.1 Introduction of Instrumentation 107
5.1.2 Cantilever 108
5.1.3 Cantilever Deflection Detection 109
5.1.4 Cantilever Calibration 110
5.2 AFM Operating in Contact Mode 112
5.2.1 Contact Mode 112
5.2.2 Friction Force Microscopy 117
5.3 AFM Operating in Oscillatory Modes 118
5.3.1 Tapping Mode 118
5.3.2 Phase Imaging 120
5.3.3 Operations Under Liquids 120
5.3.4 Non Contact Mode 122
5.4 Magnetic Force Microscopy (MFM) 123
5.4.1 Basic Imaging Mechanism 123
5.4.2 Examples of MFM Studies of Molecular Structures . . 125
5.4.3 Imaging Single Molecule Magnets 126
5.5 Force Spectrum and Surface Mapping 127
5.5.1 Force Spectrum and Imaging 127
5.5.2 Chemical Force Microscopy 128
6 Intermolecular and Intramolecular Interactions 131
6.1 Techniques for Studying Intermolecular
and Intramolecular Interactions 131
6.1.1 Biomembrane Force Probe (BFP) 131
6.1.2 Optical Tweezers 132
6.2 Static Force Measurements of Single Molecules 134
6.2.1 Single Bond Interaction 134
6.2.2 Single Pair Ligand Receptor Interactions 139
6.2.3 Guest Host Interactions 141
6.2.4 Desorption of Single Molecules at Interfaces 142
6.3 Intramolecular Interactions of Single Molecules 144
6.3.1 Elasticity of DNA Molecules 144
6.3.2 Folding and Refolding of Single Protein Molecules. . . 148
6.3.3 Stretching Other Biomolecules 149
6.3.4 Polysaccharides 152
6.3.5 Other Polymers 153
6.4 Dynamic Force Measurements of Single Molecules 154
6.4.1 Pulling Rate Effect
on Force Spectrum Measurements 154
6.4.2 Pulling Rate Effect
on Rupture Force Measurements 155
X Contents
6.4.3 Force Measurements Relevant to
Movements of Biomolecules 158
7 Electrical Conductivity of Single Molecules 159
7.1 Introduction 159
7.1.1 One Dimensional Molecular
Conductance Structures 159
7.1.2 Methods for Measuring Molecular Conductivity 163
7.2 Electrical Conductivity of Molecular Monolayers 165
7.2.1 Linear Alkane Derivatives 165
7.2.2 Conjugated Molecules 166
7.2.3 Rectification Molecular Conductance 167
7.2.4 Switching Behavior of Molecular Conductance 169
7.3 Single Molecule Conductance 170
7.3.1 Molecule Electrode Contact Effect 170
7.3.2 Conductance of Single Organic Molecules 174
7.3.3 Conductance of Single Nanotubes and Nanowires . . . 176
7.3.4 DNA Molecules 177
7.3.5 Single Molecule Devices 179
8 Single Molecule Fluorescence Imaging and
Spectroscopy: Far Field Studies 183
8.1 Introduction 183
8.1.1 Fluorescence of Molecules 183
8.1.2 General Considerations for Experimental Setup 185
8.1.3 Criteria of Single Molecule Identification 187
8.2 Single Molecule Imaging in Far Field Configuration 188
8.2.1 Imaging by Confocal Fluorescence Microscopy 188
8.2.2 Wide Field Imaging: Epi Illumination Microscopy . . . 188
8.3 Low Temperature Studies of Single Molecules
in Solid Matrices 189
8.3.1 Observation of Single Molecules
in Crystalline Matrix 189
8.3.2 Pump Probe Effects 193
8.3.3 Magnetic Resonance
of Single Fluorescence Molecules 195
8.4 Single Fluorescence Molecules in Liquid Conditions 196
8.4.1 Experimental Considerations 196
8.4.2 Examples of Fluorescence of Single Molecules
in Solutions 197
8.4.3 Single Molecule Diffusions in Living Cells 200
8.4.4 Single Pair FRET 202
8.5 Single Molecules in Other Support Media 207
8.5.1 Single Molecules in Polymer Hosts 207
8.5.2 Lateral Diffusion Behavior of Single Molecules 210
Contents XI
8.5.3 Fluorescence from Single Atomic Clusters
and Defects 212
8.6 Tip Induced Single Molecule Fluorescence 212
8.7 Dynamics of Single Polymeric Molecules Studied by
Fluorescence Microscopy and Related Techniques 213
8.7.1 Dynamics of Single Macromolecules in Solutions .... 213
8.7.2 Single Molecules Moving Through Channels 215
8.7.3 Migration of DNA Molecules on Flat Surfaces 217
8.7.4 Single Molecule Condensation of DNA 219
9 Single Molecule Fluorescence Imaging and Spectroscopy:
Near Field Studies 223
9.1 Near Field Scanning Optical Microscopy 223
9.1.1 Introduction of Near Field Effect 223
9.1.2 NSOM Probe Designs 226
9.1.3 Approaching Modes 229
9.2 Near Field Scanning Optical Microscopy and Spectroscopy . . 230
9.2.1 Near Field Optical Microscopy 230
9.2.2 Near Field Optical Spectroscopy 232
9.2.3 Fluorescence Resonance Energy Transfer (FRET)
Studied by NSOM 235
9.3 Other Near Field Optical Microscopy 237
9.3.1 Near Field Optical Chemical Sensors 237
9.3.2 Scanning Exciton Microscopy 238
10 Surface Enhanced Raman Scattering (SERS) of Single
Molecules 241
10.1 Introduction of SERS Effect 241
10.2 SERS of Single Molecules 244
10.2.1 Single Particle SERS Effect 244
10.2.2 SERS of Nanoparticle Aggregates 245
10.3 Tip Induced SERS 253
10.4 Near Field SERS 254
10.5 Raman Spectroscopy of Carbon Nanotubes 256
References 259
Index 299
|
| any_adam_object | 1 |
| author | Wang, Chen Bai, Chunli |
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| id | DE-604.BV019991301 |
| illustrated | Illustrated |
| indexdate | 2024-12-20T12:09:42Z |
| institution | BVB |
| isbn | 3540253696 9783540253693 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-013313214 |
| oclc_num | 181444771 |
| open_access_boolean | |
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| owner_facet | DE-20 DE-19 DE-BY-UBM DE-634 DE-11 |
| physical | XI, 303 S. Ill., graph. Darst. |
| publishDate | 2006 |
| publishDateSearch | 2006 |
| publishDateSort | 2006 |
| publisher | Springer |
| record_format | marc |
| series2 | NanoScience and Technology |
| spellingShingle | Wang, Chen Bai, Chunli Single molecule chemistry and physics an introduction Molecular spectroscopy Molecules Nanotechnology Freies Molekül (DE-588)4489205-6 gnd |
| subject_GND | (DE-588)4489205-6 |
| title | Single molecule chemistry and physics an introduction |
| title_auth | Single molecule chemistry and physics an introduction |
| title_exact_search | Single molecule chemistry and physics an introduction |
| title_full | Single molecule chemistry and physics an introduction C. Wang ; C. Bai |
| title_fullStr | Single molecule chemistry and physics an introduction C. Wang ; C. Bai |
| title_full_unstemmed | Single molecule chemistry and physics an introduction C. Wang ; C. Bai |
| title_short | Single molecule chemistry and physics |
| title_sort | single molecule chemistry and physics an introduction |
| title_sub | an introduction |
| topic | Molecular spectroscopy Molecules Nanotechnology Freies Molekül (DE-588)4489205-6 gnd |
| topic_facet | Molecular spectroscopy Molecules Nanotechnology Freies Molekül |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=013313214&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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