Materials modification by electronic excitation:
Gespeichert in:
| Beteiligte Personen: | , |
|---|---|
| Format: | Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
Cambridge [u.a.]
Cambridge Univ. Press
2001
|
| Ausgabe: | 1. publ. |
| Schlagwörter: | |
| Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009355029&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| Umfang: | XV, 520 S. graph. Darst. |
| ISBN: | 0521554985 |
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| 650 | 4 | |a Excitation électronique | |
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| 650 | 4 | |a Matériaux, Effets du rayonnement sur les | |
| 650 | 4 | |a Electron beams | |
| 650 | 4 | |a Electronic excitation | |
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Datensatz im Suchindex
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| DE-BY-TUM_location | LSB |
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| _version_ | 1821931298723201024 |
| adam_text | MATERIALS MODIFICATION BY ELECTRONIC EXCITATION N. ITOH NAGOYA
UNIVERSITY AND A. M. STONEHAM UNIVERSITY COLLEGE LONDON CAMBRIDGE
UNIVERSITY PRESS CONTENTS PREFACE PAGE XII 1 CONCEPTS: EXCITATION,
POLARONS AND ELECTRONIC STRUCTURE 1 1.1 BASIC IDEAS ABOUT THE
LOCALISATION OF CHARGE AND ENERGY 1 1.1.1 THE POLARON CONCEPT 3 1.1.2
EXCITATION OF METALS AND INSULATORS: WHAT IS SPECIAL ABOUT INSULATORS? 6
1.2 METHODS OF EXCITATION 7 1.2.1 EXCITATION BY ELECTROMAGNETIC
RADIATION 7 1.2.2 EXCITATION BY ELECTRONS 15 1.2.3 OTHER FORMS OF
PARTICLE EXCITATION 19 1.2.4 OTHER FORMS OF EXCITATION 23 1.3 STRUCTURE
AT THE ATOMIC SCALE 25 1.3.1 STRUCTURAL ISSUES: WHERE DO CRYSTALLINE AND
AMORPHOUS MATERIALS DIFFER? 25 1.3.2 THE VARIED FORMS OF AMORPHOUS 27
1.3.3 MESOSTRUCTURE 28 1.4 BASIC ISSUES OF ELECTRONIC STRUCTURE 31 1.4.1
BAND STRUCTURES: GENERAL FEATURES FOR CRYSTALLINE AND AMORPHOUS SOLIDS
31 1.4.2 APPROACHES TO ELECTRONIC STRUCTURE 34 1.4.3 SPECIAL CASES 35
1.4.4 LOCALISING CHARGE 38 1.5 EXCITATION AND EXCITED STATES 45 1.5.1
OPTICAL EXCITATION 46 1.5.2 EXCITATION BY IONISING RADIATION 48 1.5.3
EXCITATION AT HIGHER ENERGIES 49 1.5.4 EXCITATION AT HIGHER INTENSITIES
52 1.6 EXCITATION OF DEFECTS AND RECOVERY AFTER EXCITATION 52 V VI
CONTENTS 2 ENERGY DEPOSITION AND REDISTRIBUTION IN SOLIDS 57 2.1
INTERACTIONS OF CHARGED PARTICLES WITH SOLIDS 58 2.2 THEORY OF THE
INTERACTION OF CHARGED PARTICLES WITH SOLIDS 67 2.3 ISSUES: BEYOND THE
STANDARD MODELS 71 2.4 CHALLENGES: NON-EQUILIBRIUM SITUATIONS 74 2.5
THERMAL DIFFUSION: PROCESSES NEAR THERMAL EQUILIBRIUM 75 2.5.1 THE
PHENOMENOLOGY OF DIFFUSION RATES: THE ARRHENIUS AND MEYER-NELDEL
(COMPENSATION) EXPRESSIONS 76 2.5.2 SPECIAL CASES OF DIFFUSION 77 2.6
TRANSPORT AND CAPTURE PROCESSES 79 2.6.1 GEMINATE RECOMBINATION 79 2.6.2
RATE THEORY AND DEFECT AGGREGATES 81 3 ELECTRON-LATTICE COUPLING AND ITS
CONSEQUENCES 85 3.1 BASICS OF ELECTRON-LATTICE COUPLING 85 3.2 THE
CONFIGURATION COORDINATE DIAGRAM 88 3.2.1 THE BASIC CONFIGURATION
COORDINATE MODEL 89 3.2.2 CHOICES OF CONFIGURATION COORDINATE 90 3.2.3
SIMPLE CASES: THE F CENTRE 91 3.2.4 OPTICAL TRANSITIONS 93 3.2.5 CHARGE
TRANSFER TRANSITIONS 95 3.3 RELAXATION ENERGIES AND DEFECT STABILITY 96
3.3.1 STABILITY AND INSTABILITY 97 3.3.2 EXAMPLES OF CHARGE STATE
STABILITY 98 3.3.3 STABILITY OF SELF-TRAPPED POLARONS: STRATEGIES 99
3.3.4 STABILITY OF SMALL POLARONS: STATIC APPROACHES 101 3.3.5 STABILITY
OF SMALL POLARONS: MICROSCOPIC CALCULATION OF THE RELAXATION ENERGY 102
3.3.6 SMALL-POLARON FORMATION ENERGY: ENERGY CYCLES 105 3.3.7 SPECIFIC
PROPERTIES OF THE SELF-TRAPPED EXCITON (STX) STATE 106 3.4 MOBILITIES
AND CHARGE TRANSPORT IN NON-METALS 108 3.4.1 EXPERIMENTAL DATA ON
MOBILITIES 108 3.4.2 SMALL POLARONS AND LARGE POLARONS: IDEAS ABOUT
MOTION 108 3.4.3 SELF-TRAPPED EXCITONS VERSUS SELF-TRAPPED HOLES:
EXCITON BANDWIDTHS 110 3.4.4 CLASSICAL DIFFUSION OF IONS AND OTHER
OVER-THE-BARRIER PROCESSES 110 3.4.5 DIFFUSION OF SELF-TRAPPED CARRIERS
113 3.5 NON-RADIATIVE TRANSITIONS I: COOLING TRANSITIONS 114 3.5.1
COOLING OF ATOMIC MOTION 114 CONTENTS VLL 3.5.2 TRANSITIONS FROM ONE
ENERGY SURFACE TO ANOTHER 120 3.5.3 COOLING OF ELECTRONIC EXCITATION:
FREE CARRIER STATES 122 3.5.4 COOLING OF ELECTRONIC EXCITATION: CAPTURE
AND COOLING OF BOUND CARRIER STATES 125 3.6 NON-RADIATIVE TRANSITIONS
II: ABSOLUTE RATES 127 3.6.1 KINETICS AND DYNAMICS 127 3.6.2 MULTIPHONON
NON-RADIATIVE TRANSITIONS 128 3.7 NON-RADIATIVE TRANSITIONS III:
LOCALISATION PROCESSES AND THEIR RATES 132 3.7.1 ROUTES TO THE
SELF-TRAPPED STATE 132 3.7.2 QUANTUM MOLECULAR DYNAMICS APPROACHES 135
3.7.3 SOLVATION OF AN ELECTRON IN WATER 135 3.7.4 FROZEN GAUSSIAN
METHODS 136 4 SELF-TRAPPING 138 4.1 SELF-TRAPPED CARRIERS IN HALIDES 138
4.1.1 SELF-TRAPPED ELECTRONS 140 4.1.2 SELF-TRAPPED HOLES 141 4.1.3
RELAXATION PROCESSES OF SELF-TRAPPED HOLES 145 4.1.4 EXTRINSIC AND
PERTURBED SELF-TRAPPED HOLES 149 4.2 SELF-TRAPPED CARRIERS IN OXIDES 150
4.3 SELF-TRAPPED EXCITONS IN HALIDES 152 4.3.1 AGCL 154 4.3.2 ALKALI
HALIDES WITH THE NACL STRUCTURE 155 4.3.3 OTHER HALIDES 166 4.4
SELF-TRAPPED EXCITONS IN OXIDES 171 4.4.1 SELF-TRAPPED EXCITONS IN
OXIDES WITH CLOSED-SHELL CATIONS 171 4.4.2 SELF-TRAPPED EXCITONS OF
OXIDES WITH OPEN-SHELL CATIONS 180 4.5 SELF-TRAPPED EXCITONS IN
CRYSTALLINE SEMICONDUCTORS 181 SUMMARY 185 5 LOCAL LATTICE MODIFICATION
BY ELECTRONIC EXCITATION OF HALIDES 187 5.1 EXCITONIC MECHANISMS FOR
DEFECT FORMATION 188 5.1.1 ADIABATIC POTENTIAL ENERGY SURFACES AND
RELAXATION CHANNELS 188 5.1.2 EXPERIMENTAL EVIDENCE FOR THREE CHANNELS
FOR DEFECT PAIR FORMATION IN ALKALI HALIDES 193 5.1.3 BRANCHING BETWEEN
THE RELAXATION CHANNELS FROM EXCITON TO DEFECT PAIR 195 5.1.4 THERMAL
CONVERSION FROM SELF-TRAPPED EXCITON TO DEFECT PAIR 201 VLLL CONTENTS
5.1.5 OTHER MATERIALS IN WHICH THE EXCITONIC MECHANISM IS EFFECTIVE 205
5.2 DEFECT FORMATION BY OTHER MECHANISMS 207 5.2.1 DEFECT FORMATION FROM
INTERACTING EXCITONS 207 5.2.2 DEFECT GENERATION BY TWO-HOLE
LOCALISATION 208 5.2.3 THE PHOTOGRAPHIC PROCESS IN SILVER HALIDES 209
5.2.4 PHOTOCHROMIC AND PHOTOSENSITIVE GLASSES 214 5.2.5 CREATION OF
DEFECT PAIRS IN THE CATION SUBLATTICE 215 5.3 DEFECTS CREATED BY
IONISING RADIATION 216 5.3.1 DEFECT PAIRS CREATED AT LOW TEMPERATURES
217 5.3.2 STABILISATION OF INTERSTITIALS 219 SUMMARY 223 6 LOCAL LATTICE
MODIFICATION BY ELECTRONIC EXCITATION OF CRYSTALLINE INSULATING OXIDES
224 6.1 BASIC PHENOMENA 224 6.1.1 OXIDES AND HALIDES: BASICS AND
SIMILARITIES 224 6.1.2 SELF-TRAPPING IN OXIDES 225 6.1.3 CHARGE TRANSFER
AND COLOUR 226 6.1.4 NON-LINEAR PROCESSES AND NEGATIVE U 228 6.1.5
AMORPHISATION 229 6.2 EFFECTS INDUCED UNDER ELECTRON BEAM EXCITATION 230
6.2.1 DAMAGE AND DEGRADATION 230 6.2.2 AMORPHISATION BY ELECTRON BEAMS
232 6.2.3 TRANSIENT DEFECTS 233 6.3 ELECTRICAL BREAKDOWN AND RELATED
PHENOMENA 234 6.3.1 METAL-INSULATOR TRANSITIONS IN OXIDE FILMS 235 6.3.2
ELECTRICAL BREAKDOWN IN SIMPLE CERAMIC OXIDES, LIKE MGO AND ALUMINA 237
6.3.3 BREAKDOWN IN THE OXIDE ON SILICON 238 6.3.4 RADIATION-INDUCED
ELECTRICAL DEGRADATION 242 SUMMARY 244 7 LOCAL LATTICE MODIFICATION OF
SEMICONDUCTORS BY ELECTRONIC EXCITATION 245 7.1 GENERAL COMPARISONS:
SWITCHING BETWEEN STATES AND MOTION 245 7.2 ENHANCED DIFFUSION 247 7.2.1
CHARACTERISTICS OF ENHANCED DIFFUSION 247 7.2.2 ROUTES TO ENHANCED
DIFFUSION 250 7.2.3 UNDERSTANDING ENHANCED DIFFUSION 252 7.2.4 TYPES OF
ENHANCED DIFFUSION 253 7.3 LOCAL HEATING MODELS ( HOT-SPOT OR
PHONON-KICK MECHANISMS) 253 7.3.1 THE MODEL OF WEEKS, TULLY, AND
KIMERLING 254 CONTENTS IX 7.3.2 THE MODEL OF MASRI AND STONEHAM 254
7.3.3 THE MODEL OF SUMI 255 7.3.4 OTHER GENERAL ISSUES 256 7.4 LOCAL
EXCITATION MODELS, INCLUDING THE BOURGOIN-CORBETT MECHANISM 259 7.4.1
CASE I: ENERGY EXTREMA AT THE SAME SITE 260 7.4.2 CASE II: ENERGY
SURFACES WITH EXTREMA AT DIFFERENT SITES 261 7.4.3 THE BOURGOIN-CORBETT
MODEL 263 7.4.4 ANALOGOUS SYSTEMS: METASTABILITY AND REORIENTATION 264
7.5 HOW CAN THE MECHANISMS BE DISTINGUISHED FROM EACH OTHER? 266 7.5.1
CONSISTENCY ARGUMENTS 267 7.5.2 REASONABLENESS ARGUMENTS 267 7.5.3 ARE
CHARGE STATE CHANGES POSSIBLE AND SIGNIFICANT? 268 7.6 ISSUES IN
ENHANCED DIFFUSION: FURTHER DISCUSSION OF MECHANISMS 269 7.6.1 COMPETING
PROCESSES: ISOTOPE EFFECTS IN ELECTRICAL ISOLATION 269 7.6.2 DISLOCATION
GROWTH AND MOTION 270 7.6.3 ENHANCED OXIDATION 273 SUMMARY 274 8 LOCAL
LATTICE MODIFICATION OF AMORPHOUS MATERIALS BY ELECTRONIC EXCITATION 275
8.1 ELECTRONS, HOLES, AND EXCITONS IN AMORPHOUS SOLIDS 280 8.1.1 THE
OPTICAL ABSORPTION EDGE 280 8.1.2 MOTION OF ELECTRONS AND HOLES 282 8.2
OPTICAL ABSORPTION AND LUMINESCENCE 284 8.2.1 AMORPHOUS SILICAS: A-SI0 2
287 8.2.2 CHALCOGENIDES 292 8.2.3 DIAMOND-LIKE CARBON (A-C:H; DLC) AND
AMORPHOUS SILICON (A-SI:H) 294 8.3 DEFECT FORMATION 300 8.3.1 AMORPHOUS
SILICAS: A-SI0 2 301 8.3.2 CHALCOGENIDES 309 8.3.3 AMORPHOUS SILICON:
A-SI:H 311 8.4 PHOTO-INDUCED STRUCTURAL CHANGES: PHOTODARKENING 313 8.5
ION-BEAM-INDUCED STRUCTURAL CHANGES 319 8.5.1 ION-INDUCED
CRYSTALLISATION AND AMORPHISATION OF SILICATE GLASSES 319 APPENDIX:
BASIC DEFECTS IN GLASSES 321 SUMMARY 324 9 ATOMIC EMISSION AND SURFACE
MODIFICATION 325 9.1 ENERGY ABSORPTION NEAR SURFACES 325 X CONTENTS
9.1.1 PERFECT SURFACES 327 9.1.2 NEAR-SURFACE DEFECTS 328 9.1.3 SURFACE
DEFECTS 330 9.1.4 REAL SURFACES: RECOGNISING IMPERFECTION 333 9.1.5
SURFACE TOPOGRAPHY 333 9.1.6 EXCITATION OF SURFACE STATES 335 9.1.7
SURFACE EXCITATION FOLLOWING BULK EXCITATION 335 9.1.8 EXOELECTRON
EMISSION 337 9.1.9 LUMINESCENCE FROM SURFACES 339 9.1.10 LOCAL LATTICE
MODIFICATION ON SURFACES 339 9.1.11 CORE EXCITATION ON SURFACES 341
9.1.12 LASER EXCITATION OF SURFACES 341 9.2 SPUTTERING AND SURFACE
MODIFICATION OF HALIDES 343 9.2.1 EXCITONS AND HOLES ON SURFACES 343
9.2.2 MECHANISMS FOR THE SPUTTERING OF ALKALI HALIDES 345 9.2.3
SPUTTERING OF OTHER HALIDES 360 9.3 SPUTTERING AND SURFACE MODIFICATION
OF OXIDES 364 9.3.1 EMISSIONS BY CORE EXCITATION 364 9.3.2 SURFACE
MODIFICATION OF QUARTZ 365 9.3.3 LASER EXCITATION OF OTHER OXIDES 367
9.4 SEMICONDUCTORS 368 9.4.1 ATOMIC EMISSIONS FROM SEMICONDUCTORS BY
LASER IRRADIATION 369 9.4.2 STM OBSERVATION OF PHOTO-INDUCED ATOMIC
EMISSION FROM SI SURFACES 373 9.4.3 PHOTO-INDUCED SURFACE MODIFICATION
OF COMPOUND SEMICONDUCTORS 374 9.4.4 SCANNING PROBE MICROSCOPY REMOVAL
OF ATOMS 375 SUMMARY 378 10 INTERFACE REACTIONS INDUCED BY ELECTRONIC
EXCITATION 379 10.1 ATOMIC AND ELECTRONIC STRUCTURES OF THE INTERFACES
380 10.1.1 INTERFACE ATOMIC STRUCTURES 3 80 10.1.2 INTERFACES BETWEEN
CRYSTALLINE AND NON-CRYSTALLINE SOLIDS 383 10.1.3 DEFECTS AT INTERFACES
387 10.2 ENERGY AND CHARGE DEPOSITION NEAR INTERFACES: THE MODIFICATION
OF INTERFACES 387 10.2.1 ENERGY DEPOSITION BY ELASTIC ENCOUNTERS 387
10.2.2 ENERGY DEPOSITION BY ELECTRONIC EXCITATION 388 10.3 PHOTO-INDUCED
PROCESSES AT INTERFACES 389 10.3.1 LUMINESCENCE AT INTERFACES 389 10.3.2
MODIFICATION OF INTERFACE STRUCTURES 390 CONTENTS XI 10.4 MIXING AND
MOVEMENT OF IONS 392 10.4.1 MIXING BY ELASTIC ENCOUNTERS 392 10.4.2
MIXING BY ELECTRONIC EXCITATION 393 10.5 RADIATION-ENHANCED ADHESION 394
10.5.1 PHENOMENOLOGY 394 10.5.2 SUMMARY OF EXISTING DATA 395 10.5.3 HOW
TO INTERPRET RADIATION-ENHANCED ADHESION 397 10.5.4 RELATED PHENOMENA:
ANODIC BONDING 399 10.6 OXIDATION AND CHEMICAL REACTIONS AT INTERFACES
400 10.7 AMORPHISATION AND RECRYSTALLISATION 404 SUMMARY 405 11 HIGH
EXCITATION INTENSITIES 407 11.1 INTRODUCTION 407 1.1.1 THERMAL MODELS OF
MODIFICATION 409 1.1.2 NON-UNIFORM DAMAGE 410 1.1.3 THE EARLY STAGES OF
ENERGY DEPOSITION 411 1.1.4 PROCESSING BY HIGH-INTENSITY EXCITATION 412
1.1.5 SPUTTERING BY ION BEAMS 413 11.2 LASER ANNEALING 415 11.3 LASER
DAMAGE 418 11.4 LASER ABLATION 422 11.4.1 ENERGY ABSORPTION AND TRANSFER
423 11.4.2 GAPS LESS THAN THE LASER PHOTON ENERGY 425 11.4.3 GAPS IN
EXCESS OF THE LASER PHOTON ENERGY: EFFECTS OF PRE-EXISTING DEFECTS 426
11.4.4 MESOSCOPIC MODELLING OF LASER ABLATION 429 11.5 LITHOGRAPHY AND
NANOLITHOGRAPHY 431 11.5.1 LITHOGRAPHY BY ELECTRON BEAMS 431 11.5.2
NANOLITHOGRAPHY OF MGO AND OTHER OXIDES 433 11.5.3 NANOLITHOGRAPHY AND
ANALOGOUS PHENOMENA IN OTHER INORGANIC MATERIALS 435 11.6 IRRADIATION
WITH HEAVY IONS 435 11.6.1 PROCESSES TAKING PLACE NEAR GEV HEAVY-ION
PATHS IN THE FIRST FEW FEMTOSECONDS 436 11.6.2 REGISTRATION OF HEAVY-ION
TRACKS 438 11.6.3 EFFECTS OF HEAVY-ION IRRADIATION ON SURFACES AND
INTERFACES 439 11.6.4 THE COULOMB EXPLOSION MODEL 440 11.6.5 THERMAL
SPIKE MODEL 441 11.6.6 EXCITONIC MODEL 441 SUMMARY 443 XLL CONTENTS 12
APPLICATIONS OF MATERIALS MODIFICATION BY EXCITATION 444 12.1 AIMS OF
MATERIALS MODIFICATION 444 12.2 MODIFYING SURFACE AND NEAR-SURFACE
REGIONS 448 12.3 MODIFYING THE BULK SOLID 453 12.4 DAMAGE AND
DETERIORATION 458 12.5 CHANGING RATES AND ALTERING PROCESSES 462 12.6
CONCLUDING COMMENTS 464 SUMMARY 465 REFERENCES 467 INDEX 509
|
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| author | Itoh, Noriaki Stoneham, Arthur M. 1940- |
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| dewey-full | 620.1/1228 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 620 - Engineering and allied operations |
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| dewey-search | 620.1/1228 |
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| id | DE-604.BV013690220 |
| illustrated | Illustrated |
| indexdate | 2024-12-20T10:51:53Z |
| institution | BVB |
| isbn | 0521554985 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-009355029 |
| oclc_num | 43076814 |
| open_access_boolean | |
| owner | DE-703 DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-11 |
| owner_facet | DE-703 DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-11 |
| physical | XV, 520 S. graph. Darst. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | Cambridge Univ. Press |
| record_format | marc |
| spellingShingle | Itoh, Noriaki Stoneham, Arthur M. 1940- Materials modification by electronic excitation Excitation électronique Faisceaux laser Faisceaux électroniques Matériaux, Effets du rayonnement sur les Electron beams Electronic excitation Laser beams Materials Effect of radiation on Stoffeigenschaft (DE-588)4192147-1 gnd Festkörper (DE-588)4016918-2 gnd Elektronische Anregung (DE-588)4463785-8 gnd |
| subject_GND | (DE-588)4192147-1 (DE-588)4016918-2 (DE-588)4463785-8 |
| title | Materials modification by electronic excitation |
| title_auth | Materials modification by electronic excitation |
| title_exact_search | Materials modification by electronic excitation |
| title_full | Materials modification by electronic excitation N. Itoh and A. M. Stoneham |
| title_fullStr | Materials modification by electronic excitation N. Itoh and A. M. Stoneham |
| title_full_unstemmed | Materials modification by electronic excitation N. Itoh and A. M. Stoneham |
| title_short | Materials modification by electronic excitation |
| title_sort | materials modification by electronic excitation |
| topic | Excitation électronique Faisceaux laser Faisceaux électroniques Matériaux, Effets du rayonnement sur les Electron beams Electronic excitation Laser beams Materials Effect of radiation on Stoffeigenschaft (DE-588)4192147-1 gnd Festkörper (DE-588)4016918-2 gnd Elektronische Anregung (DE-588)4463785-8 gnd |
| topic_facet | Excitation électronique Faisceaux laser Faisceaux électroniques Matériaux, Effets du rayonnement sur les Electron beams Electronic excitation Laser beams Materials Effect of radiation on Stoffeigenschaft Festkörper Elektronische Anregung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009355029&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT itohnoriaki materialsmodificationbyelectronicexcitation AT stonehamarthurm materialsmodificationbyelectronicexcitation |
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| Signatur: |
0049 B.18.D.02.2003 A 17 Lageplan |
|---|---|
| Exemplar 1 | Dauerhaft ausgeliehen Ausgeliehen – Rückgabe bis: 31.12.9999 |