Parametric sensitivity in chemical systems:
Gespeichert in:
| Beteiligte Personen: | , , |
|---|---|
| Format: | Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
Cambridge [u.a.]
Cambridge Univ. Press
1999
|
| Ausgabe: | 1. publ. |
| Schriftenreihe: | Cambridge series in chemical engineering
|
| Schlagwörter: | |
| Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008687120&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| Umfang: | XVI, 342 S. |
| ISBN: | 0521621712 |
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Datensatz im Suchindex
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| adam_text | PARAMETRIC SENSITIVITY IN CHEMICAL SYSTEMS A. VARMA M. MORBIDELLI H.WU
CAMBRIDGE UNIVERSITY PRESS CONTENTS PREFACE PAGE XV 1 INTRODUCTION 1 I .
I THE CONCEPT OF SENSITIVITY 1 1.2 USES OF THE SENSITIVITY CONCEPT 5 1.3
OVERVIEW OF THE BOOK CONTENTS 7 REFERENCES 8 2 INTRODUCTION TO
SENSITIVITY ANALYSIS 9 2.1 SENSITIVITY INDICES 9 2.1.1 LOCAL SENSITIVITY
9 EXAMPLE 2.1 CONVERSION SENSITIVITY IN A BATCH REACTOR 11 2.1.2
OBJECTIVE SENSITIVITY 13 EXAMPLE 2,2 SENSITIVITY OF THE MAXIMUM YIELD IN
AN ISOTHERMAL BATCH REACTOR WITH CONSECUTIVE REACTIONS 14 2.1.3 GLOBAL
SENSITIVITY 16 2.2 COMPUTATION OF SENSITIVITY INDICES 17 2.2.1 LOCAL
SENSITIVITY 17 EXAMPLE 2.3 SENSITIVITY ANALYSIS OF AN ISOTHERMAL BATCH
REACTOR WITH CONSECUTIVE REACTIONS OF ARBITRARY ORDER 18 2.2.2 GLOBAL
SENSITIVITY 24 NOMENCLATURE 32 REFERENCES 33 3 THERMAL EXPLOSION IN
BATCH REACTORS 3 6 3.1 BASIC EQUATIONS 37 3.2 GEOMETRY-BASED CRITERIA
FOR THERMAL RUNAWAY 38 3.2.1 THE CASE OF NEGLIGIBLE REACTANT
CONSUMPTION: SEMENOV THEORY 38 IX PARAMETRIC SENSITIVITY IN CHEMICAL
SYSTEMS EXAMPLE 3.1 APPLICATION OF SEMENOV CRITERION TO THERMAL
EXPLOSION OF METHYL NITRATE 43 3.2.2 CRITERIA ACCOUNTING FOR REACTANT
CONSUMPTION 44 EXAMPLE 3.2 APPLICATION OF AE AND VF CRITERIA TO THERMAL
EXPLOSION OF METHYL NITRATE 53 3.3 SENSITIVITY-BASED CRITERIA FOR
THERMAL RUNAWAY 55 3.3.1 THE MORBIDELLI AND VARMA (MV) CRITERION 56
EXAMPLE 3.3 APPLICATION OF THE MV CRITERION TO CATALYTIC HYDROLYSIS OF
ACETIC ANHYDRIDE 63 3.3.2 THE VAJDA AND RABITZ (VR) CRITERION 64 EXAMPLE
3.4 A COMPARISON BETWEEN VARIOUS CRITERIA IN PREDICTING EXPLOSION LIMITS
IN AZOMETHANE DECOMPOSITION 67 3.3.3 THE STROZZI AND ZALDIVAR (SZ)
CRITERION 69 3.4 EXPLICIT CRITERIA FOR THERMAL RUNAWAY 70 NOMENCLATURE
76 REFERENCES 77 4 RUNAWAY IN TUBULAER REACTORS 80 4.1 BASIC EQUATIONS
FOR TUBULAER PLUG-FLOW REACTORS 81 4.2 PLUG-FLOW REACTORS WITH CONSTANT
EXTERNAL COOLING 83 4.2.1 RUNAWAY CRITERIA 83 EXAMPLE 4.1 RUNAWAY
BEHAVIOR IN THE NAPHTHALENE OXIDATION REACTOR 85 4.2.2 THE REGION OF
PSEUDO-ADIABATIC OPERATION (PAO) 89 4.2.3 INFLUENCE OF PAO ON THE
RUNAWAY REGION 94 EXAMPLE 4.2 RUNAWAY BEHAVIOR IN A NAPHTHALENE
OXIDATION REACTOR OPERATING IN THE PSEUDO-ADIABATIC OPERATION REGION 100
4.3 PLUG-FLOW REACTORS VARYING COOLANT TEMPERATURE 101 4.3.1 THE REGIONS
OF PSEUDO-ADIABATIC OPERATION 101 4.3.2 INFLUENCE OF PAO ON RUNAWAY
REGIONS 104 4.4 ROLE OF RADIAL TEMPERATURE AND CONCENTRATION GRADIENTS
111 4.5 COMPLEX KINETIC SCHEMES 116 I 2 4.5.1 THE CASE OF TWO
CONSECUTIVE REACTIONS (A * SS * C) 119 EXAMPLE 4.3 REACTOR OPERATION
DIAGRAM FOR NAPHTHALENE OXIDATION PROCESS 130 4.5.2 THE CASE OF TWO
PARALLEL REACTIONS (A -U SS; A -^ C) 132 EXAMPLE 4.4 REACTOR OPERATION
DIAGRAM FOR ETHYLENE EPOXIDATION PROCESS 13 5 NOMENCLATURE 138
REFERENCES 140 X CONTENTS 5 PARAMETRIC SENSITIVITY IN CONTINUOUS-FLOW
STIRRED TANK REACTORS 143 5.1 SENSITIVITY ANALYSIS 144 5.2 REGIONS OF
PARAMETRICALLY SENSITIVE BEHAVIOR 152 5.2.1 ROLE OFTHE INVOLVED
PHYSICOCHEMICAL PARAMETERS 152 5.2.2 RELATION BETWEEN MULTIPLICITY AND
SENSITIVITY BEHAVIOR 157 5.3 ROLE OF MIXING ON REACTOR PARAMETRIC
SENSITIVITY 159 5.4 EXPLICIT CRITERIA FOR PARAMETRIC SENSITIVITY 163
NOMENCLATURE 166 REFERENCES 167 6 RUNAWAY IN FIXED-BED CATALYTIC
REACTORS 169 6.1 THE HETEROGENEOUS MODEL OF A FIXED-BED CATALYTIC
REACTOR 170 6.2 RUNAWAY OF A SINGLE CATALYST PARTICLE: LOCAL RUNAWAY 172
6.2.1 CRITICAL CONDITIONS FOR LOCAL RUNAWAY OF PARTICLE TEMPERATURE 173
6.2.2 RUNAWAY REGIONS 179 6.3 RUNAWAY OF FIXED-BED REACTORS: GLOBAL
RUNAWAY 189 6.3.1 CRITICAL CONDITIONS FOR GLOBAL RUNAWAY OF PARTICLE
TEMPERATURE 189 6.3.2 RUNAWAY REGIONS 192 EXAMPLE 6.1 EXPERIMENTAL
ANALYSIS OF RUNAWAY IN AIIXED-BED REACTOR FOR VINYL ACETATE SYNTHESIS
196 EXAMPLE 6.2 EXPERIMENTAL ANALYSIS OF RUNAWAY IN A FIXED-BED REACTOR
FOR CARBON MONOXIDE OXIDATION 203 6.3.3 LIMITING BEHAVIOR 205 EXAMPLE
6.3 RUNAWAY REGIONS IN THE CASE OF SEVERE INTRAPARTICLE MASS TRANSFER
RESISTANCE 206 6.3.4 EFFECT OF PSEUDO-ADIABATIC OPERATION ON RUNAWAY
REGIONS 208 6.4 EXPLICIT CRITERIA FOR RUNAWAY 213 NOMENCLATURE 216
REFERENCES 218 7 PARAMETRIC SENSITIVITY AND IGNITION PHENOMENA IN
COMBUSTION SYSTEMS 220 7.1 GENERAL DEFINITION OF IGNITION LIMITS 221 7.2
EXPLOSION LIMITS IN HYDROGEN-OXYGEN MIXTURES 224 7.2.1 APPLICATION OFTHE
SENSITIVITY CRITERION 224 7.2.2 COMPARISON BETWEEN EXPERIMENTAL AND
CALCULATED EXPLOSION LIMITS 231 XI PARAMETRIC SENSITIVITY IN CHEMICAL
SYSTEMS 7.3 FURTHER INSIGHT INTO EXPLOSION BEHAVIOR IN HYDROGEN-OXYGEN
MIXTURES 234 7.3.1 EXPLOSION IN THE LOW PRESSURE REGION 235 7.3.2
EXPLOSION IN THE HIGH PRESSURE REGION 243 REFERENCES * 244 8 SENSITIVITY
ANALYSIS IN MECHANISTIC STUDY AND MODEL REDUCTION 247 8.1 SENSITIVITY
ANALYSIS IN MECHANISTIC STUDIES 248 8.1.1 APPLICATIONS OF THE GREEN S
FUNCTION METHOD 249 EXAMPLE 8.1 OXIDATION OF WET CARBON MONOXIDE 250
EXAMPLE 8.2 SENSITIVITY ANALYSIS OF THE BELOUSOV- ZHABOTINSKY
OSCILLATING REACTION 254 8.1.2 APPLICATIONS OF THE FINITE DIFFERENCE
METHOD 259 EXAMPLE 8.3 EXPLOSION MECHANISM IN HYDROGEN-OXYGEN SYSTEMS:
THE FIRST LIMIT 260 EXAMPLE 8,4 EXPLOSION MECHANISM IN HYDROGEN-OXYGEN
SYSTEMS: THE SECOND LIMIT 265 EXAMPLE 8.5 EXPLOSION MECHANISM IN
HYDROGEN-OXYGEN SYSTEMS: THE THIRD LIMIT 269 EXAMPLE 8.6 EXPLOSION
MECHANISM IN HYDROGEN-OXYGEN SYSTEMS: THE WEAK-STRONG EXPLOSION
BOUNDARIES (WSEB) 271 8.2 REDUCTION OF DETAILED KINETIC MODELS 273
EXAMPLE 8.7 MINIMUM REDUCED KINETIC MODEL FORTHE EXPLOSION LIMITS OF
HYDROGEN-OXYGEN SYSTEMS 274 EXAMPLE 8.8 REDUCED KINETIC MODEL FOR THE
COMBUSTION OF METHANE-ETHANE SYSTEMS 280 REFERENCES 284 9 SENSITIVITY
ANALYSIS IN AIR POLLUTION 287 9.1 BASIC EQUATIONS 288 9.2 SENSITIVITY
ANALYSIS OF REGIONAL AIR QUALITY WITH RESPECT TO EMISSION SOURCES 290
9.2.1 DEFINITION OF SENSITIVITIES 290 9.2.2 A CASE STUDY: EMISSIONS OF
NO X AND SO2 IN THE EASTERN UNITED STATES 292 9.3 GLOBAL SENSITIVITY
ANALYSIS OF TRAJECTORY MODEL FOR PHOTOCHEMICAL AIR POLLUTION 302 9.3.1
GLOBAL SENSITIVITIES AND THE FAST METHOD 302 9.3.2 A CASE STUDY:
EMISSIONS OF NO, NO2, REACTIVE HYDROCARBONS AND O3 303 REFERENCES 310
XII CONTENTS 10 SENSITIVITY ANALYSIS IN METABOLIE PROCESSES 312 10.1 THE
GENERAL APPROACH FOR SENSITIVITY ANALYSIS 313 10.1.1 MATHEMATICAL
FRAMEWORK 313 10.1.2 A CASE STUDY: THE YEAST GLYCOLYTIC PATHWAY 317 1
0.2 THE MATRIX METHOD FROM METABOLIE CONTROL THEORY 320 10.2.1 MODEL
FRAMEWORK 322 10.2.2 A CASE STUDY: THE METABOLIE PATHWAY OF
GLUCONEOGENESIS FROM LACTATE 324 1 0.2.3 SOME USEFUI THEOREMS FOR
SENSITIVITY ANALYSIS 328 NOMENCLATURE 330 REFERENCES 331 AUTHOR INDEX
335 SUBJECT INDEX 339 XIII
|
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| indexdate | 2024-12-20T10:36:01Z |
| institution | BVB |
| isbn | 0521621712 |
| language | English |
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| physical | XVI, 342 S. |
| publishDate | 1999 |
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| publisher | Cambridge Univ. Press |
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| series2 | Cambridge series in chemical engineering |
| spellingShingle | Varma, Arvind Morbidelli, Massimo Wu, Hua Parametric sensitivity in chemical systems Procédés chimiques - Modèles mathématiques Mathematisches Modell Chemical processes Mathematical models Mathematisches Modell (DE-588)4114528-8 gnd Chemischer Prozess (DE-588)4147636-0 gnd |
| subject_GND | (DE-588)4114528-8 (DE-588)4147636-0 |
| title | Parametric sensitivity in chemical systems |
| title_auth | Parametric sensitivity in chemical systems |
| title_exact_search | Parametric sensitivity in chemical systems |
| title_full | Parametric sensitivity in chemical systems A. Varma ; M. Morbidelli ; H. Wu |
| title_fullStr | Parametric sensitivity in chemical systems A. Varma ; M. Morbidelli ; H. Wu |
| title_full_unstemmed | Parametric sensitivity in chemical systems A. Varma ; M. Morbidelli ; H. Wu |
| title_short | Parametric sensitivity in chemical systems |
| title_sort | parametric sensitivity in chemical systems |
| topic | Procédés chimiques - Modèles mathématiques Mathematisches Modell Chemical processes Mathematical models Mathematisches Modell (DE-588)4114528-8 gnd Chemischer Prozess (DE-588)4147636-0 gnd |
| topic_facet | Procédés chimiques - Modèles mathématiques Mathematisches Modell Chemical processes Mathematical models Chemischer Prozess |
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