Verfügbarkeit: Physics of highly excited atoms and ions

Physics of highly excited atoms and ions:

Gespeichert in:

Bibliographische Detailangaben
Beteiligte Personen:	Lebedev, Vladimir S. (VerfasserIn), Bejgman, Izrail L. 1940- (VerfasserIn)
Format:	Buch
Sprache:	Englisch
Veröffentlicht:	Berlin [u.a.] Springer 1998
Schriftenreihe:	Springer series on atoms + plasmas 22
Schlagwörter:	Atomic spectroscopy Ions > Spectra Rydberg states Atomspektroskopie Atom Ionenspektroskopie Rydberg-Zustand Ion Angeregter Zustand
Links:	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008190001&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Umfang:	X, 298 S. graph. Darst.
ISBN:	354064234X

Internformat

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Datensatz im Suchindex

DE-BY-TUM_call_number	0202 PHY 503f 2002 A 4092
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adam_text	V. S. LEBEDEV I. L. BEIGMAN PHYSICS OF HIGHLY EXCITED ATOMS AND IONS WITH 59 FIGURES SPRINGER CONTENTS 1. INTRODUCTION 1 1.1 PHYSICAL PROPERTIES AND FEATURES OF RYDBERG ATOMS AND IONS 1 1.2 SCOPE OF THE BOOK 7 2. CLASSICAL AND QUANTUM DESCRIPTION OF RYDBERG ATOM .... 11 2.1 CLASSICAL MOTION IN A COULOMB FIELD 11 2.1.1 ORBITAL ELECTRON MOTION 11 2.1.2 ACTION VARIABLES 14 2.2 WAVE FUNCTIONS: COORDINATE REPRESENTATION 17 2.2.1 QUANTUM WAVE FUNCTION OF HYDROGEN-LIKE STATES 17 2.2.2 JWKB APPROXIMATION 21 2.2.3 SEMICLASSICAL APPROACH IN ACTION VARIABLES 24 2.3 WAVE FUNCTIONS: MOMENTUM REPRESENTATION 26 2.3.1 HYDROGENLIKE WAVE FUNCTIONS 26 2.3.2 MOMENTUM WAVE FUNCTIONS WITH QUANTUM DEFECT.... 28 2.4 DENSITY MATRIX AND DISTRIBUTION FUNCTION 28 2.4.1 CLASSICAL DISTRIBUTION FUNCTIONS 28 2.4.2 COULOMB GREEN S FUNCTION : 31 2.4.3 DENSITY MATRIX 33 2.4.4 WIGNER FUNCTION . . 36 3. RADIATIVE TRANSITIONS AND FORM FACTORS 39 3.1 PROBABILITIES OF RADIATIVE TRANSITIONS 39 3.1.1 GENERAL FORMULAS 39 3.1.2 SEMICLASSICAL AND ASYMPTOTIC APPROACHES 40 3.1.3 SUMMED OVER ANGULAR QUANTUM NUMBERS LINE STRENGTH. KRAMERS APPROXIMATION 43 3.2 PHOTOIONIZATION AND PHOTORECOMBINATION 44 3.2.1 GENERAL FORMULAS 44 3.2.2 ASYMPTOTIC APPROACH ; 44 3.2.3 KRAMERS FORMULAS AND GAUNT FACTOR 45 3.3 TRANSITION FORM FACTORS 46 3.3.1 GENERAL FORMULAS 46 3.3.2 N * RT! TRANSITIONS: QUANTUM EXPRESSIONS 47 VIII CONTENTS 3.3.3 N * N TRANSITIONS: ASYMPTOTIC EXPRESSIONS 49 3.3.4 NL * NL TRANSITIONS: SEMICLASSICAL EXPRESSIONS 53 3.3.5 CLASSICAL APPROACH 54 3.3.6 ANGULAR FACTORS FOR COMPLEX ATOMS 55 4. BASIC APPROACHES TO COLLISIONS INVOLVING HIGHLY EXCITED ATOMS AND IONS 59 4.1 FORMULATION OF PROBLEM 59 4.1.1 FEATURES OF COLLISIONS WITH NEUTRAL AND CHARGED PARTICLES 59 4.1.2 STATIONARY PROBLEM OF SCATTERING 61 4.2 BORN APPROXIMATION: MOMENTUM REPRESENTATION 66 4.3 TIME-DEPENDENT APPROACH: IMPACT-PARAMETER REPRESENTATION 68 4.3.1 CLOSE COUPLED EQUATIONS FOR TRANSITION AMPLITUDES .. 69 4.3.2 NORMALIZED PERTURBATION THEORY 71 4.3.3 CONNECTION WITH MOMENTUM TRANSFER REPRESENTATION . 73 4.4 SEMICLASSICAL APPROACH IN ACTION VARIABLES 75 1.4. I CLASSICAL PERTURBATION THEORY 75 4.4.2 RELATION BETWEEN CLASSICAL AND QUANTUM VALUES 77 4.4.3 MODEL OF EQUIDISTANT LEVELS AND CORRESPONDENCE PRINCIPLE FOR 5-MATRIX 82 4.5 IMPULSE APPROXIMATION APPROACH 83 4.5.1 QUANTUM IMPULSE APPROXIMATION 84 4.5.2 BINARY ENCOUNTER APPROACH 89 5. COLLISIONS OF RYDBERG ATOM WITH NEUTRAL PARTICLES: WEAK-COUPLING MODELS 93 5.1 QUASI-FREE ELECTRON MODEL 93 5.2 SCATTERING OF ULTRA-SLOW ELECTRONS BY ATOMS AND MOLECULES . . 95 5.2.1 ELECTRON-ATOM SCATTERING 96 5.2.2 ELECTRON-MOLECULE SCATTERING 102 5.3 SEMICLASSICAL THEORY: IMPACT-PARAMETER APPROACH WITH FERMI PSEUDOPOTENTIAL 106 5.3.1 HISTORICAL SKETCH 106 5.3.2 PROBABILITIES OF THE NLJ - N L J AND NL * N V TRANSITIONS 107 5.3.3 BINARY-ENCOUNTER THEORY: NL * » N AND N ^ N TRANSITIONS 110 5.4 IMPULSE APPROXIMATION FOR RYDBERG ATOM-NEUTRAL COLLISIONS 116 5.4.1 INTRODUCTORY REMARKS 116 5.4.2 FAST AND SLOW COLLISIONS 118 5.4.3 CROSS SECTIONS OF SLOW COLLISIONS: GENERAL EXPRESSIONS 120 5.4.4 EXPRESSIONS THROUGH THE FORM FACTORS AND SCATTERING LENGTH APPROXIMATION 123 5.4.5 TOTAL SCATTERING CROSS SECTION 124 CONTENTS IX 5.4.6 RESONANCE ON QUASI-DISCRETE LEVEL 126 5.4.7 VALIDITY CRITERIA OF QUASI-FREE ELECTRON MODEL AND IMPULSE APPROXIMATION , 128 6. ELEMENTARY PROCESSES INVOLVING RYDBERG ATOMS AND NEUTRAL PARTICLES: EFFECTS OF ELECTRON-PROJECTILE INTERACTION 133 6.1 CLASSIFICATION OF PROCESSES AND THEORETICAL TREATMENTS 133 6.2 TRANSITIONS BETWEEN THE FINE-STRUCTURE COMPONENTS AND ELASTIC SCATTERING 136 6.2.1 WEAK COUPLING LIMIT 136 6.2.2 EXTENSION TO STRONG-COUPLING REGION 139 6.3 ORBITAL ANGULAR MOMENTUM AND ENERGY TRANSFER: /-MIXING AND N, /-CHANGING PROCESSES 142 6.3.1 SEMICLASSICAL UNITARIZED APPROACH TO INELASTIC NL ** N TRANSITIONS 142 6.3.2 QUASI-ELASTIC LIMIT: /MIXING PROCESS 145 6.3.3 EFFECTIVE SCATTERING LENGTH 147 6.3.4 SCALING LAWS 150 6.4 IONIZATION OF RYDBERG ATOM BY ATOMIC PROJECTILE 156 6.5 QUENCHING OF RYDBERG STATES: THERMAL COLLISIONS WITH ATOMS 157 6.5.1 COLLISIONS WITH RARE GAS ATOMS 158 6.5.2 COLLISIONS WITH ALKALI-METAL ATOMS 167 6.6 QUENCHING AND IONIZATION OF RYDBERG STATES: THERMAL COLLISIONS WITH MOLECULES 171 6.6.1 QUASI-RESONANT ENERGY EXCHANGE OF RYDBERG ELECTRON WITH ROTATIONAL MOTION OF MOLECULE 171 6.6.2 ION-PAIR FORMATION AND CHARGE TRANSFER: COLLISION OF RYDBERG ATOM WITH ELECTRON-ATTACHING MOLECULE .. 178 7. EFFECTS OF ION CORE IN RYDBERG ATOM-NEUTRAL COLLISIONS .. 183 7.1 MECHANISMS OF PERTURBER-CORE SCATTERING 183 7.2 SEPARATED-ATOMS APPROACH: SHAKE-UP MODEL 185 7.2.1 GENERAL TREATMENT 185 7.2.2 DIPOLE APPROXIMATION 189 7.3 QUASI-MOLECULAR APPROACH: BASIC ASSUMPTIONS 193 7.4 EXCHANGE OF RYDBERG ELECTRON ENERGY WITH TRANSLATIONAL MOTION OF ATOMS 196 7.4.1 MATRIX ELEMENTS OF TRANSITIONS WITHIN ONE ELECTRONIC TERM OF QUASI-MOLECULAR ION 196 7.4.2 CROSS SECTIONS OF DE-EXCITATION AND IONIZATION 198 7.4.3 COLLISIONS OF HIGHLY EXCITED HYDROGEN WITH HELIUM ... 200 7.5 RESONANT EXCITATION AND IONIZATION 202 7.5.1 EXCHANGE OF ELECTRON ENERGY IN QUASI-MOLECULE 202 X CONTENTS 7.5.2 DIPOLE TRANSITIONS BETWEEN SYMMETRICAL AND ANTISYMMETRICAL TERMS 205 7.5.3 QUADRUPOLE TRANSITIONS IN NONSYMMETRICAL COLLISIONS OF RARE GAS ATOMS 208 8. INELASTIC TRANSITIONS INDUCED BY COLLISIONS OF RYDBERG ATOM (ION) WITH CHARGED PARTICLES 213 8.1 BASIC PROBLEMS 213 8.2 N-CHANGING TRANSITIONS 215 8.2.1 CLASSICAL APPROACH 215 8.2.2 BORN APPROXIMATION 217 8.2.3 SEMICLASSICAL APPROACH 223 8.2.4 COULOMB-BORN APPROXIMATION 228 8.3 /-CHANGING TRANSITIONS 236 8.3.1 BORN APPROXIMATION 236 8.3.2 CLOSE COUPLING METHOD 238 8.3.3 METHOD OF EFFECTIVE MAGNETIC FIELD 242 8.3.4 FITTING FORMULAS 243 8.3.5 COMPARISON WITH EXPERIMENT 245 9. SPECTRAL-LINE BROADENING AND SHIFT 251 9.1 CLASSICAL AND QUANTUM TREATMENTS OF IMPACT BROADENING ... 251 9.1.1 IMPACT-PARAMETER METHOD 251 9.1.2 QUANTUM FORMULAS 255 9.2 THEORY OF WIDTH AND SHIFT OF RYDBERG LEVELS IN GAS 257 9.2.1 MECHANISM OF CORE-PERTURBER SCATTERING 258 9.2.2 MECHANISM OF ELECTRON-PERTURBER SCATTERING 259 9.3 COMPARISON OF THEORY WITH EXPERIMENT 262 9.3.1 BROADENING AND SHIFT IN RARE GASES 262 9.3.2 BROADENING AND SHIFT IN ALKALI-METAL VAPORS 266 9.4 BROADENING OF N N LINES IN A PLASMA 278 LIST OF SYMBOLS 283 REFERENCES 287 SUBJECT INDEX : 295
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series	Springer series on atoms + plasmas
series2	Springer series on atoms + plasmas
spellingShingle	Lebedev, Vladimir S. Bejgman, Izrail L. 1940- Physics of highly excited atoms and ions Springer series on atoms + plasmas Atomic spectroscopy Ions Spectra Rydberg states Atomspektroskopie (DE-588)4143333-6 gnd Atom (DE-588)4003412-4 gnd Ionenspektroskopie (DE-588)4455365-1 gnd Rydberg-Zustand (DE-588)4178785-7 gnd Ion (DE-588)4027597-8 gnd Angeregter Zustand (DE-588)4142423-2 gnd
subject_GND	(DE-588)4143333-6 (DE-588)4003412-4 (DE-588)4455365-1 (DE-588)4178785-7 (DE-588)4027597-8 (DE-588)4142423-2
title	Physics of highly excited atoms and ions
title_auth	Physics of highly excited atoms and ions
title_exact_search	Physics of highly excited atoms and ions
title_full	Physics of highly excited atoms and ions V. S. Lebedev ; I. L. Beigman
title_fullStr	Physics of highly excited atoms and ions V. S. Lebedev ; I. L. Beigman
title_full_unstemmed	Physics of highly excited atoms and ions V. S. Lebedev ; I. L. Beigman
title_short	Physics of highly excited atoms and ions
title_sort	physics of highly excited atoms and ions
topic	Atomic spectroscopy Ions Spectra Rydberg states Atomspektroskopie (DE-588)4143333-6 gnd Atom (DE-588)4003412-4 gnd Ionenspektroskopie (DE-588)4455365-1 gnd Rydberg-Zustand (DE-588)4178785-7 gnd Ion (DE-588)4027597-8 gnd Angeregter Zustand (DE-588)4142423-2 gnd
topic_facet	Atomic spectroscopy Ions Spectra Rydberg states Atomspektroskopie Atom Ionenspektroskopie Rydberg-Zustand Ion Angeregter Zustand
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008190001&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
volume_link	(DE-604)BV000903784
work_keys_str_mv	AT lebedevvladimirs physicsofhighlyexcitedatomsandions AT bejgmanizraill physicsofhighlyexcitedatomsandions

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