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Bibliographic Details
Main Author:	Sposito, Garrison 1939- (Author)
Format:	Book
Language:	English
Published:	Oxford Clarendon Press 1981
Links:	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001477234&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Physical Description:	XII, 223 S.: graph.Darst.
ISBN:	0198575688

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Record in the Search Index

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adam_text	Titel: The thermodynamics of soil solutions Autor: Sposito, Garrison Jahr: 1981 CONTENTS THE CHEMICAL THERMODYNAMICS OF SOIL SOLUTIONS 3 I. VARIABLES OF STATE AND THERMODYNAMIC POTENTIALS 1.1. Soils as thermodynamic systems 3 1.2. Thermodynamic processes in soils 6 1.3. Variables of state for thermodynamic soil systems 7 1.4. Thermodynamic potentials 10 1.5. Useful formal relationships 12 1.6. The Gibbs phase rule in thermodynamic soil systems 16 THE CHEMICAL THERMODYNAMICS OF SOIL SOLUTIONS 20 II. CHEMICAL EQUILIBRIUM 2.1. Thermal, mechanical, and chemical equilibria in soils 20 2.2. Standard States for soil components involved in isothermal, isobaric reactions 25 2.3. Thermodynamic activity and the equilibrium constant 33 2.4. Standard State chemical potentials 41 2.5. Standard State chemical potentials and the equilibrium constant 48 2.6. Reference States and activity coefficients 53 2.7. Conditional equilibrium constants 62 SOLUBILITY EQUILIBRIA IN SOJL SOLUTIONS 66 3.1. Solid phases and the activities of soil solution species 66 3.2. Predominance diagrams 69 3.3. The Principle of Hard and Soft Acids and Bases 75 3.4. Complex formation and metal solubility: Fundamental concepts 80 3.5. Complex formation and metal solubility: Applications 83 3.6. Activity ratio and solubility diagrams 88 3.7. Coprecipitated solid phases 94 ELECTROCHEMICAL EQUILIBRIA IN SOILS 102 4.1. Oxidation-reduction reactions in soils 102 4.2. The electron activity 107 4.3. Soluble redox species 111 4.4. p£-pH diagrams 114 4.5. Electrochemistry in soil solutions and suspensions 116 5. THE THERMODYNAMIC THEORY OF ION EXCHANGE 126 5.1. The ion exchange selectivity coefficient 126 5.2. Exchange isotherms 134 5.3. Mixed-exchanger systems 139 5.4. Exchanger phase activity coefficients and the exchange equilibrium constant 143 5.5. Specific adsorption 150 6. THE MOLECULAR THEORY OF CATION EXCHANGE 155 6.1. Fundamental principles 155 6.2. Exchange isotherms 160 6.3. The discrete site model 166 6.4. The diffuse double layer model 169 6.5. The surface complex model 178 7. THE THERMODYNAMIC THEORY OF WATER IN SOIL 187 7.1. Variables of state and thermodynamic potentials 187 7.2. Thermodynamic stability conditions 190 7.3. The chemical potential of soil water 193 7.4. Thermodynamic theory of the measurement of the water potential 7.5. The moisture characteristic: Hysteresis 201 7.6. Soil water in a gravitational field 205 SELECTED PHYSICAL CONSTANTS 209 INDEX OF PRINCIPAL SYMBOLS 210 INDEX OF SUBJECTS 221 INDEX OF AUTHORS 217
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isbn	0198575688
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physical	XII, 223 S.: graph.Darst.
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spellingShingle	Sposito, Garrison 1939- The thermodynamics of soil solutions
title	The thermodynamics of soil solutions
title_auth	The thermodynamics of soil solutions
title_exact_search	The thermodynamics of soil solutions
title_full	The thermodynamics of soil solutions Garrison Sposito
title_fullStr	The thermodynamics of soil solutions Garrison Sposito
title_full_unstemmed	The thermodynamics of soil solutions Garrison Sposito
title_short	The thermodynamics of soil solutions
title_sort	the thermodynamics of soil solutions
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001477234&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
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Call Number:	1001 76.2004 A 693 Floor plan
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