The thermodynamics of soil solutions:
Gespeichert in:
| Beteilige Person: | |
|---|---|
| Format: | Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
Oxford
Clarendon Press
1981
|
| Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001477234&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| Umfang: | XII, 223 S.: graph.Darst. |
| ISBN: | 0198575688 |
Internformat
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Datensatz im Suchindex
| DE-BY-TUM_call_number | 1001 76.2004 A 693 |
|---|---|
| DE-BY-TUM_katkey | 1468504 |
| DE-BY-TUM_location | Mag |
| DE-BY-TUM_media_number | 040050248307 |
| _version_ | 1821932979335725056 |
| adam_text | Titel: The thermodynamics of soil solutions
Autor: Sposito, Garrison
Jahr: 1981
CONTENTS
THE CHEMICAL THERMODYNAMICS OF SOIL SOLUTIONS 3
I. VARIABLES OF STATE AND THERMODYNAMIC POTENTIALS
1.1. Soils as thermodynamic systems 3
1.2. Thermodynamic processes in soils 6
1.3. Variables of state for thermodynamic soil systems 7
1.4. Thermodynamic potentials 10
1.5. Useful formal relationships 12
1.6. The Gibbs phase rule in thermodynamic soil systems 16
THE CHEMICAL THERMODYNAMICS OF SOIL SOLUTIONS 20
II. CHEMICAL EQUILIBRIUM
2.1. Thermal, mechanical, and chemical equilibria in soils 20
2.2. Standard States for soil components involved in isothermal, isobaric
reactions 25
2.3. Thermodynamic activity and the equilibrium constant 33
2.4. Standard State chemical potentials 41
2.5. Standard State chemical potentials and the equilibrium constant 48
2.6. Reference States and activity coefficients 53
2.7. Conditional equilibrium constants 62
SOLUBILITY EQUILIBRIA IN SOJL SOLUTIONS 66
3.1. Solid phases and the activities of soil solution species 66
3.2. Predominance diagrams 69
3.3. The Principle of Hard and Soft Acids and Bases 75
3.4. Complex formation and metal solubility: Fundamental concepts 80
3.5. Complex formation and metal solubility: Applications 83
3.6. Activity ratio and solubility diagrams 88
3.7. Coprecipitated solid phases 94
ELECTROCHEMICAL EQUILIBRIA IN SOILS 102
4.1. Oxidation-reduction reactions in soils 102
4.2. The electron activity 107
4.3. Soluble redox species 111
4.4. p£-pH diagrams 114
4.5. Electrochemistry in soil solutions and suspensions 116
5. THE THERMODYNAMIC THEORY OF ION EXCHANGE 126
5.1. The ion exchange selectivity coefficient 126
5.2. Exchange isotherms 134
5.3. Mixed-exchanger systems 139
5.4. Exchanger phase activity coefficients and the exchange equilibrium
constant 143
5.5. Specific adsorption 150
6. THE MOLECULAR THEORY OF CATION EXCHANGE 155
6.1. Fundamental principles 155
6.2. Exchange isotherms 160
6.3. The discrete site model 166
6.4. The diffuse double layer model 169
6.5. The surface complex model 178
7. THE THERMODYNAMIC THEORY OF WATER IN SOIL 187
7.1. Variables of state and thermodynamic potentials 187
7.2. Thermodynamic stability conditions 190
7.3. The chemical potential of soil water 193
7.4. Thermodynamic theory of the measurement of the water potential
7.5. The moisture characteristic: Hysteresis 201
7.6. Soil water in a gravitational field 205
SELECTED PHYSICAL CONSTANTS 209
INDEX OF PRINCIPAL SYMBOLS 210
INDEX OF SUBJECTS 221
INDEX OF AUTHORS 217
|
| any_adam_object | 1 |
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| author_facet | Sposito, Garrison 1939- |
| author_role | aut |
| author_sort | Sposito, Garrison 1939- |
| author_variant | g s gs |
| building | Verbundindex |
| bvnumber | BV002248014 |
| classification_rvk | RB 10160 |
| ctrlnum | (OCoLC)251975524 (DE-599)BVBBV002248014 |
| discipline | Geographie |
| format | Book |
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| id | DE-604.BV002248014 |
| illustrated | Not Illustrated |
| indexdate | 2024-12-20T07:48:17Z |
| institution | BVB |
| isbn | 0198575688 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001477234 |
| oclc_num | 251975524 |
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| owner_facet | DE-12 DE-703 DE-M49 DE-BY-TUM DE-706 |
| physical | XII, 223 S.: graph.Darst. |
| publishDate | 1981 |
| publishDateSearch | 1981 |
| publishDateSort | 1981 |
| publisher | Clarendon Press |
| record_format | marc |
| spellingShingle | Sposito, Garrison 1939- The thermodynamics of soil solutions |
| title | The thermodynamics of soil solutions |
| title_auth | The thermodynamics of soil solutions |
| title_exact_search | The thermodynamics of soil solutions |
| title_full | The thermodynamics of soil solutions Garrison Sposito |
| title_fullStr | The thermodynamics of soil solutions Garrison Sposito |
| title_full_unstemmed | The thermodynamics of soil solutions Garrison Sposito |
| title_short | The thermodynamics of soil solutions |
| title_sort | the thermodynamics of soil solutions |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001477234&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT spositogarrison thethermodynamicsofsoilsolutions |
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Bibliotheksmagazin
| Signatur: |
1001 76.2004 A 693 Lageplan |
|---|---|
| Exemplar 1 | Ausleihbar Am Standort |