An introduction to redox polymers for energy-storage applications:
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| Main Authors: | , , |
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| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
[2023]
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| Subjects: | |
| Links: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35090-2/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034075544&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| Physical Description: | xiv, 530 Seiten Illustrationen, Diagramme |
| ISBN: | 9783527350902 |
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| 100 | 1 | |a Schubert, Ulrich Sigmar |d 1969- |e Verfasser |0 (DE-588)113792077 |4 aut | |
| 245 | 1 | 0 | |a An introduction to redox polymers for energy-storage applications |c Ulrich S. Schubert, Andreas Winter, and George R. Newkome |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c [2023] | |
| 264 | 4 | |c ©2023 | |
| 300 | |a xiv, 530 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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| 653 | |a CHA0: Elektrochemie | ||
| 653 | |a Chemie | ||
| 653 | |a Chemistry | ||
| 653 | |a EG32: Wasserstoff, Batterien u. Brennstoffzellen | ||
| 653 | |a Electrochemistry | ||
| 653 | |a Elektrochemie | ||
| 653 | |a Energie | ||
| 653 | |a Energy | ||
| 653 | |a Hydrogen, Batteries & Fuel Cells | ||
| 653 | |a PY30: Polymersynthese | ||
| 653 | |a Polymer Science & Technology | ||
| 653 | |a Polymer Synthesis | ||
| 653 | |a Polymersynthese | ||
| 653 | |a Polymerwissenschaft u. -technologie | ||
| 653 | |a Wasserstoff, Batterien u. Brennstoffzellen | ||
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| 700 | 1 | |a Winter, Andreas |d 1972- |e Verfasser |0 (DE-588)1016244169 |4 aut | |
| 700 | 1 | |a Newkome, George R. |d 1938- |e Verfasser |0 (DE-588)1234616327 |4 aut | |
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Record in the Search Index
| _version_ | 1819326163890208768 |
|---|---|
| adam_text | V
CONTENTS
LIST
OF
ABBREVIATIONS
XI
1
THE
EMERGENCE
OF
REDOX
POLYMERS
IN
THE
FIELD
OF
ENERGY-STORAGE
APPLICATIONS
1
STUDY
GOALS
1
1.1
1.2
1.2.1
1.2.2
1.2.3
AN
INTRODUCTION
TO
BATTERY
SYSTEMS
1
REDOX
POLYMERS:
A
SHORT
VIEW
ON
THEIR
LONG
HISTORY
3
THE
FIRST
ERA
OF
REDOX
POLYMERS
4
THE
SECOND
ERA
OF
REDOX
POLYMERS
5
THE
THIRD
ERA
OF
REDOX
POLYMERS
9
REFERENCES
10
2
POLYMER-CONTAINING
BATTERIES
17
STUDY
GOALS
17
2.1
2.2
2.3
2.3.1
2.3.2
2.4
2.5
2.5.1
2.5.2
2.6
2.6.1
2.6.2
2.7
2.7.1
2.7.2
2.7.3
2.7.4
2.7.5
2.8
INTRODUCTION
17
WORKING
PRINCIPLES
21
CHARACTERIZATION
OF
ENERGY-STORAGE
DEVICES
23
PERFORMANCE
PARAMETERS
23
CHARGING/DISCHARGING
CHARACTERISTICS
25
BATTERY
HOUSING
27
SOLID-STATE
BATTERIES
INCORPORATING
POLYMERS,
AS
ACTIVE
MATERIALS
30
WORKING
PRINCIPLE
31
MATERIAL
REQUIREMENTS
33
CAPACITORS
INCORPORATING
POLYMERS,
AS
ACTIVE
MATERIALS
37
HISTORIC
DEVELOPMENT
AND
WORKING
PRINCIPLE
37
MATERIAL
REQUIREMENTS
41
REDOX-FLOW
BATTERIES
INCORPORATING
POLYMERS
AS
ACTIVE
MATERIALS
44
WORKING
PRINCIPLE
46
MATERIALS
REQUIREMENTS
47
AQUEOUS
PRFBS
50
ORGANIC
PRFBS
51
SUSPENSION
RFBS
53
CONCLUDING
REMARKS
58
REFERENCES
59
VI
CONTENTS
3
REDOX
POLYMERS:
ARCHITECTURES,
SYNTHESIS,
AND
CHARACTERIZATION
69
STUDY
GOALS
69
3.1
3.2
3.3
3.3.1
3.3.2
3.3.2.1
3.3.2.2
3.3.2.3
3.3.3
3.4
3.4.1
3.4.2
3.4.2.1
3.4.2.2
3.4.2.3
3.4.2.4
3.4.2.5
3.4.3
3.5
INTRODUCTION
69
POLYMER
ARCHITECTURE
VS.
BATTERY
CELL
PERFORMANCE
70
POLYMER
ARCHITECTURES
72
HOMOPOLYMERS
72
COPOLYMERS
73
ALTERNATING
COPOLYMERS
74
STATISTICAL
AND
GRADIENT
COPOLYMERS
76
BLOCK
COPOLYMERS
77
MISCELLANEOUS
POLYMER
ARCHITECTURES
80
POLYMERIZATION
METHODS
88
STEP-GROWTH
POLYMERIZATIONS
89
CHAIN-GROWTH
POLYMERIZATIONS
91
FREE-RADICAL
POLYMERIZATION
91
CONTROLLED
RADICAL
POLYMERIZATION
92
ANIONIC
POLYMERIZATION
100
CATIONIC
POLYMERIZATIONS
102
RING-OPENING
METATHESIS
POLYMERIZATIONS
(ROMP)
102
REDOX
POLYMERIZATIONS
103
TEMPO-CONTAINING
REDOX
POLYMERS:
A
CASE
STUDY
ON
HOW
THE
BACKBONE
STRUCTURE
INFLUENCES
THE
POLYMERIC
PROPERTIES
105
3.6
3.6.1
3.6.2
3.6.3
3.7
CHARACTERIZATION
OF
REDOX
POLYMERS
109
CYCLIC
VOLTAMMETRY
(CV)
109
ELECTROCHEMICAL
IMPEDANCE
SPECTROSCOPY
(EIS)
115
ELECTROCHEMICAL
METHODS
COUPLED
TO
OTHER
ANALYTICAL
TECHNIQUES
117
CONCLUDING
REMARKS
120
REFERENCES
121
4
CONJUGATED
POLYMERS
IN
THE
CONTEXT
OF
ENERGY-STORAGE
APPLICATIONS
133
STUDY
GOALS
133
4.1
4.2
4.2.1
4.2.2
4.2.3
4.2.4
INTRODUCTION
133
THE
CLASSIC
CONJUGATED
POLYMERS
AT
A
GLANCE
137
POLYANILINE
(PANI)
137
POLYPYRROLE
(PPY)
141
POLYTHIOPHENE
(PT)
AND
PEDOT:PSS
144
CONJUGATED
POLYMERS
FOR
ENERGY-STORAGE
APPLICATIONS:
GENERAL
CONSIDERATIONS
147
4.3
4.3.1
4.3.2
4.3.3
4.3.4
4.3.5
4.3.5.1
CONJUGATED
POLYMERS,
AS
ACTIVE
MATERIALS
FOR
BATTERY
SYSTEMS
150
POLYACETYLENE
151
POLYANILINE
156
POLYPYRROLE
164
POLYTHIOPHENE,
PEDOT,
AND
RELATED
POLYMERS
175
BEYOND
THE
BIG
THREE
:
MISCELLANEOUS
CONJUGATED
POLYMERS
182
POLY(P-PHENYLENE)
182
CONTENTS
VII
4.3
.5.2
POLYINDOLE
184
4.4
CONCLUDING
REMARKS
187
REFERENCES
188
5
REDOX-ACTIVE,
SULFUR-CONTAINING
POLYMERS
203
STUDY
GOALS
203
5.1
INTRODUCTION
203
5.2
FUNDAMENTALS
OF
SULFUR-CONTAINING
BATTERIES
204
5.3
COMPOSITE
ELECTRODES
INCORPORATING
SULFUR
AND
CONDUCTIVE
POLYMERS
206
5.3.1
POLYPYRROLE,
AS
THE
MATRIX
POLYMER
207
5.3.2
POLYANILINE,
AS
THE
MATRIX
POLYMER
210
5.3.3
POLYTHIOPHENE,
AS
THE
MATRIX
POLYMER
214
5.3.4
MISCELLANEOUS
MATRIX
POLYMERS
216
5.4
SULFUR-CONTAINING
POLYMERS
IN
BATTERY
APPLICATIONS
220
5.4.1
POLYMERS
CONTAINING
DISULFIDE
MOIETIES
220
5.4.2
POLYMERS
CONTAINING
OLIGOSULFIDE
OR
POLYSULFIDE
MOIETIES
226
5.4.3
BEYOND
SULFIDES:
POLYMERS
CONTAINING
OTHER
REDOX-ACTIVE
ORGANOSULFUR
MOIETIES
237
5.5
CONCLUDING
REMARKS
245
REFERENCES
246
6
RADICAL-CONTAINING
POLYMERS
FOR
ENERGY-STORAGE
APPLICATIONS
255
STUDY
GOALS
255
6.1
INTRODUCTION
255
6.2
ORGANIC
RADICAL
POLYMERS
258
6.2.1
FREE-RADICAL
MOIETIES
USED
IN
ORPS
258
6.2.2
INFLUENCE
OF
THE
BACKBONE
STRUCTURE
ON
THE
ORP
PROPERTIES
262
6.2.3
INFLUENCE
OF
THE
POLYMER
ARCHITECTURE
ON
THE
ORP
PROPERTIES
263
6.3
TEMPO-CONTAINING
POLYMERS
FOR
ENERGY-STORAGE
APPLICATIONS
272
6.3.1
TEMPO-CONTAINING
POLYMERS
IN
SOLID-STATE
BATTERIES
272
6.3.1.1
THE
SUCCESS
STORY
OF
PTMA
272
6.3.1.2
BEYOND
PTMA:
POLYMERS
WITH
VARIOUS
BACKBONE
STRUCTURES
279
6.3.2
TEMPO-CONTAINING
POLYMERS
IN
FLOW-CELL
APPLICATIONS
286
6.4
BEYOND
TEMPO:
OTHER
NITROXYL
MOIETIES
IN
ORPS
292
6.5
MISCELLANEOUS
FREE-RADICAL
MOIETIES
IN
ORPS
295
6.6
CONCLUDING
REMARKS
299
REFERENCES
301
7
POLYMERS
EQUIPPED
WITH
REDOX-ACTIVE
QUINONE
MOIETIES
309
STUDY
GOALS
309
7.1
INTRODUCTION
309
7.2
GENERAL
CONSIDERATIONS
REGARDING
CARBONYL
COMPOUNDS,
AS
ACTIVE
ELECTRODE
MATERIALS
312
73
QUINONE-CONTAINING
POLYMERS
FOR
ENERGY-STORAGE
APPLICATIONS
313
VIII
CONTENTS
7.3.1
7.3.2
7.4
7.5
POLYMERS
WITH
QUINONE
MOIETIES
WITHIN
THE
BACKBONE
315
POLYMERS
WITH
QUINONE
MOIETIES,
AS
SIDE
CHAINS
326
POLYKETONE-CONTAINING
POLYMERS
FOR
ENERGY-STORAGE
APPLICATIONS
330
POLYMERS,
WHICH
CONTAIN
MISCELLANEOUS
REDOX-ACTIVE
CARBONYL
MOIETIES
334
7.5.1
SIDE-CHAIN
POLYMERS,
WHICH
CONTAIN
REDOX-ACTIVE
CARBONYL
MOIETIES
334
7.5.2
MAIN-CHAIN
POLYMERS,
WHICH
CONTAIN
REDOX-ACTIVE
CARBONYL
MOIETIES
338
7.6
CONCLUDING
REMARKS
343
REFERENCES
344
8
POLYIMIDES
AND
RELATED
POLYMERS
IN
BATTERY
APPLICATIONS
349
STUDY
GOALS
349
8.1
8.2
8.3
8.3.1
8.3.2
8.4
8.5
8.6
INTRODUCTION
349
CONVENTIONAL
PIS,
AS
ACTIVE
MATERIALS
353
NON-CONVENTIONAL
PIS,
AS
ACTIVE
MATERIALS
363
POLYIMIDES
WITH
NON-INNOCENT
MOIETIES
WITHIN
THE
SPACER
363
POLYIMIDES
WITH
SUBSTITUENTS
ON
THE
DIIMIDE
CORE
371
CONJUGATED
POLYMERS
INCORPORATING
THE
CORE
OF
DIIMIDE
MOIETIES
374
MULTIDIMENSIONAL
POLYIMIDES
377
MISCELLANEOUS
POLYMER
STRUCTURES
INCORPORATING
REDOX-ACTIVE
IMIDE
MOIETIES
380
8.7
CONCLUDING
REMARKS
383
REFERENCES
384
9
POLYMERS
CONTAINING
REDOX-ACTIVE
VIOLOGEN-TYPE
MOIETIES
391
STUDY
GOALS
391
9.1
9.2
9.3
9.4
9.4.1
9.4.2
9.5
INTRODUCTION
391
VIOLOGEN-CONTAINING
POLYMERS
FOR
SOLID-STATE
BATTERIES
393
VIOLOGEN-CONTAINING
POLYMERS
FOR
SUPERCAPACITORS
403
VIOLOGEN-CONTAINING
POLYMERS
FOR
REDOX-FLOW
BATTERIES
406
AQUEOUS
REDOX-FLOW
BATTERIES
407
NONAQUEOUS
REDOX-FLOW
BATTERIES
409
CONCLUDING
REMARKS
413
REFERENCES
414
10
10.1
10.2
10.3
10.4
POLYMERS:
CONTAINING
REDOX-ACTIVE
N-HETEROCYCLIC
MOIETIES
419
INTRODUCTION
419
POLYMERS:
CONTAINING
TRIPHENYLAMINE
MOIETIES
421
POLYMERS:
CONTAINING
REDOX-ACTIVE
CARBAZOLE
MOIETIES
435
POLYMERS:
CONTAINING
REDOX-ACTIVE
5,10-DIHYDROPHENAZINE
MOIETIES
443
CONTENTS
IX
INDEX
521
10.5
10.6
POLYMERS:
CONTAINING
REDOX-ACTIVE
PHENAZINE
MOIETIES
450
POLYMERS:
CONTAINING
REDOX-ACTIVE
PHENOTHIAZINE
OR
PHENOXAZINE
MOIETIES
462
10.7
CONCLUDING
REMARKS
470
REFERENCES
471
11
REDOX-ACTIVE
METALLOPOLYMERS
479
STUDY
GOALS
479
11.1
11.2
11.3
11.4
11.5
INTRODUCTION
479
APPLICATIONS
RELATED
TO
REDOX-ACTIVE
METALLOPOLYMERS
481
FERROCENE-CONTAINING
POLYMERS
FOR
ENERGY-STORAGE
APPLICATIONS
482
BEYOND
FERROCENE:
OTHER
TYPES
OF
REDOX-ACTIVE
METALLOPOLYMERS
493
CONCLUDING
REMARKS
502
REFERENCES
502
12
STUDENTS
SECTION:
REPRESENTATIVE
EXERCISES
ON
REDOX
POLYMERS
AND
THEIR
USAGE
IN
ENERGY-STORAGE
APPLICATIONS
509
12.1
12.2
INTRODUCTION
509
PROBLEMS
509
REFERENCES
519
|
| any_adam_object | 1 |
| author | Schubert, Ulrich Sigmar 1969- Winter, Andreas 1972- Newkome, George R. 1938- |
| author_GND | (DE-588)113792077 (DE-588)1016244169 (DE-588)1234616327 |
| author_facet | Schubert, Ulrich Sigmar 1969- Winter, Andreas 1972- Newkome, George R. 1938- |
| author_role | aut aut aut |
| author_sort | Schubert, Ulrich Sigmar 1969- |
| author_variant | u s s us uss a w aw g r n gr grn |
| building | Verbundindex |
| bvnumber | BV048809583 |
| classification_rvk | ZP 4130 VN 6050 |
| ctrlnum | (OCoLC)1344380712 (DE-599)DNB1267778571 |
| discipline | Chemie / Pharmazie Energietechnik |
| format | Book |
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| id | DE-604.BV048809583 |
| illustrated | Illustrated |
| indexdate | 2024-12-20T19:52:31Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527350902 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-034075544 |
| oclc_num | 1344380712 |
| open_access_boolean | |
| owner | DE-29T DE-11 DE-703 |
| owner_facet | DE-29T DE-11 DE-703 |
| physical | xiv, 530 Seiten Illustrationen, Diagramme |
| publishDate | 2023 |
| publishDateSearch | 2023 |
| publishDateSort | 2023 |
| publisher | Wiley-VCH |
| record_format | marc |
| spellingShingle | Schubert, Ulrich Sigmar 1969- Winter, Andreas 1972- Newkome, George R. 1938- An introduction to redox polymers for energy-storage applications Redox-Akkumulator (DE-588)4480266-3 gnd Energiespeicherung (DE-588)4014722-8 gnd Batterie (DE-588)4004687-4 gnd Redoxpolymere (DE-588)4394331-7 gnd |
| subject_GND | (DE-588)4480266-3 (DE-588)4014722-8 (DE-588)4004687-4 (DE-588)4394331-7 |
| title | An introduction to redox polymers for energy-storage applications |
| title_auth | An introduction to redox polymers for energy-storage applications |
| title_exact_search | An introduction to redox polymers for energy-storage applications |
| title_full | An introduction to redox polymers for energy-storage applications Ulrich S. Schubert, Andreas Winter, and George R. Newkome |
| title_fullStr | An introduction to redox polymers for energy-storage applications Ulrich S. Schubert, Andreas Winter, and George R. Newkome |
| title_full_unstemmed | An introduction to redox polymers for energy-storage applications Ulrich S. Schubert, Andreas Winter, and George R. Newkome |
| title_short | An introduction to redox polymers for energy-storage applications |
| title_sort | an introduction to redox polymers for energy storage applications |
| topic | Redox-Akkumulator (DE-588)4480266-3 gnd Energiespeicherung (DE-588)4014722-8 gnd Batterie (DE-588)4004687-4 gnd Redoxpolymere (DE-588)4394331-7 gnd |
| topic_facet | Redox-Akkumulator Energiespeicherung Batterie Redoxpolymere |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35090-2/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=034075544&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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