Verfügbarkeit: Rubber reinforcement with particulate fillers

Rubber reinforcement with particulate fillers:

Gespeichert in:

Bibliographische Detailangaben
Beteiligte Personen:	Wang, Meng-Jiao (VerfasserIn), Morris, Michael (VerfasserIn)
Format:	Buch
Sprache:	Englisch
Veröffentlicht:	Cincinnati, Ohio ; Munich Hanser Publications [2021]
Schlagwörter:	Stoffeigenschaft Synthesekautschuk Kautschuk Siliciumdioxid Vulkanisat Teilchen Verstärkungswerkstoff Elastomer Ruß Grafit Füllstoff Gummiindustrie Gummi FBKTKAUT: Elastomere und Kautschuk PLAS2021
Links:	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032827221&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Umfang:	XIV, 589 Seiten Illustrationen, Diagramme 25 cm
ISBN:	9781569907191 1569907196

Internformat

MARC


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Datensatz im Suchindex

DE-BY-TUM_call_number	0702 WER 670 2021 A 2958
DE-BY-TUM_katkey	2575995
DE-BY-TUM_location	07
DE-BY-TUM_media_number	040009460455
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adam_text	CONTENTS PREFACE ................................................................................................... I ABOUT THE AUTHORS ................................................................................. IH 1. MANUFACTURE OF FILLERS ........................................................................ 1 1.1 MANUFACTURE OF CARBON BLACK ............................................................................ 3 1.1.1 MECHANISMS OF CARBON BLACK FORMATION .................................................. 3 1.1.2 MANUFACTURING PROCESS OF CARBON BLACK ................................................. 6 1.1.2.1 OIL-FURNACE PROCESS ............................................................................ 6 1.1.2.2 THE THERMAL BLACK PROCESS .............................................................. 10 1.1.2.3 ACETYLENE BLACK PROCESS .................................................................. 11 1.1.2.4 LAMPBLACK PROCESS ........................................................................... 11 1.1.2.5 IMPINGEMENT (CHANNEL, ROLLER) BLACK PROCESS ................................ 12 1.1.2.6 RECYCLE BLACKS ................................................................................... 12 1.1.2.7 SURFACE MODIFICATION OF CARBON BLACKS ........................................... 13 1.1.2.7.1 ATTACHMENTS OF THE AROMATIC RING NUCLEUS TO CARBON BLACK ............................................................................. 13 1.1.2.7.2 ATTACHMENTS TO THE AROMATIC RING STRUCTURE THROUGH OXIDIZED GROUPS ........................................................................ 13 1.1.2.7.3 METAL OXIDE TREATMENT .............................................................. 14 1.2 MANUFACTURE OF SILICA ........................................................................................ 14 1.2.1 MECHANISMS OF PRECIPITATED SILICA FORMATION ........................................ 15 1.2.2 MANUFACTURING PROCESS OF PRECIPITATED SILICA ......................................... 16 1.2.3 MECHANISMS OF FUMED SILICA FORMATION ................................................. 18 1.2.4 MANUFACTURE PROCESS OF FUMED SILICA ..................................................... 18 REFERENCES .................................................................................................................. 19 2. CHARACTERIZATION OF FILLERS ............................................................... 22 2.1 CHEMICAL COMPOSITION ...................................................................................... 23 2.1.1 CARBON BLACK ............................................................................................ 23 V 2.1.2 SILICA ............................................................................................................ 25 2.2 MICRO-STRUCTURE OF FILLERS ................................................................................27 2.2.1 CARBON BLACK ............................................................................................. 27 2.2.2 SILICA ........................................................................................................... 29 2.3 FILLER MORPHOLOGIES .......................................................................................... 29 2.3.1 PRIMARY PARTICLES-SURFACE AREA ................................................................ 29 2.3.1.1 TRANSMISSION ELECTRON MICROSCOPE (TEM) ..................................... 30 2.3.1.2 GAS PHASE ADSORPTIONS ...................................................................... 34 2.3.1.2.1 TOTAL SURFACE AREA MEASURED BY NITROGEN ADSORPTION - BET/NSA ............................................................ 35 2.3.1.2.2 EXTERNAL SURFACE AREA MEASURED BY NITROGEN ADSORPTION - STS A ................................................................... 41 2.3.1.2.3 MICRO-PORE SIZE DISTRIBUTION MEASURED BY NITROGEN ADSORPTION .................................................................. 46 2.3.1.3 LIQUID PHASE ADSORPTIONS ................................................................ 51 2.3.1.3.1 IODINE ADSORPTIONS ..................................................................... 52 2.3.1.3.2 ADSORPTION OF LARGE MOLECULES ................................................ 56 2.3.2 STRUCTURE-AGGREGATE SIZE AND SHAPE ....................................................... 61 2.3.2.1 TRANSMISSION ELECTRON MICROSCOPY .................................................. 62 2.3.2.2 DISC CENTRIFUGE PHOTOSEDIMENTOMETER ............................................ 66 2.3.2.3 VOID VOLUME MEASUREMENT .............................................................. 68 2.3.2.3.1 OIL ABSORPTION ............................................................................ 69 23.2.3.2 COMPRESSED VOLUME ................................................................. 75 23.2.3.3 MERCURY POROSIMETRY ................................................................. 80 2.3.3 TINTING STRENGTH ........................................................................................ 83 2.4 FILLER SURFACE CHARACTERISTICS ........................................................................... 92 2.4.1 CHARACTERIZATION OF SURFACE CHEMISTRY OF FILLER-SURFACE GROUPS .......... 92 2.4.2 CHARACTERIZATION OF PHYSICAL CHEMISTRY OF FILLER SURFACE-SURFACE ENERGY ............................................................................ 93 2.4.2.1 CONTACT ANGLE .................................................................................... 98 2.4.2.1.1 SINGLE LIQUID PHASE ...................................................................98 2.4.2.1.2 DUAL LIQUID PHASES ................................................................... 102 2.4.2.2 HEAT OF IMMERSION ........................................................................... 106 2.4.2.3 INVERSE GAS CHROMATOGRAPH ........................................................... 111 2.4.2.3.1 PRINCIPLE OF MEASURING FILLER SURFACE ENERGY WITH IGC ..... 111 2.4.2.3.2 ADSORPTION AT INFINITE DILUTION ............................................... 112 2.4.2.3.3 ADSORPTION AT FINITE CONCENTRATION ........................................ 118 2.4.2.3.4 SURFACE ENERGY OF THE FILLERS .................................................. 123 2.4.2.3.5 ESTIMATION OF RUBBER-FILLER INTERACTION FROM ADSORPTION ENERGY OF ELASTOMER ANALOGS ................................................ 139 2.4.2.4 BOUND RUBBER MEASUREMENT ......................................................... 142 VI REFERENCES ................................................................................................................ 143 3. EFFECT OF FILLERS IN RUBBER .............................................................. 153 3.1 HYDRODYNAMIC EFFECT - STRAIN AMPLIFICATION ............................................... 153 3.2 INTERFACIAL INTERACTION BETWEEN F ILL ER AND POLYMER ....................................... 155 3.2.1 BOUND RUBBER ......................................................................................... 155 3.2.2 RUBBER SHELL ........................................................................................... 159 3.3 OCCLUSION OF RUBBER ....................................................................................... 161 3.4 FILLER AGGLOMERATION ...................................................................................... 163 3.4.1 OBSERVATIONS OF FILLER AGGLOMERATION ................................................... 163 3.4.2 MODES OF FILLER AGGLOMERATION .............................................................. 164 3.4.3 THERMODYNAMICS OF FILLER AGGLOMERATION ............................................ 167 3.4.4 KINETICS OF FILLER AGGLOMERATION ........................................................... 170 REFERENCES ................................................................................................................ 173 4. FILLER DISPERSION ............................................................................. 177 4.1 BASIC CONCEPT OF FILLER DISPERSION ................................................................. 177 4.2 PARAMETERS INFLUENCING FILLER DISPERSION ...................................................... 179 4.3 LIQUID PHASE MIXING ....................................................................................... 187 REFERENCES ................................................................................................................ 191 5. EFFECT OF FILLERS ON THE PROPERTIES OF UNCURED COMPOUNDS ..... 193 5.1 BOUND RUBBER ................................................................................................ 193 5.1.1 SIGNIFICANCE OF BOUND RUBBER ............................................................ 194 5.1.2 MEASUREMENT OF BOUND RUBBER .......................................................... 195 5.1.3 NATURE OF BOUND RUBBER ATTACHMENT ................................................. 197 5.1.4 POLYMER MOBILITY IN BOUND RUBBER ................................................... 202 5.1.5 POLYMER EFFECTS ON BOUND RUBBER ..................................................... 203 5.1.5.1 MOLECULAR WEIGHT EFFECTS ........................................................... 203 5.1.5.2 POLYMER CHEMISTRY EFFECTS ......................................................... 203 5.1.6 EFFECT OF FILLER ON BOUND RUBBER ....................................................... 204 5.1.6.1 SURFACE AREA AND STRUCTURE .......................................................... 204 5.1.6.2 SPECIFIC SURFACE ACTIVITY OF CARBON BLACKS .............................. 206 5.1.6.3 EFFECT OF SURFACE CHARACTERISTICS ON BOUND RUBBER ................. 210 5.1.6.4 CARBON BLACK SURFACE MODIFICATION ............................................ 211 5.1.6.5 SILICA SURFACE MODIFICATION ........................................................... 215 5.1.7 EFFECT OF MIXING CONDITIONS ON BOUND RUBBER ............................... 215 5.1.7.1 TEMPERATURE AND TIME OF MIXING ................................................ 216 VN 5.1.7.2 MIXING SEQUENCE EFFECT OF RUBBER INGREDIENTS ....................... 218 5.1.7.2.1 MIXING SEQUENCE OF OIL AND OTHER ADDITIVES ................... 219 5.1.7.2.2 MIXING SEQUENCE OF SULFUR, SULFUR DONOR, AND OTHER CROSSLINKERS ................................................................ 221 5.1.7.2.3 BOUND RUBBER OF SILICA COMPOUNDS .................................. 222 5.1.7.3 BOUND RUBBER IN WET MASTERBATCHES ........................................ 223 5.1.7.4 BOUND RUBBER OF FUMED SILICA-FILLED SILICONE RUBBER ......... 225 5.2 VISCOSITY OF FILLED COMPOUNDS .................................................................. 227 5.2.1 FACTORS INFLUENCING VISCOSITY OF THE CARBON BLACK-FILLED COMPOUNDS ........................................................................................... 227 5.2.2 MASTER CURVE OF VISCOSITY VS. EFFECTIVE VOLUME OF CARBON BLACKS ....................................................................................... 230 5.2.3 VISCOSITY OF SILICA COMPOUNDS .......................................................... 233 5.2.4 VISCOSITY GROWTH - STORAGE HARDENING ............................................ 238 5.3 DIE SWELL AND SURFACE APPEARANCE OF THE EXTRUDATE .............................. 241 5.3.1 DIE SWELL OF CARBON BLACK COMPOUNDS ........................................... 241 5.3.2 DIE SWELL OF SILICA COMPOUNDS ......................................................... 246 5.3.3 EXTRUDATE APPEARANCE .......................................................................... 247 5.4 GREEN STRENGTH .............................................................................................. 249 5.4.1 EFFECT OF POLYMERS ................................................................................ 249 5.4.2 EFFECT OF FILLER PROPERTIES .................................................................... 252 REFERENCES ................................................................................................................ 255 6. EFFECT OF FILLERS ON THE PROPERTIES OF VULCANIZATES ................... 263 6.1 SWELLING ......................................................................................................... 263 6.2 STRESS-STRAIN BEHAVIOR ................................................................................. 271 6.2.1 LOW STRAIN ............................................................................................. 271 6.2.2 HARDNESS ................................................................................................. 274 6.2.3 MEDIUM AND HIGH STRAINS - THE STRAIN DEPENDENCE OF MODULUS .................................................................................................. 275 6.3 STRAIN-ENERGY LOSS - STRESS-SOFTENING EFFECT .......................................... 279 6.3.1 MECHANISMS OF STRESS-SOFTENING EFFECT ............................................ 282 6.3.1.1 GUM .................................................................................................. 282 6.3.1.2 FILLED VULCANIZATES ......................................................................... 283 6.3.1.3 RECOVERY OF STRESS SOFTENING ....................................................... 287 6.3.2 EFFECT OF FILLERS ON STRESS SOFTENING .................................................. 288 6.3.2.1 CARBON BLACKS ................................................................................ 288 6.3.2.1.1 EFFECT OF LOADING .................................................................. 288 6.3.2.1.2 EFFECT OF SURFACE AREA .......................................................... 289 VM 6.3.2.1.3 EFFECT OF STRUCTURE ................................................................. 290 6.3.2.2 PRECIPITATED SILICA ........................................................................ 290 6.4 FRACTURE PROPERTIES ........................................................................................ 295 6.4.1 CRACK INITIATION ..................................................................................... 295 6.4.2 TEARING .................................................................................................. 296 6.4.2.1 STATE OF TEARING ............................................................................. 296 6.4.2.1.1 EFFECT OF FILLER ...................................................................... 301 6.4.2.1.2 EFFECT OF POLYMER CRYSTALLIZABILITY AND NETWORK STRUCTURE ................................................................. 302 6.4.2.2 TEARING ENERGY .............................................................................. 306 6.4.2.2.1 EFFECT OF FILLER ....................................................................... 306 6.4.2.2.2 EFFECT OF POLYMER CRYSTALLIZABILITY AND NETWORK STRUCTURE ................................................................. 307 6.4.3 TENSILE STRENGTH AND ELONGATION AT BREAK ........................................ 315 6.4.4 FATIGUE ................................................................................................... 318 REFERENCES ............................................................................................................... 321 7. EFFECT OF FILLERS ON THE DYNAMIC PROPERTIES OF VULCANIZATES ................................................................................ 329 7.1 DYNAMIC PROPERTIES OF VULCANIZATES .......................................................... 329 7.2 DYNAMIC PROPERTIES OF FILLED VULCANIZATES .............................................. 332 7.2.1 STRAIN AMPLITUDE DEPENDENCE OF ELASTIC MODULUS OF FILLED RUBBER ......................................................................................... 332 7.2.2 STRAIN AMPLITUDE DEPENDENCE OF VISCOUS MODULUS OF FILLED RUBBER ......................................................................................... 340 7.2.3 STRAIN AMPLITUDE DEPENDENCE OF LOSS TANGENT OF FILLED RUBBER ......................................................................................... 343 7.2.4 HYSTERESIS MECHANISMS OF FILLED RUBBER CONCERNING DIFFERENT MODES OF FILLER AGGLOMERATION .......................................................... 348 7.2.5 TEMPERATURE DEPENDENCE OF DYNAMIC PROPERTIES OF FILLED VULCANIZATES ............................................................................... 350 7.3 DYNAMIC STRESS SOFTENING EFFECT ................................................................ 354 7.3.1 STRESS-SOFTENING EFFECT OF FILLED RUBBERS MEASURED WITH MODE 2 .......................................................................................... 355 7.3.2 EFFECT OF TEMPERATURE ON DYNAMIC STRESS-SOFTENING ...................... 359 7.3.3 EFFECT OF FREQUENCY ON DYNAMIC STRESS-SOFTENING .......................... 360 7.3.4 STRESS-SOFTENING EFFECT OF FILLED RUBBERS MEASURED WITH MODE 3 .................................................................................................. 362 7.3.5 EFFECT OF FILLER CHARACTERISTICS ON DYNAMIC K STRESS-SOFTENING AND HYSTERESIS 369 7.3.6 DYNAMIC STRESS-SOFTENING OF SILICA COMPOUNDS PRODUCED BY LIQUID PHASE MIXING 371 7.4 TIME-TEMPERATURE SUPERPOSITION OF DYNAMIC PROPERTIES OF FILLED VULCANIZATES 7.5 HEAT BUILD-UP 7.6 RESILIENCE ....................................................................................................... 387 REFERENCES 8. RUBBER REINFORCEMENT RELATED TO TIRE PERFORMANCE 394 8.1 ROLLING RESISTANCE 394 8.1.1 MECHANISMS OF ROLLING RESISTANCE - RELATIONSHIP BETWEEN ROLLING RESISTANCE AND HYSTERESIS 394 8.1.2 EFFECT OF FILLER ON TEMPERATURE DEPENDENCE OF DYNAMIC PROPERTIES 396 8.1.2.1 EFFECT OF FILLER LOADING 396 8.1.2.2 EFFECT OF FILLER MORPHOLOGY 397 8.1.2.2.1 EFFECT OF SURFACE AREA 397 8.1.2.2.2 EFFECT OF STRUCTURE 400 8.1.2.3 EFFECT OF FILLER SURFACE CHARACTERISTICS 402 8.1.2.3.1 EFFECT OF CARBON BLACK GRAPHITIZATION ON DYNAMIC PROPERTIES 403 8.1.2.3.2 COMPARISON OF CARBON BLACK AND SILICA 405 8.1.2.3.3 EFFECT OF FILLER BLENDS (BLEND OF SILICA AND CARBON BLACK, WITHOUT COUPLING AGENT) 408 8.1.2.3.4 EFFECT OF SURFACE MODIFICATION OF SILICA 411 8.1.2.3.5 EFFECT OF SURFACE MODIFICATION OF CARBON BLACK ON DYNAMIC PROPERTIES 414 8.1.2.3.6 CARBON/SILICA DUAL PHASE FILLER 418 8.1.2.3.7 POLYMERIC FILLER 423 8.1.3 MIXING EFFECT 425 8.1.4 PRECROSSLINKING EFFECT 428 8.2 SKID RESISTANCE - FRICTION 430 8.2.1 MECHANISMS OF SKID RESISTANCE 434 8.2.1.1 FRICTION AND FRICTION COEFFICIENTS - STATIC FRICTION AND DYNAMIC FRICTION 434 8.2.1.2 FRICTION BETWEEN TWO RIGID SOLID SURFACES 434 8.2.2 FRICTION OF RUBBER ON RIGID SURFACE 435 8.2.2.1 DRY FRICTION 435 X 8.2.2.1.1 ADHESION FRICTION ..................................................................... 435 8.2.2.1.2 HYSTERESIS FRICTION ................................................................... 437 8.2.2.2 WET FRICTION .................................................................................... 438 8.2.2.2.1 ELASTOHYDRODYNAMIC LUBRICATION ........................................... 439 8.2.2.2.2 THE THICKNESS OF LUBRICANT FILM FOR RUBBER SLIDING OVER RIGID ASPERITY ................................................................. 439 8.2.2.2.3 BOUNDARY LUBRICATION ............................................................. 439 8.2.2.2.4 DIFFERENCE IN BOUNDARY LUBRICATION BETWEEN RIGID-RIGID AND RIGID-ELASTOMER SURFACES ............................ 440 8.2.2.3 REVIEW OF FRICTIONAL PROPERTIES OF SOME TIRE TREAD MATERIALS .......................................................................................... 442 8.2.2.3 .1 CARBON AND GRAPHITE ................................................................ 442 8.2.2.3.2 GLASS ......................................................................................... 443 8.2.2.3.3 RUBBER ..................................................................................... 443 8.2.2.3.4 PREDICTION OF FRICTION OF FILLED RUBBERS ON DRY AND WET ROAD SURFACES BASED ON SURFACE CHARACTERISTICS OF DIFFERENT MATERIALS .................................................................. 444 8.2.2.4 MORPHOLOGY OF THE WORN SURFACE OF FILLED VULCANIZATES ............ 444 8.2.2.4. 1 COMPARISON OF POLYMER-FILLER INTERACTION BETWEEN CARBON BLACK AND SILICA ......................................................... 445 8.2.2.4.2 EFFECT OF BREAK-IN OF SPECIMENS UNDER WET CONDITIONS ON FRICTION COEFFICIENTS .......................................................... 448 8.2.2.4.3 ABRASION RESISTANCE OF FILLED VULCANIZATES UNDER WET AND DRY CONDITIONS ......................................................... 449 8.2.2.4.4 OBSERVATION OF THE CHANGE IN FRICTION COEFFICIENTS DURING SKID TEST ..................................................................... 450 8.2.2.4.5 SEM OBSERVATION OF WORN SURFACE ........................................ 451 8.2.3 WET SKID RESISTANCE OF TIRE ................................................................. 451 8.2.3.1 THREE ZONE CONCEPT ....................................................................... 452 8.2.3.2 EFFECT OF DIFFERENT FILLERS IN THE THREE ZONES ............................... 454 8.2.3.2.1 MINIMIZATION OF SQUEEZE-FILM ZONE ...................................... 454 8.2.3.2.2 MINIMIZATION OF TRANSITION ZONE AND MAXIMIZING ITS BOUNDARY LUBRICATION COMPONENT ......................................... 454 8.2.3.2.3 MAXIMIZATION OF TRACTION ZONE ............................................. 456 8.2.3.3 INFLUENCING FACTORS ON WET SKID RESISTANCE ................................ 456 8.2.3.3.1 EFFECT OF TEST CONDITIONS ON WET SKID RESISTANCE ................. 458 8.2.3.3.2 EFFECT OF COMPOUND PROPERTIES AND TEST METHODS ON WET SKID RESISTANCE .............................................................. 464 8.2.3.4 DEVELOPMENT OF A NEW FILLER FOR WET SKID RESISTANCE ............... 467 8.3 ABRASION RESISTANCE ...................................................................................... 471 XI 8.3.1 ABRASION MECHANISMS ............................................................................ 471 8.3.2 EFFECT OF FILLER PARAMETERS ON ABRASION ................................................ 480 8.3.2.1 EFFECT OF FILLER LOADING ................................................................... 480 8.3.2.2 EFFECT OF FILLER SURFACE AREA ........................................................... 482 8.3.2.3 EFFECT OF FILLER STRUCTURE ................................................................. 483 8.3.2.4 EFFECT OF FILLER-ELASTOMER INTERACTION ............................................ 485 8.3.2.4.1 EFFECT OF FILLER-ELASTOMER INTERACTION RELATED TO SURFACE AREA ............................................................................ 485 8.3.2.4.2 EFFECT OF HEAT TREATMENT OF CARBON BLACK ........................... 486 8.3.2.4.3 EFFECT OF OXIDATION OF CARBON BLACK .................................... 487 8.3.2.4.4 EFFECT OF PHYSICAL ADSORPTION OF CHEMICALS ON CARBON BLACK SURFACE .............................................................. 487 8.3.2.5 EFFECT OF CARBON BLACK MIXING PROCEDURE .................................... 488 8.3.2.6 SILICA VS. CARBON BLACK .................................................................. 490 8.3.2.7 SILICA IN EMULSION SBR COMPOUNDS ............................................. 491 8.3.2.8 SILICA IN NR COMPOUNDS ................................................................ 492 8.3.2.9 EFFECT OF CSDPF ON ABRASION RESISTANCE ..................................... 494 REFERENCES ................................................................................................................ 495 9. DEVELOPMENT OF NEW MATERIALS FOR TIRE APPLICATION ................ 508 9.1 CHEMICAL MODIFIED CARBON BLACK ................................................................. 508 9.2 CARBON-SILICA DUAL PHASE FILLER (CSDPF) .................................................... 510 9.2.1 CHARACTERISTICS OF CHEMISTRY .................................................................. 512 9.2.2 CHARACTERISTICS OF COMPOUNDING ............................................................ 513 9.2.3 APPLICATION OF CSDPF 4000 IN PASSENGER TIRES ................................... 515 9.2.4 APPLICATION OF CSDPF 2000 IN TRUCK TIRES .......................................... 515 9.3 NR/CARBON BLACK MASTERBATCH PRODUCED BY LIQUID PHASE MIXING ........... 516 9.3.1 MECHANISMS OF MIXING, COAGULATION, AND DEWATERING ........................ 517 9.3.2 COMPOUNDING CHARACTERISTICS ................................................................ 518 9.3.2.1 MASTICATION EFFICIENCY ..................................................................... 519 9.3.2.2 CEC PRODUCT FORM ........................................................................... 520 9.3.2.3 MIXING EQUIPMENT ........................................................................... 520 9.3.2.4 MIXING PROCEDURES ........................................ 521 9.3.2.4.1 TWO-STAGE MIXING .................................................................. 521 9.3.2.4.2 SINGLE-STAGE MIXING ................................................................ 522 9.3.2.5 TOTAL MIXING CYCLE ......................................................................... 523 9.3.3 CURE CHARACTERISTICS ............................................................................... 524 9.3.4 PHYSICAL PROPERTIES OF CEC VULCANIZATES .............................................. 524 9.3.4.1 STRESS-STRAIN PROPERTIES ................................................................... 524 XN 9.3.4.2 ABRASION RESISTANCE ....................................................................... 525 9.3.4.3 DYNAMIC HYSTERESIS AT HIGH TEMPERATURE ..................................... 526 9.3.4.4 CUT-CHIP RESISTANCE ....................................................................... 529 9.3.4.5 FLEX FATIGUE .................................................................................... 529 9.4 SYNTHETIC RUBBER/SILICA MASTERBATCH PRODUCED WITH LIQUID PHASE MIXING ...................................................................................... 530 9.4.1 PRODUCTION PROCESS OF EVEC ................................................................. 531 9.4.2 COMPOUND PROPERTIES ............................................................................. 532 9.4.2.1 BOUND RUBBER CONTENT ................................................................... 533 9.4.2.2 MOONEY VISCOSITY .......................................................................... 534 9.4.2.3 EXTRUSION ......................................................................................... 534 9.4.2.4 CURE CHARACTERISTICS ....................................................................... 535 9.4.3 VULCANIZATE PROPERTIES .......................................................................... 537 9.4.3.1 HARDNESS OF VULCANIZATES ............................................................... 537 9.4.3.2 STATIC STRESS-STRAIN PROPERTIES ........................................................ 537 9.4.3.3 TENSILE STRENGTH AND ELONGATION AT BREAK ...................................... 540 9.4.3.4 TEAR STRENGTH ................................................................................... 540 9.4.3.5 DYNAMIC PROPERTIES ........................................................................ 541 9.4.3.5.1 STRAIN DEPENDENCE OF DYNAMIC PROPERTIES ........................... 541 9.4.3.5.2 TEMPERATURE DEPENDENCE OF DYNAMIC PROPERTIES ................ 544 9.4.3.5.3 REBOUND AND HEAT BUILD-UP .................................................... 548 9.4.3.6 ABRASION RESISTANCE ....................................................................... 548 9.5 POWDERED RUBBER ........................................................................................... 549 9.5.1 PRODUCTION OF POWDERED RUBBER ........................................................... 549 9.5.2 MIXING OF POWDERED RUBBER .................................................................. 549 9.5.3 PROPERTIES OF POWDERED RUBBER COMPOUNDS ........................................ 550 9.6 MASTERBATCHES WITH OTHER FILLERS ................................................................... 551 9.6.1 STARCH ....................................................................................................... 551 9.6.2 ORGANO-CLAYS .......................................................................................... 553 REFERENCES ............................................................................................................... 553 10. REINFORCEMENT OF SILICONE RUBBER ........................................... 558 10.1 FUMED VS. PRECIPITATED SILICA ...................................................................... 559 10.2 INTERACTION BETWEEN SILICA AND SILICONE POLYMERS ................................. 560 10.2.1 SURFACE ENERGY CHARACTERIZATION BY INVERSE GAS CHROMATOGRAPHY .................................................................................. 560 10.2.2 BOUND RUBBER IN SILICA-PDMS SYSTEMS ............................................ 562 10.3 CREPE HARDENING ........................................................................................... 563 10.4 SILICA SURFACE MODIFICATION ......................................................................... 564 XFFL 10.5 MORPHOLOGICAL PROPERTIES OF SILICA .............................................................. 565 10.5.1 SURFACE AREA ......................................................................................... 565 10.5.2 STRUCTURE PROPERTIES OF SILICA ................................................................ 567 10.6 MIXING AND PROCESSING OF SILICONE COMPOUNDS ......................................... 568 10.7 SILICA DISPERSION IN SILICONE RUBBER ........................................................... 572 10.8 STATIC MECHANICAL PROPERTIES ........................................................................ 573 10.8.1 TENSILE MODULUS .................................................................................... 573 10.8.2 TENSILE STRENGTH AND ELONGATION PROPERTIES .......................................... 576 10.8.3 COMPRESSION SET ................................................................................... 576 10.9 DYNAMIC MECHANICAL PROPERTIES .................................................................. 578 REFERENCES ................................................................................................................ 580 INDEX ..................................................................................................... 583 XIV
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author	Wang, Meng-Jiao Morris, Michael
author_GND	(DE-588)1241834598 (DE-588)1241834741
author_facet	Wang, Meng-Jiao Morris, Michael
author_role	aut aut
author_sort	Wang, Meng-Jiao
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ctrlnum	(OCoLC)1264258257 (DE-599)DNB1219590231
discipline	Chemie / Pharmazie Werkstoffwissenschaften / Fertigungstechnik
format	Book
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id	DE-604.BV047424705
illustrated	Illustrated
indexdate	2024-12-20T19:19:13Z
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isbn	9781569907191 1569907196
language	English
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physical	XIV, 589 Seiten Illustrationen, Diagramme 25 cm
publishDate	2021
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spellingShingle	Wang, Meng-Jiao Morris, Michael Rubber reinforcement with particulate fillers Stoffeigenschaft (DE-588)4192147-1 gnd Synthesekautschuk (DE-588)4133407-3 gnd Kautschuk (DE-588)4030108-4 gnd Siliciumdioxid (DE-588)4077447-8 gnd Vulkanisat (DE-588)4324736-2 gnd Teilchen (DE-588)4059317-4 gnd Verstärkungswerkstoff (DE-588)4303769-0 gnd Elastomer (DE-588)4014162-7 gnd Ruß (DE-588)4178736-5 gnd Grafit (DE-588)4158067-9 gnd Füllstoff (DE-588)4155585-5 gnd Gummiindustrie (DE-588)4323287-5 gnd Gummi (DE-588)4022538-0 gnd
subject_GND	(DE-588)4192147-1 (DE-588)4133407-3 (DE-588)4030108-4 (DE-588)4077447-8 (DE-588)4324736-2 (DE-588)4059317-4 (DE-588)4303769-0 (DE-588)4014162-7 (DE-588)4178736-5 (DE-588)4158067-9 (DE-588)4155585-5 (DE-588)4323287-5 (DE-588)4022538-0
title	Rubber reinforcement with particulate fillers
title_auth	Rubber reinforcement with particulate fillers
title_exact_search	Rubber reinforcement with particulate fillers
title_full	Rubber reinforcement with particulate fillers Meng-Jiao Wang, Michael Morris
title_fullStr	Rubber reinforcement with particulate fillers Meng-Jiao Wang, Michael Morris
title_full_unstemmed	Rubber reinforcement with particulate fillers Meng-Jiao Wang, Michael Morris
title_short	Rubber reinforcement with particulate fillers
title_sort	rubber reinforcement with particulate fillers
topic	Stoffeigenschaft (DE-588)4192147-1 gnd Synthesekautschuk (DE-588)4133407-3 gnd Kautschuk (DE-588)4030108-4 gnd Siliciumdioxid (DE-588)4077447-8 gnd Vulkanisat (DE-588)4324736-2 gnd Teilchen (DE-588)4059317-4 gnd Verstärkungswerkstoff (DE-588)4303769-0 gnd Elastomer (DE-588)4014162-7 gnd Ruß (DE-588)4178736-5 gnd Grafit (DE-588)4158067-9 gnd Füllstoff (DE-588)4155585-5 gnd Gummiindustrie (DE-588)4323287-5 gnd Gummi (DE-588)4022538-0 gnd
topic_facet	Stoffeigenschaft Synthesekautschuk Kautschuk Siliciumdioxid Vulkanisat Teilchen Verstärkungswerkstoff Elastomer Ruß Grafit Füllstoff Gummiindustrie Gummi
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=032827221&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT wangmengjiao rubberreinforcementwithparticulatefillers AT morrismichael rubberreinforcementwithparticulatefillers AT hanserpublications rubberreinforcementwithparticulatefillers

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