Accessing molecule-metal and hetero-molecular interfaces with direct and resonant photoelectron spectroscopy:
Gespeichert in:
| Beteilige Person: | |
|---|---|
| Format: | Hochschulschrift/Dissertation Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
2014
|
| Schlagwörter: | |
| Links: | https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-107928 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027735510&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| Beschreibung: | Zsfassung in dt. und engl. Sprache |
| Umfang: | VI, 207 S. Ill., graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Accessing molecule-metal and hetero-molecular interfaces with direct and resonant photoelectron spectroscopy |c von Christoph Sauer |
| 246 | 1 | 3 | |a Untersuchung von Molekül/Metall- und heteromolekularen Grenzflächen mittels direkter und resonanter Photoelektronenspektroskopie |
| 264 | 1 | |c 2014 | |
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Datensatz im Suchindex
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| adam_text | ACCESSING MOLECULE-METAL AND HETERO-MOLECULAR
INTERFACES WITH DIRECT AND RESONANT PHOTOELECTRON
SPECTROSCOPY
DISSERTATION
ZUR ERLANGUNG DES NATURWISSENSCHAFTLICHEN DOKTORGRADES DER
JULIUS-MAXIMILIANS-UNIVERSITAT WIIRZBURG
VORGELEGT VON-
CHRISTOPH SAUER
AUS WIIRZBURG
WIIRZBURG 2014
HTTP://D-NB.INFO/1066682534
CONTENTS
III
CONTENTS
1 INTRODUCTION 1
2 THEORETICAL CONCEPTS 5
2.1 BASIC THEORY OF THE APPLIED EXPERIMENTAL TECHNIQUES 5
2.1.1 PHOTOELECTRON SPECTROSCOPY 6
2.1.2 NEAR EDGE X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY 7
2.1.3 RESONANT PHOTOELECTRON SPECTROSCOPY 7
2. .4 EXCITATION OF MOLECULAR VIBRATIONS IN RESONANT PHOTOELECTRON
SPEC
TROSCOPY 9
2.2 FROM THE GUNNARSSON-SCHONHAMMER THEORY TO THE FINGERPRINT APPROACH
ANALYSIS OF HETERO-MOLECULAR SYSTEMS 11
2.3 THE MOLECULE-METAL INTERFACE IN A CLUSTER MODEL 17
2.3.1 THE MOLECULAR CLUSTER MODEL HAMILTONIAN 18
2.3.2 GENERAL CALCULATIONS 19
2.3.3 VALENCE PHOTOELECTRON SPECTROSCOPY 21
2.3.4 CORE LEVEL PHOTOELECTRON SPECTROSCOPY 23
2.3.5 NEAR EDGE X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY 24
2.3.6 RESONANT PHOTOELECTRON SPECTROSCOPY 24
3 EXPERIMENT 27
3.1 EXPERIMENTAL SETUP AT UE52-PGM 27
3.2 SAMPLE PREPARATION 29
3.3 DATA TREATMENT 32
3.4 THICKNESS CALIBRATION OF ADSORBATES WITH PHOTOELECTRON SPECTROSCOPY
. . 35
4 ANALYZING HETERO-ORGANIC FILMS ON METAL SUBSTRATES WITH PHOTOELECTRON
SPECTROSCOPY - THE
FINGERPRINT APPROACH
ANALYSIS 39
4.1 FINGERPRINT APPROACH ANALYSIS OF VERTICAL HETERO-ORGANIC SYSTEMS AT
300 K 40
4.1.1 METAL-PHTHALOCYANINE AND PTCDA MOLECULES ON AG(L 11) ... 41
4.1.2 F4TCNQ AND PTCDA MOLECULES ON AG(L 10) 54
4.2 STABILITY OF HETERO-ORGANIC SYSTEMS AT ELEVATED TEMPERATURES 59
4.2.1 METAL-PHTHALOCYANINE AND PTCDA MOLECULES ON AG(L 11) ... 59
4.2.2 F4TCNQ AND PTCDA MOLECULES ON AG( 110) 70
4.3 SUMMARY AND DISCUSSION 72
IV
CONTENTS
5 RESONANT PHOTOELECTRON SPECTROSCOPY APPLIED TO ^-CONJUGATED MOLECULES:
FROM HOMO TO HETERO-MOLECULAR SYSTEMS 79
5.1 PHOTON ENERGY DEPENDENT INTENSITY VARIATIONS 82
5.1.1 NTCDA 83
5.1.2 CORONENE 86
5.2 PHOTON ENERGY DEPENDENT LINE-SHAPE EVOLUTION OF MOLECULAR ORBITAL
SIGNALS 91
5.2.1 MULTILAYER FILMS 92
5.2.2 INFLUENCE OF THE ADSORPTION ON A METAL SURFACE 100
5.3 REVELATION OF CHARGE TRANSFER RELATED FEATURES 104
5.3.1 THE CHARGE TRANSFER STATE AT THE CORONENE/AG(L 11) INTERFACE . . .
105
5.3.2 CHARGE TRANSFER SIGNATURES IN THE VALENCE REGION 114
5.3.3 CONSTANT KINETIC ENERGY FEATURES 123
5.4 APPLICATION TO HETERO-ORGANIC INTERFACE SYSTEMS 134
5.4.1 LATERAL HETERO-ORGANIC INTERFACE: CUPC + PTCDA/AG(LL 1) ... 136
5.4.2 VERTICAL HETERO-ORGANIC INTERFACE: CUPC/LML PTCDA/AG(L 11) . 140
5.5 SUMMARY AND CONCLUSION 147,.
6 DISCUSSION AND OUTLOOK 151
7 SUMMARY / ZUSAMMENFASSUNG 155
APPENDIX 163
A SUPPORTING DATA FOR CHAPTER 3 164
B SUPPORTING DATA FOR CHAPTER 4 165
C SUPPORTING DATA FOR CHAPTER 5 I 73
BIBLIOGRAPHY 183
OWN PUBLICATIONS 199
ABBREVIATIONS 201
DANKSAGUNG 203
|
| any_adam_object | 1 |
| author | Sauer, Christoph |
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| discipline | Chemie / Pharmazie Physik |
| format | Thesis Book |
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| indexdate | 2024-12-20T17:07:09Z |
| institution | BVB |
| language | English |
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| physical | VI, 207 S. Ill., graph. Darst. |
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| spellingShingle | Sauer, Christoph Accessing molecule-metal and hetero-molecular interfaces with direct and resonant photoelectron spectroscopy Photoelektronenspektroskopie (DE-588)4174491-3 gnd Adsorptionsschicht (DE-588)4314127-4 gnd Organisches Molekül (DE-588)4133471-1 gnd |
| subject_GND | (DE-588)4174491-3 (DE-588)4314127-4 (DE-588)4133471-1 (DE-588)4113937-9 |
| title | Accessing molecule-metal and hetero-molecular interfaces with direct and resonant photoelectron spectroscopy |
| title_alt | Untersuchung von Molekül/Metall- und heteromolekularen Grenzflächen mittels direkter und resonanter Photoelektronenspektroskopie |
| title_auth | Accessing molecule-metal and hetero-molecular interfaces with direct and resonant photoelectron spectroscopy |
| title_exact_search | Accessing molecule-metal and hetero-molecular interfaces with direct and resonant photoelectron spectroscopy |
| title_full | Accessing molecule-metal and hetero-molecular interfaces with direct and resonant photoelectron spectroscopy von Christoph Sauer |
| title_fullStr | Accessing molecule-metal and hetero-molecular interfaces with direct and resonant photoelectron spectroscopy von Christoph Sauer |
| title_full_unstemmed | Accessing molecule-metal and hetero-molecular interfaces with direct and resonant photoelectron spectroscopy von Christoph Sauer |
| title_short | Accessing molecule-metal and hetero-molecular interfaces with direct and resonant photoelectron spectroscopy |
| title_sort | accessing molecule metal and hetero molecular interfaces with direct and resonant photoelectron spectroscopy |
| topic | Photoelektronenspektroskopie (DE-588)4174491-3 gnd Adsorptionsschicht (DE-588)4314127-4 gnd Organisches Molekül (DE-588)4133471-1 gnd |
| topic_facet | Photoelektronenspektroskopie Adsorptionsschicht Organisches Molekül Hochschulschrift |
| url | https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-107928 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027735510&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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