Gespeichert in:
| Beteilige Person: | |
|---|---|
| Format: | Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
London
Imperial College Press
2012
|
| Ausgabe: | 2. ed. |
| Schriftenreihe: | Catalytic science series
11 |
| Schlagwörter: | |
| Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025164422&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025164422&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| Beschreibung: | Previous ed.: London: Imperial College, 2005 Includes bibliographic references and index |
| Umfang: | XIV, 566 S. Ill., graf. Darst. |
| ISBN: | 184816677X 9781848166776 |
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| 245 | 1 | 0 | |a Supported metals in catalysis |c ed. by James A. Anderson ... |
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| 500 | |a Includes bibliographic references and index | ||
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Datensatz im Suchindex
| DE-BY-TUM_call_number | 0302 CIT 325f 2005 A 6544(2) |
|---|---|
| DE-BY-TUM_katkey | 1866295 |
| DE-BY-TUM_location | 03 |
| DE-BY-TUM_media_number | 040030490467 |
| _version_ | 1821934609637572609 |
| adam_text | CONTENTS
Preface to the first edition
xi
Preface to the second edition
xiii
Chapter
1
Preparation of Supported Metal Catalysts
1
Guido
Mul
and Jacob A. Moulijn
1.1
Introduction
1
1.2
General Description of Preparation Methods
4
1.2.1
Impregnation
4
1.3
CaseStudies
18
1.3.1
Impregnation: preparation of
Pt
catalysts, the
19
effect of the pre-treatment conditions
1.3.2
Precipitation vs. impregnation by ion-exchange:
23
Au
precursors and the effect of the method of
preparation and selected support on performance
in selective epoxidation of
propene
over Au/TiO«
catalysts
1.3.3
Co-precipitation: preparation of advanced
29
CaCO3 supported Ag catalysts
1.4
General Conclusions on the Preparation of
35
Metal Catalysts
Chapter
2
Determination of Dispersion and Crystallite
41
Sizes for Supported Metal Catalysts
J. A. Anderson, M.
Fernández-García
and
A. Martinez-Arias
2.1
Introduction
41
2.2
General Considerations
42
vi
Contents
2.2.1
Physical methods
42
2.2.2
Chemical methods
49
Chapter
3
Imaging and Microanalysis of Supported
81
Metal Catalysts in the Analytical Electron
Microscope
Andrew A. Herzing and ChristopherJ.
Kiely
3.1
Introduction
81
3.2
Electron-Specimen Interactions
82
3.3
Imaging Supported Metal Particles in the
ТЕМ
84
3.4
Imaging Supported Metal Nanoparticles in
94
the STEM
3.5
Other Technical Developments
100
3.6
Analytical Electron Microscopy (AEM) for
101
Catalyst Research
3.7
The Origin of Microanalytical Signals
101
3.8
X-ray Energy Dispersive Spectroscopy (XEDS)
103
of Supported Metal Catalysts
3.9
Core-Loss Electron Energy Loss Spectroscopy 111
(EELS) of Supported Metal Catalysts
3.10
Summary
117
Chapter
4
Characterization of Supported Metal
121
Catalysts by
Spectroscopie
Techniques
M.
Fernández-García
and
J.
A. Anderson
4.1
Introduction
121
4.2
Main Properties of Monometallic Systems
122
4.3
Main Properties of Bimetallic Systems
125
4.4
In situ Characterization
129
4.4.1
X-ray absorption and emission spectroscopies
129
4.4.2
Novel diffraction approaches
145
4.4.3
Vibrational spectroscopy
148
4.4.4
Valence and core photoelectron spectroscopies
159
4.4.5
Other techniques
163
Contents
vii
Chapter
5
Supported Metal Catalysts for Fine
177
Chemicals Synthesis
KRK.
Wells andJ.A. Anderson
5.1
Introduction
177
5.2
Selective
Hydrogénation
over Supported Metal Catalysts
178
5.2.1
Overview
178
5.2.2
Hydrogénation
of buta-l,3-diene over
180
non-modified metal catalysts
5.2.3
The
Hydrogénation
of buta-l^-diene over
184
modified metal catalysts
5.2.4
Hydrogénation
of (X,
ß-unsaturated
aldehydes
185
over non-modified metal catalysts
5.2.5
The
hydrogénation
of
α,β
-unsaturated
187
aldehydes over modified metal catalysts
5.3
Selective Oxidation
191
5.3.1
Supported platinum-group metals
191
5.3.2
Supported gold and silver
193
5.3.3
Catalyst deactivation
195
5.4
Enantioselective Reactions
196
5.4.1
Enantioselective
hydrogénation
of activated
197
ketones over supported platinum
5.4.2
Enantioselective
hydrogénation
over other
206
supported metals
5.5
Conclusions
208
Chapter
6
Supported Gold in CO Oxidation, the
217
Water-Gas Shift, and DeSOx Reactions
Jose A. Rodriguez
6.1
Introduction
217
6.2
Oxidation of CO on Supported Gold Nanoparticles
218
6.3
Water-Gas Shift Reaction on Supported Gold
224
Nanoparticles
6.4
Decomposition of SO2 on Supported Gold Nanoparticles
236
6.5
Conclusion
241
viii Contents
Chapter
7
Recent Progress in Supported Metal-Catalysed
247
Cl Chemistry
A. Guerrero-Ruiz and I. Rodriguez-Ramos
7.1
Introduction
247
7.2
Fischer-Tropsch Synthesis
250
7.3 Methanol
Production and Higher Alcohols from Syngas
265
7.4
Hydrogénation
Reactions and Other Possibilities
274
Aimed to Re-use CCX
7.5
Hydroforrnylation of Olefins with Synthesis Gas
279
7.6
Catalysed Reactions Involving CH4
282
7.7
CH,OH to Hydrocarbons and to Other Intermediate
283
Compounds
Chapter
8
Supported Metals in the Production
301
of Hydrogen
J.L.G.
Fierro,
M.A.
Peña
and
M.C.
Alvarez-Galvan
8.1
Introduction
301
8.2
Methane Conversion
302
8.2.1
Steam methane reforming
303
8.2.2
Methane decomposition
313
8.2.3
Partial oxidation and dry reforming of methane
329
8.3
Alcohol Conversion
349
8.3.1 Methanol 349
8.3.2
Ethanol
oxidation
366
8.4
Conversion of Other Hydrocarbon Feeds
382
Chapter
9
Supported Metals for Application in
407
Fuel Cells
Sergio
Rojas, María
Victoria
Martínez-Huerta
and M.A.
Peña
9.1
Introduction
407
9.2
Hydrogen Oxidation Reaction
411
9.3
H9/CO Electrooxidation
415
9.3.1
Pt electrocatalysts
415
9.3.2
CO tolerant catalvsts
418
Contents ix
9.4 Electrooxidation
of
Methanol 422
9.5 Electrooxidation
of Ethanol
430
9.6
Oxygen Reduction Reaction
432
9.6.1
Reaction mechanism
434
9.6.2
Electrocatalysts for the
ORR
437
9.7
Preparation of Carbon Supported Platinum
447
9.7.1
Synthesis methods
448
9.7.2
Synthesis of bimetallic and ternary catalysts
451
9.8
Catalyst Supports
456
9.8.1
Carbon blacks
457
9.8.2
New carbon materials
467
9.9
Conclusions and Future Trends
470
Chapter
10
Supported Metals in Vehicle Emission Control
493
A. Martinez-Arias,
José
С.
Conesa,
M.
Fernández-García
and
J.
A. Anderson
10.1
Introduction
493
10.2
Emissions Produced at Stoichiometric Conditions
495
10.2.1
Classical TWC
495
10.2.2
Modern TWC
500
10.3
Lean-burn Emissions
511
10.3.1
Oxidation catalysts
512
10.3.2
Treatment of soot
514
10.3.3
Catalysts for selective reduction of NOX
516
with hydrocarbons
10.3.4
Catalysts for NH3-or urea-SCR
532
10.4
Mixed Oscillating Emissions
534
10.4.1
NOX storage and reduction catalysts
534
Index
553
Supported
Metals
in Catalysis
2nd
Edition
With contributions from experts in supported metal catalysis from both
the industry and
academia,
this book presents the latest developments
in characterization and application of supported metals in heterogeneous
catalysis. In addition to thorough and updated coverage of the traditional
aspects of heterogeneous catalysis such as preparation, characterization
and use in well-established technologies such as vehicle emission control,
the book also includes emerging areas where supported metal catalysis will
make significant contributions to future developments, such as fuel cells
and fine chemicals synthesis.
The second edition of Supported Metals in Catalysis comes complete with
new and updated chapters containing important summaries of research in
a rapidly evolving field. Very few other books deal with this highly pertinent
subject matter and, as such, it is a must-have for anyone working in the
field of heterogeneous catalysis.
Imperial College Press
P767te
ISBN-13
978-1-84816-677-6
ISBN-10 1-84816-677-X
www.icpress.co.uk
|
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
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| id | DE-604.BV040309597 |
| illustrated | Illustrated |
| indexdate | 2024-12-20T16:12:11Z |
| institution | BVB |
| isbn | 184816677X 9781848166776 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025164422 |
| oclc_num | 794547638 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-703 DE-29T |
| owner_facet | DE-91G DE-BY-TUM DE-703 DE-29T |
| physical | XIV, 566 S. Ill., graf. Darst. |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | Imperial College Press |
| record_format | marc |
| series | Catalytic science series |
| series2 | Catalytic science series |
| spellingShingle | Anderson, James A. Supported metals in catalysis Catalytic science series Heterogeneous catalysis Metal catalysts Trägerkatalysator (DE-588)4185817-7 gnd Metallverbindungen (DE-588)4169640-2 gnd Heterogene Katalyse (DE-588)4123377-3 gnd |
| subject_GND | (DE-588)4185817-7 (DE-588)4169640-2 (DE-588)4123377-3 |
| title | Supported metals in catalysis |
| title_auth | Supported metals in catalysis |
| title_exact_search | Supported metals in catalysis |
| title_full | Supported metals in catalysis ed. by James A. Anderson ... |
| title_fullStr | Supported metals in catalysis ed. by James A. Anderson ... |
| title_full_unstemmed | Supported metals in catalysis ed. by James A. Anderson ... |
| title_short | Supported metals in catalysis |
| title_sort | supported metals in catalysis |
| topic | Heterogeneous catalysis Metal catalysts Trägerkatalysator (DE-588)4185817-7 gnd Metallverbindungen (DE-588)4169640-2 gnd Heterogene Katalyse (DE-588)4123377-3 gnd |
| topic_facet | Heterogeneous catalysis Metal catalysts Trägerkatalysator Metallverbindungen Heterogene Katalyse |
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Teilbibliothek Chemie
| Signatur: | 0302 CIT 325f 2005 A 6544(2) |
|---|---|
| Exemplar 1 | Ausleihbar Am Standort |