Reinforcement of polymer nano-composites: theory, experiments and applications
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Cambridge
Cambride University Press
2009
|
| Edition: | 1. publ. |
| Subjects: | |
| Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018602740&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018602740&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| Item Description: | Includes bibliographical references |
| Physical Description: | XII, 209 S. Ill., graph. Darst. |
| ISBN: | 9780521874809 |
Staff View
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| 650 | 4 | |a Nanostructured materials |x Inclusions | |
| 650 | 4 | |a Composite materials | |
| 650 | 4 | |a Rubber |x Reinforcement | |
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Record in the Search Index
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| adam_text | Contents
Preface
ix
Acknowledgement
xii
1
Introduction
1
Basics about polymers
10
2.1
Gaussian chains
-
heuristic introduction
10
2.2
Gaussian chains
-
path integrals
12
2.3
Self-interacting chains
15
Many-chain systems: melts and screening
19
3.1
Some general remarks
19
3.2
Collective variables
20
3.3
The statistics of tagged chains
26
Rubber formation
31
4.1
Classical theory of gelation
31
4.2
Percolation
34
4.3
Vulcanization
37
The elastomer matrix
40
5.1
General remarks
40
5.2
The Gaussian network
42
5.3
Entanglements and the tube model: a material law
45
5.3.1
Entanglement sliding
47
5.3.2
Finite extensibility
49
5.3.3
Tube and sliplinks
52
vi
Contents
5.4 Experiments 53
5.4.1
The stress-strain relationship
53
5.4.2
The extended tube model of rubber elasticity
55
5.4.3
Testing of the model
59
6
Polymers of larger connectivity: branched polymers and
polymeric fractals
64
6.1
Preliminary remarks
64
6.2
D-dimensionally connected polymers in a good solvent
64
6.3
D-dimensionally connected polymers between two parallel
plates in a good solvent
66
6.4
D-dimensionally connected polymers in a cylindrical pore (good
solvent)
68
6.5
Melts of fractals in restricted geometries
71
6.6
Once more the differences
74
7
Reinforcing fillers
75
7.1
Fillers for the rubber industry
75
7.2
Carbon black
77
7.2.1
Morphology of carbon black aggregates
77
7.2.2
Surface roughness of carbon blacks
84
7.2.3
Energy distribution of carbon black surfaces
92
7.3
Silica
96
8
Hydrodynamic reinforcement of elastomers
101
8.1
Reminder: Einstein-Smallwood
101
8.2
Rigid filler aggregates with fractal structure
103
8.2.1
Effective medium theory and linear elasticity
106
8.2.2
Screening lengths
109
8.2.3
Reinforcement by fractal aggregates
110
8.3
Core-shell systems 111
8.3.1
Uniform soft sphere
112
8.3.2
Softcore/hardshell
112
8.3.3
Hard core/soft shell
115
9
Polymer-filler interactions
118
9.1
General remarks and scaling
118
9.1.1
Rat surface
119
9.1.2
Generalization for fractal surfaces
120
Contents
vii
9.2 Variational
calculation statics
121
9.2.1
Variational calculation
121
9.3
Trial Hamiltonian
122
9.3.1
Minimization of the free energy
123
9.3.2
Effective interaction strength
126
9.4
Some further remarks on the interpretation
130
9.4.1
Modeling by random potentials
131
9.4.2
Annealed and quenched disorder
134
9.4.3
Dynamics of localized chains
-
freezing, glass transition
at filler surfaces
135
9.5
Equation of motion for the time correlation function
137
9.5.1
Langevin
dynamics
137
9.5.2
Self-consistent
Hartree
approximation
139
9.5.3
Equation of motion
142
9.6
Dynamic behavior of the chain
144
9.6.1
Anomalous diffusion
144
9.6.2
Center-of-mass freezing
146
9.6.3
Rouse modes freezing and a two mode toy model
147
9.7
Numerical analysis
148
9.7.1
Bifurcation diagram
149
9.8
Contribution to the modulus
151
10
Filler-filler interaction
153
10.1
Filler networking in elastomers
153
10.1.1
Flocculation of fillers during heat treatment
153
10.1.2
Kinetics of filler structures under dynamic excitation
156
10.2
Dynamic small- and medium-strain modeling
-
the Payne effect
161
10.2.1
The
Kraus
model
161
10.2.2
The viscoelastic model
164
10.2.3
The van
der Walle-Tricot-Gerspacher (WTG)
model
169
10.2.4
The links-nodes-blobs (LNB) model
171
10.2.5
The model of the variable network density
172
10.2.6
The cluster-cluster aggregation (CCA) model
174
10.3
Stress-softening and quasistatic stress-strain modeling
-
the Mullins effect
182
10.3.1
The dynamic flocculation model
182
10.3.2
The Kantor-Webman model of flexible chain aggregates
193
References
196
Index
204
Reinforced rubber allows the
production
of passenger car
tires
with
improved rolling resistance and wet grip. This book provides in-depth coverage
of the physics behind elastomer reinforcement, with a particular focus on the
modification of polymer properties using active fillers such as carbon black and
silica. The authors build a firm theoretical base through a detailed discussion
of the physics of polymer chains and matrices before moving on to describe
reinforcing fillers and their applications in the improvement of the mechanical
properties of high-performance rubber materials.
Reinforcement is explored on all relevant length scales, from molecular
to macroscopic, usinga variety of methods rangingfrom statistical physics
and computer simulations to experimental techniques. Presenting numerous
technological applications of reinforcement in rubber such as tire tread
compounds, this book is ideal for academic researchers and professionals
working in polymer science.
T. A. vilgis is Professor of Theoretical Physics at the university of Mainz and a
researcher at the Max Planck institute for Polymer Research. He is a mem
ber
of
several scientific societies including the German Physical Society, EPS, and APS.
He has written morethan
250
scientific papers,
3
popular science books.and
2
scientific cookbooks.
G.Heinrich
is Professor of Polymer Materials at
Technische Universität
Dresden
and is also Director of the institute of Polymer Materials within the Leibniz institute
of Polymer Research,
не
has written or contributed to over
250
scientific papers and
book chapters on polymer science.
M. Kliippel is a lecturer in Polymer Materials at Leibniz University, Hannover and Head
of the
De partment
of Material Concepts and Modelling at the German institute of
Rubber Technology
(DIK).
He has published more than
150
scientific papers and
is a member of the German Physical Society, the German Rubber Society, and the
Rubber Division of ACS.
|
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| author | Vilgis, Thomas 1955- |
| author_GND | (DE-588)111202132 (DE-588)10935348X (DE-588)136225349 |
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| ctrlnum | (OCoLC)308198231 (DE-599)BSZ308122933 |
| dewey-full | 668.4/94 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 668 - Technology of other organic products |
| dewey-raw | 668.4/94 |
| dewey-search | 668.4/94 |
| dewey-sort | 3668.4 294 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Physik |
| edition | 1. publ. |
| format | Book |
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| id | DE-604.BV035742546 |
| illustrated | Illustrated |
| indexdate | 2024-12-20T13:59:09Z |
| institution | BVB |
| isbn | 9780521874809 |
| language | English |
| lccn | 2009013054 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-018602740 |
| oclc_num | 308198231 |
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| owner | DE-703 DE-29T DE-898 DE-BY-UBR |
| owner_facet | DE-703 DE-29T DE-898 DE-BY-UBR |
| physical | XII, 209 S. Ill., graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Cambride University Press |
| record_format | marc |
| spellingShingle | Vilgis, Thomas 1955- Reinforcement of polymer nano-composites theory, experiments and applications Reinforced plastics Nanostructured materials Inclusions Composite materials Rubber Reinforcement Verbundwerkstoff (DE-588)4062670-2 gnd Gummi (DE-588)4022538-0 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd |
| subject_GND | (DE-588)4062670-2 (DE-588)4022538-0 (DE-588)4342626-8 |
| title | Reinforcement of polymer nano-composites theory, experiments and applications |
| title_auth | Reinforcement of polymer nano-composites theory, experiments and applications |
| title_exact_search | Reinforcement of polymer nano-composites theory, experiments and applications |
| title_full | Reinforcement of polymer nano-composites theory, experiments and applications T. A. Vilgis, G. Heinrich, M. Klüppel |
| title_fullStr | Reinforcement of polymer nano-composites theory, experiments and applications T. A. Vilgis, G. Heinrich, M. Klüppel |
| title_full_unstemmed | Reinforcement of polymer nano-composites theory, experiments and applications T. A. Vilgis, G. Heinrich, M. Klüppel |
| title_short | Reinforcement of polymer nano-composites |
| title_sort | reinforcement of polymer nano composites theory experiments and applications |
| title_sub | theory, experiments and applications |
| topic | Reinforced plastics Nanostructured materials Inclusions Composite materials Rubber Reinforcement Verbundwerkstoff (DE-588)4062670-2 gnd Gummi (DE-588)4022538-0 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd |
| topic_facet | Reinforced plastics Nanostructured materials Inclusions Composite materials Rubber Reinforcement Verbundwerkstoff Gummi Nanostrukturiertes Material |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018602740&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018602740&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
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