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Main Authors:	Batten, Stuart R. (Author), Neville, Suzanne M. (Author), Turner, David R. (Author)
Format:	Book
Language:	English
Published:	Cambridge RSC Publ. 2009
Subjects:	Polymerkomplexe Supramolekulare Struktur
Links:	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992257&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016992257&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA
Physical Description:	XIII, 424 S. Ill., graph. Darst.
ISBN:	9780854048373

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adam_text	Contents Chapter 1 Introduction 1.1 Introduction 1 1.2 Crystal Engineering, Supramolecular Chemistry, Metallosupramolecules 4 1.3 What is a Coordination Polymer? 6 1.4 Synthetic Techniques 10 1.5 Design, Analysis, Application 12 References 13 Chapter 2 Nets: A Tool for Description and Design 2.1 Introduction 19 2.2 Defining Networks 20 2.3 Identifying and Naming Nets 25 2.4 ID Nets 28 2.5 2D Nets 29 2.6 Common 3D Nets 36 2.6.1 S-Connected Nets 36 2.6.2 4-Connected Nets 39 2.6.3 5-Connected Nets 45 2.6.4 ó-Connected Nets 46 2.6.5 Higher Connected Nets 47 2.6.6 Mixed Connectivity Nets 48 2.7 Rod Packings 52 References 53 Coordination Polymers: Design, Analysis and Application By Stuart R. Batten, Suzanne M. Neville and David R. Turner © Stuart R. Batten, Suzanne M. Neville and David R. Turner, 2009 Published by the Royal Society of Chemistry, www.rsc.org Contents Chapter 3 Interpénétration 3.1 Introduction 59 3.2 Nomenclature 67 3.3 ID Interpénétration 69 3.4 2D Interpénétration 70 3.5 3D Interpénétration 77 3.6 Interpénétration of Nets of Different Composition, Topology and Dimensions 84 3.7 Self-penetration 87 3.8 Other Entangled Systems 89 References 89 Chapter 4 Malleability of Coordination Polymers 4.1 Introduction 4.2 Supramolecular Isomerism 4.3 Malleability of Building Blocks 4.4 Synthetic Approach 4.5 Solvent Effects 4.6 Other Guests 4.7 Counterions 4.8 Weaker Interactions 4.9 Conclusion References 96 98 107 111 115 119 120 124 134 134 Chapter 5 Transition Metal Coordination Polymers 5.1 Introduction 5.2 Pseudohalide Ligands 5.2.1 The Cyanide Ligand 5.2.2 The Azide Ligand 5.2.3 NCX Ligands (X = O, S, Se) 5.2.4 Small Polynitrile Ligands (e.g. dca/tcm) 5.3 Larger Nitrile Donor Ligands 5.3.1 Neutral Ligands 5.3.2 Anionie Nitrile Ligands 5.4 Pyridyl Donor Ligands 5.4.1 2-Connecting Ligands 5.4.2 3-Connecting Ligands 5.4.3 4-Connecting Ligands 5.5 Five-membered Ring Nitrogen Donor Ligands 5.5.1 2-Connecting Ligands 5.5.2 S-Connecting Ligands 5.5.3 Other Connectors 144 146 146 149 152 153 156 156 158 159 159 164 165 166 167 169 170 Contents јц 5.6 N-Oxide Ligands 170 5.7 Carboxylate Ligands 172 5.7.1 2-Connecting Ligands 173 5.7.2 S-Connecting Ligands 175 5.7.3 ^Connecting Ligands 177 5.8 Other Ligands 178 5.9 Mixed Donor Atom Ligands 180 5.10 Mixed Ligand Coordination Polymers 181 References 183 Chapter 6 Rare Earth Coordination Polymers 6.1 Introduction 191 6.2 Cyanide/Nitrile and Pseudohalide Ligands 192 6.3 Five-membered Ring Donors 195 6.4 Pyridyl Donor Ligands 196 6.5 TV-Oxide Donors 196 6.6 Rare Earth-Carboxylate Polymers 202 6.6.1 Monocarboxylate Ligands 203 6.6.2 Dicarboxylate Ligands 205 6.6.3 Tricarboxylate Ligands 210 6.6.4 Tetracarboxylate Ligands 212 6.7 Other Ligands 212 6.7.1 Oxalate Coordination Polymers 212 6.7.2 Chloranilic Acid and Dihydroxybenzoquinone 215 6.7.3 Polymers with Sulfonate-containing Ligands 217 6.7.4 Amide Ligands 217 6.7.5 Pyridylcarboxylate Ligands 219 6.8 Mixed 3d/4f Coordination Polymers 221 6.8.1 Cyanide-based Bimetallic Polymers 221 6.8.2 Carboxylate-based Bimetallic Polymers 224 6.8.3 Pyridylcarboxylate Ligands 224 6.8.4 Other Mixed O/N Donor Ligands 229 6.9 Actinide Coordination Polymers 229 References 231 Chapter 7 Organometallic Networks 7.1 Introduction 238 7.2 Large Aromatic Ligands 239 7.2.1 Cation -π Interactions in Ag(i)-PAH Systems 239 7.2.2 Cation -π Interactions with Cyclophanes 241 7.2.3 Non-aromatic Cation -π Interactions 243 7.3 Organometallic Complexes as Ligands 245 7.3.1 Metallocene Bridging Ligands 245 7.3.2 Metal-Quinone Bridging Complexes 246 xii Contents 7.4 Isocarbonyl Polymers 248 7.5 RjSn/RsPb Systems 251 7.5.1 Metal-Cyanide Polymers 251 7.5.2 (Triorganostannyl)tetrazole Polymers 252 References 254 Chapter 8 Inorganic-Organic Hybrids 8.1 Introduction 257 8.2 OD Metal-Oxide Substructures 259 8.3 ID Metal-Oxide Substructures 260 8.3.1 2D Polymers with ID Metal-Oxide Substructures 261 8.3.2 3D Polymers with ID Metal-Oxide Substructures 263 8.4 2D Metal-Oxide Substructures (Pillared Layers) 264 References 271 Chapter 9 Magnetism in Coordination Polymers 9.1 Introduction 273 9.2 Long-range Magnetic Ordering 273 9.2.1 Introduction 273 9.2.2 Molecule-based Magnets 275 9.2.3 Single-chain Magnets 293 9.3 Spin Crossover 295 9.3.1 Introduction 295 9.3.2 Five-membered Heterocyclic Ring Bridging Ligands 297 9.3.3 Six-membered Ring Bridging Ligands 301 9.3.4 Cyanide Bridges in Hofmann Phases 305 References 307 Chapter 10 Porous Coordination Polymers 10.1 Introduction 313 10.1.1 Terminology 313 10.2 Designing Permanent Porosity 315 10.2.1 Flexible Porosity 317 10.2.2 Rigid Porosity 322 10.3 Solvent Exchange 326 10.3.1 Flexible Guest Exchange 327 10.3.2 Rigid Guest Exchange 329 10.4 Gas Storage 330 10.4.1 Hydrogen Gas Storage 331 10.4.2 Methane Gas Storage 335 Contents xjj¡ 10.4.3 Carbon Dioxide Gas Storage 336 10.4.4 Other Gases 337 10.5 Ion Exchange 338 10.6 Multifunctional Porous Materials 338 10.7 Conclusion 340 References 341 Chapter 11 Acentric and Chiral Networks 11.1 Introduction 345 11.2 Acentric Networks for Non-linear Optical Behaviour 346 11.3 Chiral Networks 352 11.3.1 ID Helices from Achiral Components 352 11.3.2 2D Chiral Nets from Achiral Components 354 11.3.3 3D Chiral Nets from Achiral Components 355 11.3.4 Chiral Ligands 361 11.3.5 Applications 367 References 369 Chapter 12 Reactive Coordination Polymers 12.1 Introduction 375 12.2 Topotactic Reactions 375 12.3 Chemically Reactive Ligands 386 12.4 Catalysis 386 References 391 Chapter 13 Other Properties of Coordination Polymers 13.1 Introduction 396 13.2 Luminescence 397 13.3 Redox Activity 399 13.4 Conductivity 401 13.5 Negative Thermal Expansion 404 13.6 Multifunctional Materials 407 References 408 Subject Index 416 Coordination Polymers: Design, Analysis and Application ¡s the first book to provide a broad overview of all the major facets of coordination polymer research. It combines chapters on nets and interpénétration with wide-ranging surveys of transition metal and rare earth coordination polymers and their properties.The aim is to provide a flavour of each aspect of coordination polymers whilst introducing the important concepts and developments using carefully selected examples. After an introduction, the text is split into three sections: •Design (nets, interpénétration, malleability) •Analysis (transition metal coordination polymers, rare earth coordination polymers, organometallic networks, organic-inorganic hybrids) •Application (magnetic properties, porosity, acentric and chiral networks, reactive coordination polymers, other properties). Written in the style of a tutorial review, the book is suitable for both senior specialists and new postgraduate students taking theirfirst steps in the field. Coordination Polymers: Design, Analysis and Application also provides an authoritative and detailed reference source.
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spellingShingle	Batten, Stuart R. Neville, Suzanne M. Turner, David R. Coordination polymers design, analysis and application Polymerkomplexe (DE-588)4137334-0 gnd Supramolekulare Struktur (DE-588)4208977-3 gnd
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title	Coordination polymers design, analysis and application
title_auth	Coordination polymers design, analysis and application
title_exact_search	Coordination polymers design, analysis and application
title_full	Coordination polymers design, analysis and application Stuart R. Batten ; Suzanne M. Neville and David R. Turner
title_fullStr	Coordination polymers design, analysis and application Stuart R. Batten ; Suzanne M. Neville and David R. Turner
title_full_unstemmed	Coordination polymers design, analysis and application Stuart R. Batten ; Suzanne M. Neville and David R. Turner
title_short	Coordination polymers
title_sort	coordination polymers design analysis and application
title_sub	design, analysis and application
topic	Polymerkomplexe (DE-588)4137334-0 gnd Supramolekulare Struktur (DE-588)4208977-3 gnd
topic_facet	Polymerkomplexe Supramolekulare Struktur
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Call Number:	0302 CHE 700f 2009 A 7674
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