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Biocatalytic separation of isomers using supercritical fluids:

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Bibliographic Details
Main Author:	Almeida Paiva, Alexandre Babo de 1978- (Author)
Format:	Thesis/Dissertation Book
Language:	English
Published:	2008
Subjects:	Enantiomere Enzymkatalyse Trennverfahren Überkritischer Zustand Hochschulschrift
Links:	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016728490&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Physical Description:	165 S. Ill., graph. Darst. 30 cm

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Record in the Search Index

DE-BY-TUM_call_number	0001 DA 2008 97
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adam_text	BIOCATALYTIC SEPARATION OF ISOMERS USING SUPERCRITICAL FLUIDS VOM PROMOTIONSAUSSCHUSS DER TECHNISCHEN UNIVERSITAET HAMBURG-HARBURG ZUR ERLANGUNG DES AKADEMISCHEN GRADES DOKTOR-INGENIEUR GENEHMIGTE DISSERTATION VON ALEXANDRE BABO DE ALMEIDA PAIVA AUS LISBOA, PORTUGAL 2008 CONTENTS ACKNOWLEDGEMENTS III LIST OF SYMBOLS VI 1. SUMMARY 10 2. INTRODUCTION 13 2.1. GREEN CHEMISTRY 13 2.2. ALTERNATIVE GREEN SOLVENTS 17 2.2.1. SOLVENT FREE PROCESSES 17 2.2.2. WATER 18 2.2.3. SUPERCRITICAL FLUIDS 18 2.2.3.1. APPLICATIONS 20 2.2.4. IONICLIQUIDS 21 2.2.4.1. APPLICATIONS 23 2.3. BIOCATALYSIS 24 2.3.1. HISTORY OF ENZYME DEVELOPMENT 24 2.3.2. ENZYME APPLICATIONS 25 2.3.3. LIPASES 27 2.3.4. BIOCATALYSIS IN SUPERCRITICAL CARBON DIOXIDE 28 2.3.5. ENZYMATIC PROCESSES IN BIPHASIC SYSTEM 29 2.3.6. CHIRALITY AND ENANTIOMER SEPARATION 31 2.3.6.1. KINETIC RESOLUTION 32 2.4. PHASE EQUILIBRIUM 35 2.4.1. THE NEED FOR PHASE EQUILIBRIUM 35 2.4.2. PHASE EQUILIBRIA IN MULTICOMPONENT SYSTEMS 36 2.4.2.1. THERMODYNAMICS OF VAPOR-LIQUID EQUILIBRIA 37 2.4.3. EQUATIONSOF STATE . 41 2.4.3.1. HISTORY 41 2.4.3.2. EQUATIONSOF STATE FOR MIXTURES 42 2.4.3.3. PREDICTIVE EQUATIONS OF STATE 45 2.5. STRUCTURE OF THE EXPERIMENTAL SECTION 47 3. PHASE EQUILIBRIA 50 3.1. EXPERIMENTAL SECTION 50 VII 3.1.1. MATERIALS 51 3.1.2. APPARATES 51 3.1.2.1. VIEW CELL 52 3.1.2.2. SAMPLING SECTION 53 3.1.3. METHOD 54 3.1.4. ANALYSIS 55 3.2. RESULTS 55 3.2.1. TERNARY SYSTEM (R,S)-L-PHENYLETHANOL / VINYL ACETATE / C02 55 3.2.1.1. MODELING 61 3.2.1.2. PHASE EQUILIBRIUM PREDICTION 64 3.2.2. TERNARY SYSTEM (R,S)-L-PHENYL-ETHYL ACETATE / VINYL ACETATE / C02 70 3.2.2.1. MODELING 74 3.2.3. TERNARY SYSTEM (R,S)-L-PHENYLETHANOL / (R,S)-L-PHENYL-ETHYL ACETATE / C02 78 3.2.3.1. MODELING 81 3.2.4. QUATERNARY SYSTEM VINYL ACETATE / (R,S)-L-PHENYL-ETHYL ACETATE / (R,S)-1- PHENYLETHANOL / C02 85 3.2.4.1. MODELING 91 3.3. SUMMARY CHAPTER 3 92 4. IONIC LIQUID / SCC02 SYSTEM 94 4.1. RESULTS 95 4.2. SUMMARY - CHAPTER 4 97 5. ENANTIOMERIC KINETIC RESOLUTION IN SCC02 99 5.1. EXPERIMENTAL SECTION 99 5.1.1. MATERIALS 99 5.1.2. APPARATES AND METHOD 100 5.1.2.1. BATCH REACTION APPARATES 100 5.1.2.2. CONTINUOUS REACTION APPARATES 103 5.2. RESULTS - BATCH REACTION 105 5.2.1. VINYL DECANOATE 105 5.2.2. VINYL LAURATE 107 5.2.3. VINYL STEARATE 108 5.2.4. METHYL ESTERS 111 5.2.5. ENZYME AMOUNT INFLUENCE 113 VIII 5.3. RESULTS - CONTINUOUS REACTION 115 5.4. SUMMARY CHAPTER 5 118 6. (R,S)-1-PHENYLETHANOL / (R,S)-1-PHENYL-ETHYL LAURATE SEPARATION 119 6.1. MATERIALS 119 6.2. RESULTS 119 6.3.MODELING 128 6.4. SUMMARY CHAPTER 6 131 7. CONTINUOUS KINETIC RESOLUTION AND SEPARATION OF (R,S)-1 -PHENYLETHANOL 133 7.1. MATERIALS 134 7.2. EXPERIMENTAL APPARATES 134 7.3.EXPERIMENTALMETHOD 138 7.4. RESULTS 139 7.5. SUMMARY CHAPTER 7 144 8. DISCUSSION 145 REFERENCES 149 APPENDIX A 159 GC CALIBRATION CURVES 159 CURRICULUM VITAE 164 IX
any_adam_object	1
author	Almeida Paiva, Alexandre Babo de 1978-
author_GND	(DE-588)134290186
author_facet	Almeida Paiva, Alexandre Babo de 1978-
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dewey-full	547.1223 543
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dewey-ones	547 - Organic chemistry 543 - Analytical chemistry
dewey-raw	547.1223 543
dewey-search	547.1223 543
dewey-sort	3547.1223
dewey-tens	540 - Chemistry and allied sciences
discipline	Chemie / Pharmazie
format	Thesis Book
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spellingShingle	Almeida Paiva, Alexandre Babo de 1978- Biocatalytic separation of isomers using supercritical fluids Enantiomere Enzymkatalyse Trennverfahren Überkritischer Zustand
subject_GND	(DE-588)4113937-9
title	Biocatalytic separation of isomers using supercritical fluids
title_auth	Biocatalytic separation of isomers using supercritical fluids
title_exact_search	Biocatalytic separation of isomers using supercritical fluids
title_full	Biocatalytic separation of isomers using supercritical fluids von Alexandre Babo de Almeida Paiva
title_fullStr	Biocatalytic separation of isomers using supercritical fluids von Alexandre Babo de Almeida Paiva
title_full_unstemmed	Biocatalytic separation of isomers using supercritical fluids von Alexandre Babo de Almeida Paiva
title_short	Biocatalytic separation of isomers using supercritical fluids
title_sort	biocatalytic separation of isomers using supercritical fluids
topic	Enantiomere Enzymkatalyse Trennverfahren Überkritischer Zustand
topic_facet	Enantiomere Enzymkatalyse Trennverfahren Überkritischer Zustand Hochschulschrift
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016728490&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT almeidapaivaalexandrebabode biocatalyticseparationofisomersusingsupercriticalfluids

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Call Number:	0001 DA 2008 97 Floor plan
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