Verfügbarkeit: Electronic, magnetic and optical materials

Electronic, magnetic and optical materials:

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Bibliographische Detailangaben
Beteilige Person:	Fulay, Pradeep P. (VerfasserIn)
Format:	Buch
Sprache:	Nichtbestimmte Sprache
Veröffentlicht:	Boca Raton, FL [u.a.] CRC Press 2010
Schlagwörter:	Werkstoff Magnetische Eigenschaft Optische Eigenschaft Elektronische Eigenschaft
Links:	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016136318&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Umfang:	XVII, 418 S. Ill., graph. Darst.
ISBN:	084939564X 9780849395642

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Datensatz im Suchindex

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adam_text	Contents Preface ............................................................................................................................................xiii Author ............................................................................................................................................xvii Chapter 1 Introduction ..................................................................................................................1 1.1 Introduction .......................................................................................................1 1.2 Classification of Materials .................................................................................1 1.3 Crystalline Materials .........................................................................................1 1.4 Ceramics, Metals and Alloys, and Polymers .....................................................5 1.4.1 Bonding in Materials ............................................................................5 1.5 Functional Classification of Materials ...............................................................6 1.6 Crystal Structures ..............................................................................................6 1.7 Directions and Planes in Crystal Structures ....................................................10 1.7.1 Miller Indices for Directions ..............................................................10 1.7.2 Miller Indices for Planes ....................................................................10 1.7.3 Miller-Bravais Indices for Hexagonal Systems .................................10 1.7.4 Interplanar Spacing ............................................................................11 1.8 Interstitial Sites or Holes in Crystal Structures ...............................................13 1.9 Coordination Numbers ....................................................................................13 1.10 Radius Ratio Concept ......................................................................................14 1.11 Crystal Structures of Different Materials ........................................................15 1.11.1 Structure of Sodium Chloride ............................................................15 1.11.2 Structure of Cesium Chloride ............................................................15 1.11.3 Diamond Cubic Structure ...................................................................16 1.11.4 Zinc Blende Structure ........................................................................18 1.11.5 Wurtzite Structure ..............................................................................19 1.11.6 Fluorite and Antifluorite Structure .....................................................19 1.11.7 Corundum Structure ...........................................................................19 1.11.8 Perovskite Crystal Structure ...............................................................20 1.11.9 Spinel and Inverse Spinel Structures ..................................................21 1.12 Defects in Materials ........................................................................................22 1.13 Point Defects in Ceramic Materials ................................................................23 1.14 Kröger-Vink Notation for Point Defects .........................................................24 1.15 Dislocations .....................................................................................................26 1.16 Stacking Faults and Grain Boundaries ............................................................27 1.17 Microstructure-Property Relationships ..........................................................28 1.17.1 Grain Boundary Effects .....................................................................28 1.17.2 Grain Size Effects ..............................................................................28 1.17.3 Microstructure-Insensitive Properties ................................................30 1.18 Amorphous Materials ......................................................................................30 1.18.1 Atomic Arrangements in Amorphous Materials ................................30 1.18.2 Applications of Amorphous Materials ...............................................31 1.19 Nanostructured Materials ................................................................................33 1.20 Defects in Materials: Good News or Bad News? ............................................33 1.21 Problems ..........................................................................................................33 VI Contents Glossary ......................................................................................................................34 References ..................................................................................................................37 Chapter 2 Electrical Conduction in Metals and Alloys ..............................................................39 2.1 Introduction .....................................................................................................39 2.2 Ohm s Law .......................................................................................................41 2.3 Sheet Resistance (Rs).......................................................................................46 2.4 Classical Theory of Electrical Conduction ......................................................48 2.5 Drift, Mobility, and Conductivity ....................................................................49 2.6 Electronic and Ionic Conductors .....................................................................52 2.7 Limitations of the Classical Theory of Conductivity ......................................52 2.8 Resistivity of Metallic Materials .....................................................................55 2.8.1 Effect of Thermal Expansion .............................................................60 2.9 Joule Heating or PR Losses ............................................................................60 2.10 Dependence of Resistivity on Thickness .........................................................61 2.11 Chemical Composition-Microstructure-Conductivity Relationships in Metals ...................................................................................62 2.11.1 Influence of Atomic-Level Defects ....................................................62 2.11.2 Influence of Impurities .......................................................................63 2.12 Resistivity of Metallic Alloys ..........................................................................66 2.13 Quantum Mechanical Approach to Conductivity ...........................................69 2.14 Electrons in an Atom .......................................................................................71 2.15 Electrons in a Solid ..........................................................................................72 2.16 Band Structure of Solids ..................................................................................73 2.17 Concept of the Fermi Energy Level ................................................................76 2.18 Problems ..........................................................................................................77 Glossary ......................................................................................................................80 References ..................................................................................................................83 Chapter 3 Fundamentals of Semiconductor Materials ...............................................................85 3.1 Introduction .....................................................................................................85 3.2 Intrinsic Semiconductors .................................................................................85 3.3 Temperature Dependence of Carrier Concentrations ......................................89 3.4 Band Structure of Semiconductors ..................................................................90 3.5 Direct and Indirect Bandgap Semiconductors .................................................96 3.6 Applications of Direct Bandgap Materials ......................................................96 3.7 Motions of Electrons and Holes ....................................................................100 3.8 Extrinsic Semiconductors ..............................................................................102 3.9 Donor-Doped (η -Type) Semiconductors ........................................................102 3.10 Acceptor-Doped (p -Туре) Semiconductors ...................................................103 3.11 Amphoteric Dopants, Compensation, and Isoelectronic Dopants ................104 3.12 Dopant Ionization ..........................................................................................105 3.13 Conductivity of Intrinsic and Extrinsic Semiconductors ..............................109 3.14 Effect of Temperature on the Mobility of Carriers .......................................111 3.15 Effect of Dopant Concentration on Mobility .................................................112 3.16 Temperature Dependence of Conductivity ....................................................114 3.17 Effect of Partial Dopant Ionization ...............................................................114 3.18 Effect of Temperature on the Bandgap ..........................................................117 3.19 Effect of Dopant Concentration on the Bandgap (£ )...................................119 Contents VII 3.20 Effect of Crystallite Size on the Bandgap ....................................................119 3.21 Semiconductivity in Ceramic Materials ........................................................120 3.22 Problems ........................................................................................................121 Glossary ....................................................................................................................122 References ................................................................................................................124 Chapter 4 Fermi Energy Levels in Semiconductors .................................................................127 4.1 Fermi Energy Levels in Metals .....................................................................127 4.2 Fermi Energy Levels in Semiconductors ......................................................129 4.3 Electron and Hole Concentrations .................................................................131 4.4 Fermi Energy Levels in Intrinsic Semiconductors ........................................134 4.5 Carrier Concentrations in Intrinsic Semiconductors .....................................136 4.6 Fermi Energy Levels in η -Type and p -Туре Semiconductors ........................138 4.7 Fermi Energy as a Function of the Temperature ...........................................140 4.8 Fermi Energy Positions and the Fermi-Dirac Distribution ..........................143 4.9 Degenerate or Heavily Doped Semiconductors .............................................143 4.10 Fermi Energy Levels across Materials and Interfaces ..................................145 4.11 Problems ........................................................................................................147 Glossary ....................................................................................................................148 References ................................................................................................................149 Chapter 5 Semiconductor p -η Junctions ...................................................................................151 5.1 Formation of a p -η Junction ...........................................................................151 5.2 Drift and Diffusion of Carriers .....................................................................154 5.3 Constructing the Band Diagram for a p -η Junction ......................................154 5.4 Calculation of Contact Potential ....................................................................157 5.5 Space Charge at the p -η Junction ..................................................................160 5.6 Electric Field Variation across the Depletion Region ................................... 161 5.7 Variation of Electric Potential .......................................................................162 5.8 Width of the Depletion Region and Penetration Depths ...............................164 5.9 Reverse-Biased p -η Junction .........................................................................166 5.10 Diffusion Currents in a Forward-Biased p -η Junction ..................................167 5.11 Drift Currents in a p -η Junction ....................................................................168 5.12 Diode Based on a p -η Junction ...................................................................... 171 5.13 Reverse-Bias Breakdown ...............................................................................174 5.14 Zener Diodes .................................................................................................178 5.15 Problems ........................................................................................................180 Glossary .................................................................................................................... 181 References ................................................................................................................183 Chapter 6 Semiconductor Devices ............................................................................................185 6.1 Metal-Semiconductor Contacts ....................................................................185 6.2 Schottky Contacts ..........................................................................................185 6.2.1 Band Diagrams .................................................................................185 6.2.2 Surface Pinning of the Fermi Energy Level ....................................188 6.2.3 Current-Voltage Characteristics for Schottky Contacts ..................189 6.2.4 Advantages of Schottky Diodes .......................................................193 6.3 Ohmic Contacts .............................................................................................194 6.3.1 Band Diagram ..................................................................................194 viii Contents 6.4 Solar Cells .....................................................................................................194 6.4.1 Principles of Operation ....................................................................197 6.4.2 Current-Voltage Characteristics for a Solar Cell .............................201 6.4.3 Solar Cell Efficiency and Materials .................................................203 6.5 Light-Emitting Diodes ...................................................................................203 6.5.1 Operating Principle ..........................................................................204 6.5.2 LED Materials ..................................................................................204 6.5.3 LEDs Based on Indirect Bandgap Materials ....................................206 6.5.4 LED Emission Spectral Ranges .......................................................207 6.5.5 7-У Curve for LEDs.........................................................................208 6.5.6 LED Efficiency .................................................................................210 6.5.7 LED Packaging ................................................................................210 6.6 Bipolar Junction Transistor ............................................................................210 6.6.1 Principles of Operation of the Bipolar Junction Transistor ..............212 6.6.2 Bipolar Junction Transistor Action ...................................................213 6.6.3 Current Flows in an npn Transistor ..................................................213 6.6.4 Transistor Currents and Parameters .................................................215 6.6.4.1 Collector Current ..............................................................215 6.6.4.2 Emitter Current .................................................................216 6.6.4.3 Base Current .....................................................................216 6.6.5 Role of Base Current ........................................................................218 6.6.6 Transistor Operating Modes .............................................................218 6.6.7 Current-Voltage Characteristics of the Bipolar Junction Transistor ..........................................................................................218 6.6.8 Current Flows in a pnp Transistor ....................................................220 6.6.9 Applications of Bipolar Junction Transistors ...................................220 6.7 Field-Effect Transistors .................................................................................223 6.8 Types of Field-Effect Transistors ...................................................................223 6.9 MESFET/-V Characteristics ........................................................................224 6.9.1 MESFET with No Bias ....................................................................224 6.9.2 MESFET with a Gate Bias ...............................................................225 6.10 Metal Insulator Field-Effect Transistors ........................................................226 6.11 Metal Oxide Semiconductor Field-Effect Transistors ...................................226 6.11.1 MOSFET in Integrated Circuits .......................................................226 6.11.2 Role of Materials in MOSFET .........................................................226 6.11.3 NMOS, PMOS, and CMOS Devices ................................................228 6.11.4 Enhancement-Mode MOSFET .........................................................229 6.11.5 Mechanism for Enhancement MOSFET ..........................................230 6.11.6 Depletion-Mode MOSFET ...............................................................232 6.12 Problems ........................................................................................................232 Glossary ....................................................................................................................234 References ................................................................................................................238 Chapter 7 Linear Dielectric Materials ......................................................................................239 7.1 Dielectric Materials .......................................................................................239 7.1.1 Electrostatic Induction .....................................................................239 7.2 Capacitance and Dielectric Constant ............................................................240 7.2.1 Parallel-Plate Capacitor Filled with a Vacuum ................................240 7.2.2 Parallel-Plate Capacitors with an Ideal Dielectric Material .............242 7.3 Dielectric Polarization ...................................................................................249 Contents ix 7.4 Local Electric Field (£local) ............................................................................252 7.5 Polarization Mechanisms — Overview ..........................................................254 7.6 Electronic or Optical Polarization .................................................................254 7.6.1 Electronic Polarization of Atoms .....................................................254 7.6.2 Electronic Polarizability of Ions and Molecules ..............................260 7.7 Ionic, Atomic, or Vibrational Polarization ....................................................260 7.8 Shannon s Polarizability Approach for Predicting Dielectric Constants ......262 7.8.1 Outline of the Approach ...................................................................262 7.8.2 Limitations of Shannon s Approach .................................................263 7.9 Dipolar or Orientational Polarization ............................................................265 7.10 Interfacial, Space Charge, or Maxwell-Wagner Polarization .......................266 7.11 Spontaneous or Ferroelectric Polarization ....................................................267 7.12 Dependence of the Dielectric Constant on Frequency ..................................268 7.12.1 Connection to the Optical Properties: Lorentz-Lorenz Equation ................................................................269 7.13 Complex Dielectric Constant and Dielectric Losses .....................................272 7.13.1 Complex Dielectric Constant ...........................................................272 7.13.2 Real Dielectrics and Ideal Dielectrics ..............................................273 7.13.3 Frequency Dependence of Dielectric Losses ...................................273 7.13.4 Giant Dielectric Constant Materials .................................................276 7.14 Equivalent Circuit of a Real Dielectric .........................................................277 7.15 Impedance (Z) and Admittance (Y) ...............................................................278 7.16 Power Loss in a Real Dielectric Material ......................................................280 7.16.1 Concept of tan б ...............................................................................280 7.17 Equivalent Series Resistance and Equivalent Series Capacitance ................285 7.18 Problems ........................................................................................................288 Glossary ....................................................................................................................293 References ................................................................................................................298 Chapterå Ferroelectrics, Piezoelectrics, and Pyroelectrics ......................................................299 8.1 Ferroelectric Materials ..................................................................................299 8.1.1 Ferroelectricity in Barium Titanate ..................................................299 8.1.2 Ferroelectric Domains ......................................................................301 8.1.3 Dependence of the Dielectric Constant of Ferroelectrics on Temperature and Composition .........................................................303 8.2 Relationship of Ferroelectrics and Piezoelectrics to Crystal Symmetry ......................................................................................................307 8.3 Electrostriction ..............................................................................................307 8.4 Ferroelectric Hysteresis Loop .......................................................................309 8.4.1 Trace of the Hysteresis Loop ............................................................311 8.5 Piezoelectricity ..............................................................................................315 8.5.1 Origin of the Piezoelectric Effect in Ferroelectrics .........................315 8.6 Direct and Converse Piezoelectric Effects ....................................................317 8.7 Piezoelectric Behavior of Ferroelectrics .......................................................318 8.8 Piezoelectric Coefficients ..............................................................................318 8.9 Tensor Nature of Piezoelectric Coefficients ..................................................321 8.9.1 Conventions for Directions ...............................................................321 8.9.2 General Notation for Piezoelectric Coefficients ...............................322 8.9.3 Signs of Piezoelectric Coefficients ...................................................322 8.10 Relationship between Piezoelectric Coefficients ...........................................323 x Contents 8.11 Applications of Piezoelectrics.......................................................................327 8.12 Devices Based on Piezoelectrics...................................................................327 8.12.1 Expander Plate ..................................................................................327 8.13 Technologically Important Piezoelectrics.....................................................333 8.14 Lead Zirconium Titanate ...............................................................................335 8.14.1 Piezoelectric Polymers .....................................................................336 8.15 Applications and Properties of Hard and Soft Lead Zirconium Titanate Ceramics ..........................................................................................339 8.16 Electromechanical Coupling Coefficient .......................................................341 8.17 Illustration of an Application: Piezoelectric Spark Igniter ............................344 8.18 Recent Developments ....................................................................................348 8.18.1 Strain-Tuned Ferroelectric s ..............................................................348 8.18.2 Lead-Free Piezoelectrics ..................................................................348 8.19 Piezoelectric Composites ...............................................................................349 8.20 Pyroelectric Materials and Devices ...............................................................351 8.20.1 Pyroelectric Detectors for Infrared Detection and Imaging ............355 8.21 Problems ........................................................................................................355 Glossary ....................................................................................................................358 References ................................................................................................................361 Chapter 9 Magnetic Materials ..................................................................................................363 9.1 Introduction ...................................................................................................363 9.2 Origin of Magnetism .....................................................................................363 9.3 Magnetization (Λί), Flux Density (B), Magnetic Susceptibility OcJ, Permeability (μ), and Relative Magnetic Permeability (μΓ) ...........................368 9.3.1 Magnetic Field (H), Magnetization (M), and Flux Density (B) ........................................................................368 9.3.2 Magnetic Susceptibility (χΜ) and Magnetic Permeability (μ) ................................................................................371 9.3.3 Demagnetizing Fields .......................................................................372 9.3.4 Flux Density in Ferromagnetic and Ferrimagnetic Materials ..........373 9.4 Classification of Magnetic Materials .............................................................374 9.4.1 Diamagnetic Materials .....................................................................374 9.4.2 Paramagnetic Materials ....................................................................374 9.4.3 Superparamagnetic Materials ..........................................................376 9.4.4 Antiferromagnetic Materials ............................................................378 9.5 Ferromagnetic and Ferrimagnetic Materials .................................................378 9.5.1 Hysteresis Loop ................................................................................378 9.6 Other Properties of Magnetic Materials ........................................................385 9.6.1 Curie Temperature (Гс) .....................................................................385 9.6.2 Magnetic Permeability (μ) ................................................................385 9.6.3 Coercive Field (Hc) ...........................................................................386 9.6.4 Nucleation and Pinning Control of Coercivity .................................388 9.6.5 Magnetic Anisotropy ........................................................................389 9.6.6 Magnetic Domain Walls ...................................................................391 9.6.7 180° and Non-1800 Domain Walls ...................................................393 9.6.8 Maximum Energy Products for Magnets .........................................394 9.6.9 Magnetic Losses ...............................................................................395 9.7 Magnetostriction ............................................................................................396 9.8 Soft and Hard Magnetic Materials ................................................................397 Contents xi 9.9 Hard Magnetic Materials ...............................................................................398 9.10 Isotropie, Textured (Oriented), and Bonded Magnets ...................................399 9.11 Soft Magnetic Materials ................................................................................400 9.12 Magnetic Data Storage Materials ..................................................................404 9.13 Problems ........................................................................................................405 Glossary ....................................................................................................................408 References ................................................................................................................412 Index ..............................................................................................................................................413
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spellingShingle	Fulay, Pradeep P. Electronic, magnetic and optical materials Werkstoff (DE-588)4065579-9 gnd Magnetische Eigenschaft (DE-588)4129002-1 gnd Optische Eigenschaft (DE-588)4123887-4 gnd Elektronische Eigenschaft (DE-588)4235053-0 gnd
subject_GND	(DE-588)4065579-9 (DE-588)4129002-1 (DE-588)4123887-4 (DE-588)4235053-0
title	Electronic, magnetic and optical materials
title_auth	Electronic, magnetic and optical materials
title_exact_search	Electronic, magnetic and optical materials
title_full	Electronic, magnetic and optical materials Pradeep Fulay
title_fullStr	Electronic, magnetic and optical materials Pradeep Fulay
title_full_unstemmed	Electronic, magnetic and optical materials Pradeep Fulay
title_short	Electronic, magnetic and optical materials
title_sort	electronic magnetic and optical materials
topic	Werkstoff (DE-588)4065579-9 gnd Magnetische Eigenschaft (DE-588)4129002-1 gnd Optische Eigenschaft (DE-588)4123887-4 gnd Elektronische Eigenschaft (DE-588)4235053-0 gnd
topic_facet	Werkstoff Magnetische Eigenschaft Optische Eigenschaft Elektronische Eigenschaft
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016136318&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT fulaypradeepp electronicmagneticandopticalmaterials

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