Pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic aromatic hydrocarbons (PAHs) into the North Sea: research report 2972252994828
Gespeichert in:
Beteiligte Personen: | , |
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Format: | Buch |
Sprache: | Englisch |
Veröffentlicht: |
Berlin
Umweltbundesamt
2000
|
Schriftenreihe: | Deutschland / Umweltbundesamt: Texte
2000,18 Environmental research of the Federal Ministry of the Environment, Nature Conservation and Nuclear Safety : research project water |
Schlagwörter: | |
Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009133021&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
Beschreibung: | Literaturverz. S. 129 - 136 |
Umfang: | XI, 136, [28] S. Ill., graph. Darst. : 29 cm |
Internformat
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Datensatz im Suchindex
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adam_text | Titel: Pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic
Autor: Heininger, Peter
Jahr: 2000
Table of Contents
Page
List of abbreviations IV
List of tables VIII
List of figures X
1. Introduction 1
2. Study area Elbe 4
3. Determination of particulate-bound loads via estuaries 7
4. Partition behaviour of non-polar organic contaminants 10
4.1 Fundamentals 10
4.2 Properties and partition behaviour of PAHs 12
4.3 Partition behaviour of PCBs 17
5. Sampling of suspended matter 19
6. Project goals and study programme 24
6.1 Project goals 24
6.2 Study programme 26
6.2.1 Monitoring stations 26
6.2.2 Sampling programme 27
6.2.3 Studies on a comparison of sampling methods 31
6.2.4 Parameter range 41
6.2.5 Analytical methods 44
6.2.6 Analytical quality assurance and plausibility testing 45
7. Hydrological situation and suspended matter regimen
of the river Elbe 46
II
7.2 Suspended matter regimen 49
8. Balancing profile Schnackenburg 52
8.1 Basic parameters of river water samples for suspended
matter collection 53
8.2 Variability in the cross profile 55
8.3 Variability in run-off and season 61
8.4 PAH pattern, balancing and partition coefficients 63
8.4.1 Methodological studies to determine PAHs 63
8.4.2 PAH pattern 64
8.4.3 Balancing of PAH contents 65
8.4.4 Partition coefficients 68
8.4.4.1 PAHs 68
8.4.4.2 PCBs and HCB 69
8.5 Influence of sampling technique on the composition
of suspended matter 70
8.5.1 Structural parameters and phosphorus 71
8.5.2 Organic contaminants 76
8.5.3 Heavy metals and arsenic 77
8.5.4 Filtration effects 79
9. Balancing profile Seemannshoft 80
9.1 Basic parameters of river water samples for the collection
of suspended matter 80
9.2 Variations in tidal course 84
9.2.1 Organic contaminants 84
9.2.2 Elements 88
9.3 Variability in the cross-section 91
9.3.1 Basic parameter 91
9.3.2 Organic contaminants 91
9.3.3 Elements 94
9.4 Variability depending on run-off and season 96
9.5 PAH patterns, balancing and partition coefficients 99
Ill
9.5.1 Parameters for PAH determination and balancing
of PAH contents 99
9.5.2 PAH patterns 101
9.5.3 Partition coefficients 101
9.5.3.1 PAHs 101
9.5.3.2 PCBs and HCB 104
9.6 Influence of sampling method on suspended matter composition 105
9.6.1 Structural parameters and phosphorus 105
9.6.2 Organic contaminants 109
9.6.3 Heavy metals and arsenic 110
9.6.4 Extensive comparison of flow-through centrifuge and sedimentation tank 111
10. Summary and recommendations 115
10.1 Incidence, pattern and partition behaviour of PAHs 115
10.2 Statements on the partition behaviour of other
priority pollutants 118
10.3 Run-off related and seasonal variability 118
10.4 Variability in the cross-section 120
10.5 Tidal course 121
10.6 Differences in suspended matter regimen and
composition at the monitoring stations 122
10.7 Balancing of particulate contaminant input 123
10.8 Comparison of sampling methods for suspended matter 125
11. References 129
Annex 1: Methods
Annex 2: Compiled data
Annex 3: Original data (Diskette)
VIII
List of Tables
2-1: Data on large river areas of the North Sea and central Europe
4.2-1: Partition coefficients of PAHs and distribution to phases (selection)
4.3-1: Partition coefficients of PCBs and distribution to phases (selection)
5-1: Techniques of suspended matter sampling (selection)
6.2.2-1: Study programme at S chnackenburg/Wittenberge
6.2.2-2: Study programme at Seemannshoft/Nienstedten
6.2.2-3: Measuring activities in Schnackenburg/Wittenberge (July 1998)
6.2.2-4: Measuring activities in Seemannshoft/Nienstedten (June 1998)
6.2.4-1: Parameter range
7.1-1: Monitoring sites, reference water gauge and main hydrological values
7.1-2: Run-off conditions during sampling
7.1-3: Flow-through relations Elbe - Saale - Havel
Balancing profile Schnackenburg/Wittenberge
8.2-1: Composition of suspended matter samples from the left side of the Elbe
8.3-1: Suspended matter quality depending on run-off and season
8.4.1-1: Statistical data for PAH determination
8.4.3-1: Balancing of PAH contents
8.4.4-1: Partition coefficients for PAHs
8.4.4-2: Partition coefficients for PCBs and HCB
8.5.1-1: Percentage deviations from the representative cross-section sample
(structural parameters and phosphorus)
8.5.3-1: Deviations from the representative cross profile sample
(heavy metals and arsenic)
Balancing profile Seemannshoft/Nienstedten
9.1-1: Suspended matter concentrations
9.2.1-1: Concentration fluctuations of organic pollutants in the tidal course
9.2.2-1: Concentration fluctuations of selected elements in the tidal course
IX
9.3-1: Variability of suspended matter parameters in the cross-section
Seemannshoft/Nienstedten
9.4-1: Suspended matter composition depending on upstream run-off and season
9.5.1-1: Parameters for PAH determination
9.5.1-2: Balancing of PAH contents
9.5.3.1-1: Mean partition coefficients for PAHs
9.5.3.1-2: Comparison of partition coefficients for PAHs
9.5.3.2-1: Mean partition coefficients for PCBs and HCB
9.5.3.2-2: Comparison of partition coefficients for PCBs and HCB
9.6.1-1: Deviations as a percentage from the cross-section sample
(structural parameters and phosphorus)
9.6.3-1: Deviations as a percentage from the cross-section sample
(heavy metals and arsenic)
9.6.4-1: Extensive comparison of flow-through centrifuge and sedimentation tank
10-1: Suspended matter data for the Elbe
Annexes
A.2-1: Balancing and partition coefficients for PAHs (Schnackenburg)
A.2-2: Balancing and partition coefficients for PCBs and HCB (Schnackenburg)
A.2-3: Balancing and partition coefficients for selected elements (Schnackenburg)
A.2-4: Influence of sampling method on suspended matter quality (Schnackenburg)
A.2-5: Variations of selected suspended matter contents in tidal course
A.2-6: Variations of selected suspended matter contents in the cross-section
A.2-7: Balancing and partition coefficients for PAHs (Seemannshoft)
A.2-8: Balancing and partition coefficients for PCBs and HCB (Seemannshoft)
A.2-9: Balancing and partition coefficients for selected elements (Seemannshoft)
A.2-10: Influence of sampling method on suspended matter quality (Seemannshoft)
X
List of figures
2-1: Mean PAH contents in the Elbe sediment
6.2.3-1: Comparison of different sampling methods for suspended matter in
Schnackenburg
6.2.3-2: Monitoring ship Nige Wark
6.2.3-3: CUX sampler in use
6.2.3-4: Principle of the CUX sampler
6.2.3-5: Monitoring ship Elbegrund
6.2.3-6: Assembling the flow-through centrifuge for sampling
6.2.3-7: Flow-through centrifuge Padberg Z 61
6.2.3-8: Diagram of the continuous flow centrifuge Padberg Z 61
6.2.3-9: Sedimentation tank of ARGE Elbe in use
6.2.3-10: Diagram of a sedimentation tank
6.2.3-11: Diagram of the suspended matter collector BISAM
6.2.4-1: Overview of monitoring parameters
7.1-1: Run-offs at the water gauge Tangermunde in the years 1990-1997
7.2-1: Mean annual loads 1992-1997 of suspended matter in the Elbe
7.2-2: Mean monthly values of suspended matter concentration in the Middle Elbe
(year series 1992-1997)
Balancing profile SchnackenburgAVittenberge
8.1-1: Suspended matter contents of river water samples
8.1-2: Organic carbon in river water samples
8.1-3: DOC/TOC ratio in river water samples
8.2-1: Distribution of conductivity in the cross profile
8.2-2: Conductivity throughout the year 1998
8.2-3: Composition of suspended matter in November
8.2-4: Characteristics of suspended matter in January
8.2-5: Elements in suspended matter samples
XI
8.2-6: Organic contaminants in suspended matter samples
8.4.2-1: PAH patterns / dissolved phase
8.4.2-2: PAH patterns / participate phase
8.5.1-1: Ignition losses in suspended matter samples
8.5.1-2: Particle size distribution of suspended matter samples
8.5.2-1: Organic contaminants in suspended matter samples
Balancing profile Seemannshoft/Nienstedten
9.1-1: Suspended matter contents in river water samples
9.1-2: Current velocities in the cross-section
9.1-3: Organic carbon in river water samples
9.1-4: DOC/TOC ratio in river water samples
9.2.1-1: PAH concentrations in the tidal course
9.2.1-2: PCB and HCB concentrations in the tidal course
9.2.2-1: Element concentrations in the tidal course
9.3.2-1: Organic contaminants in the cross-section Nienstedten
9.3.3-1: Elements in the cross-section Nienstedten
9.5.2-1: PAH patterns/dissolved phase
9.5.2-2: PAH patterns/particulate phase
9.6.1-1: Ignition losses of suspended matter samples
9.6.1-2: Particle size distribution of suspended matter samples
9.6.2-1: Organic contaminants depending on sampling method
9.6.4-1: Concentration relations - sedimentation tank to flow-through centrifuge
|
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series2 | Deutschland / Umweltbundesamt: Texte Environmental research of the Federal Ministry of the Environment, Nature Conservation and Nuclear Safety : research project water |
spellingShingle | Heininger, Peter Claus, Evelyn Pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic aromatic hydrocarbons (PAHs) into the North Sea research report 2972252994828 Projekt (DE-588)4115645-6 gnd Schadstoffeintrag (DE-588)4510651-4 gnd Polycyclische Aromaten (DE-588)4175141-3 gnd Umweltanalytik (DE-588)4282985-9 gnd |
subject_GND | (DE-588)4115645-6 (DE-588)4510651-4 (DE-588)4175141-3 (DE-588)4282985-9 (DE-588)4042579-4 (DE-588)4014170-6 |
title | Pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic aromatic hydrocarbons (PAHs) into the North Sea research report 2972252994828 |
title_auth | Pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic aromatic hydrocarbons (PAHs) into the North Sea research report 2972252994828 |
title_exact_search | Pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic aromatic hydrocarbons (PAHs) into the North Sea research report 2972252994828 |
title_full | Pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic aromatic hydrocarbons (PAHs) into the North Sea research report 2972252994828 by Peter Heininger (project co-ordinator) ; Evelyn Claus. With the support of Jürgen Pelzer ... Umweltbundesamt. [Red.: Fachgebiet II 3.2. Durchführende Inst. Bundesanstalt für Gewässerkunde Koblenz, Berlin, Abteilung Berlin] |
title_fullStr | Pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic aromatic hydrocarbons (PAHs) into the North Sea research report 2972252994828 by Peter Heininger (project co-ordinator) ; Evelyn Claus. With the support of Jürgen Pelzer ... Umweltbundesamt. [Red.: Fachgebiet II 3.2. Durchführende Inst. Bundesanstalt für Gewässerkunde Koblenz, Berlin, Abteilung Berlin] |
title_full_unstemmed | Pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic aromatic hydrocarbons (PAHs) into the North Sea research report 2972252994828 by Peter Heininger (project co-ordinator) ; Evelyn Claus. With the support of Jürgen Pelzer ... Umweltbundesamt. [Red.: Fachgebiet II 3.2. Durchführende Inst. Bundesanstalt für Gewässerkunde Koblenz, Berlin, Abteilung Berlin] |
title_short | Pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic aromatic hydrocarbons (PAHs) into the North Sea |
title_sort | pilot study to elaborate a harmonised method for the determination of riverine inputs of polycyclic aromatic hydrocarbons pahs into the north sea research report 2972252994828 |
title_sub | research report 2972252994828 |
topic | Projekt (DE-588)4115645-6 gnd Schadstoffeintrag (DE-588)4510651-4 gnd Polycyclische Aromaten (DE-588)4175141-3 gnd Umweltanalytik (DE-588)4282985-9 gnd |
topic_facet | Projekt Schadstoffeintrag Polycyclische Aromaten Umweltanalytik Nordsee Elbe |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=009133021&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV005532599 |
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