Essential trends in inorganic chemistry:
Gespeichert in:
| Beteilige Person: | |
|---|---|
| Format: | Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
Oxford [u.a.]
Oxford Univ. Press
1998
|
| Schlagwörter: | |
| Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008131228&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008131228&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| Beschreibung: | Hier auch später erschienene, unveränderte Nachdrucke |
| Umfang: | VI, 392 S. Ill., graph. Darst. |
| ISBN: | 0198501080 0198501099 9780198501084 |
Internformat
MARC
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| 100 | 1 | |a Mingos, David M. P. |d 1944- |e Verfasser |0 (DE-588)115395342 |4 aut | |
| 245 | 1 | 0 | |a Essential trends in inorganic chemistry |c D. M. P. Mingos |
| 264 | 1 | |a Oxford [u.a.] |b Oxford Univ. Press |c 1998 | |
| 300 | |a VI, 392 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Hier auch später erschienene, unveränderte Nachdrucke | ||
| 650 | 0 | 7 | |a Anorganische Chemie |0 (DE-588)4002145-2 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4123623-3 |a Lehrbuch |2 gnd-content | |
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| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-008131228 | |
Datensatz im Suchindex
| DE-BY-TUM_call_number | 0302 CHE 300f 1998 A 5008 |
|---|---|
| DE-BY-TUM_katkey | 1184427 |
| DE-BY-TUM_location | 03 |
| DE-BY-TUM_media_number | 040030075760 |
| _version_ | 1821931196792176640 |
| adam_text | Contents
1
The quantum mechanical basis of the
Periodic Table
1
1.1
Introduction
1
1.2
Atomic
orbitais
1
1.3
Polyelectronic atoms
6
1.4
The modern Periodic Table
11
1.5
Exchange energies
14
1.6
Closed shells and half-filled shells
15
1.7
Orbital types and the Periodic Table
17
1.8
Angular part of the wave function
19
1.9
Radial part of the wave function
24
1.10
Commonality of electronic
configurations
27
1.11
Nuclear stabilities
29
1.12
Summary
33
2
Vertical trends for the
s
and
ρ
block
elements
35
2.1
Trends associated with properies of
isolated atoms
35
2.2
Trends associated with the physical
properies of elements
46
2.3
Trends associated with the chemical
properties of the elements
59
2.4
Structural and bonding aspects of
compounds
70
2.5
Trends associated with physical
properties of compounds
93
2.6
Trends in chemical properties of
compounds
104
2.7
Modification of properties using steric
and electronic effects 1
13
2.8
Tables of properties and summaries of
trends
124
3
Horizontal and diagonal trends for the
s
and
ρ
block elements
162
3.1
Introduction
162
3.2
Variations in atomic properties
162
3.3
Variations in physical properties of the
elements
169
3.4
Variations in chemical properties
173
3.5
Ionic-covalent transition
177
3.6
Oxides
181
3.7
Hydrides
184
3.8
Common oxidizing and reducing
agents
187
3.9
Catenation
194
3.10
Lone pairs and empty
orbitais
195
3.11
Comparison of
/Vand N+
10
groups
196
3.12
Diagonal relationships
202
3.
1
3
Diagonal relationships in rows
2
and3
207
4
Isoelectronic and isostoichiometric
relationships
211
4.1
Introduction
21
1
4.2
Isoelectronic molecules and ions
213
4.3
Reactivity consequences of the structure
matrix
222
4.4
Reactivity patterns for isoelectronic
molecules
225
4.5
Octet rule, hybridization schemes, and
multiple bonding
228
4.6
Molecular orbital analysis
248
4.7
Isoelectronic relationships in catenated
and polyhedral molecules
254
4.8
Zintl isoelectronic relationships
262
4.9
Isoelectronic relationships in infinite
solids
263
4.10
Isostoichiometric relationships
267
5
Transition elements (d block), lanthanides,
and actinides (f block elements)
273
5.1
Introduction
273
5.2
Trends associated with isolated
atoms
275
5.3
Physical properties of the metals
279
5.4
Chemical properties of the metals
283
5.5
General bonding considerations
286
5.6
Chemical properties of compounds
346
5.7
Vertical trends associated with the
transition metals
361
5.8
Lanthanides
373
5.9
Actinides
380
Index
389
The growth of inorganic chemistry during the last fifty years has made it
almost impossible for the student to assimilate all the factual information avail¬
able. This book is designed to help the student begin to tackle this task by
showing exactly how a chemist uses the Periodic Table to organize and
process this mass
ofinformation.
After opening with a clear description of the quantum mechanical basis or the
Periodic Table, the author goes on to illustrate how a modern inorganic
chemist uses the basic structure of the Periodic Table to interpret a wide range
of chemical phenomena. Rather than giving the descriptive chemistries ot the
groups of elements, the author takes specific atomic, physical, and chemical
properties and illustrates how the variations are interpreted. Thus he describes
vertical trends, horizontal and diagonal trends, and then isoelectronic rela¬
tionships. The latter provides a basis for developing bonding models which
account for the structures and reactivities of molecules. Finally he describes
the horizontal and vertical relationships associated with the transition metals,
the lanthanides, and the actinides.
The basic methodology developed in Essential trends in inorganic chemistry will
enable the student to apply these basic principles to other problems and to
assimilate more detailed accounts of modern inorganic chemistry in a struc¬
tured way.
D. M. P.
Mingos
is Sir Edward
Frankland BP
Professor of Inorganic
Chemistry at Imperial College of Science, Technology and Medicine,
London, and Dean
oř
the Royal College of Science. He is the author of
Essentials of inorganic chemistry
(1995)
also published by Oxford University Press
and Introduction to cluster chemistry with D. J. Wales.
|
| any_adam_object | 1 |
| author | Mingos, David M. P. 1944- |
| author_GND | (DE-588)115395342 |
| author_facet | Mingos, David M. P. 1944- |
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| author_sort | Mingos, David M. P. 1944- |
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| classification_tum | CHE 300f |
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| dewey-full | 546 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546 |
| dewey-search | 546 |
| dewey-sort | 3546 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| genre_facet | Lehrbuch |
| id | DE-604.BV012014166 |
| illustrated | Illustrated |
| indexdate | 2024-12-20T10:22:49Z |
| institution | BVB |
| isbn | 0198501080 0198501099 9780198501084 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008131228 |
| oclc_num | 246968614 |
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| owner_facet | DE-29T DE-20 DE-91G DE-BY-TUM DE-11 DE-355 DE-BY-UBR |
| physical | VI, 392 S. Ill., graph. Darst. |
| publishDate | 1998 |
| publishDateSearch | 1998 |
| publishDateSort | 1998 |
| publisher | Oxford Univ. Press |
| record_format | marc |
| spellingShingle | Mingos, David M. P. 1944- Essential trends in inorganic chemistry Anorganische Chemie (DE-588)4002145-2 gnd |
| subject_GND | (DE-588)4002145-2 (DE-588)4123623-3 |
| title | Essential trends in inorganic chemistry |
| title_auth | Essential trends in inorganic chemistry |
| title_exact_search | Essential trends in inorganic chemistry |
| title_full | Essential trends in inorganic chemistry D. M. P. Mingos |
| title_fullStr | Essential trends in inorganic chemistry D. M. P. Mingos |
| title_full_unstemmed | Essential trends in inorganic chemistry D. M. P. Mingos |
| title_short | Essential trends in inorganic chemistry |
| title_sort | essential trends in inorganic chemistry |
| topic | Anorganische Chemie (DE-588)4002145-2 gnd |
| topic_facet | Anorganische Chemie Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008131228&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008131228&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
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Teilbibliothek Chemie
| Signatur: |
0302 CHE 300f 1998 A 5008
Lageplan |
|---|---|
| Exemplar 1 | Ausleihbar Am Standort |