Verfügbarkeit: Battery hazards and accident prevention

Gespeichert in:

Bibliographische Detailangaben
Beteiligte Personen:	Levy, Samuel C. (VerfasserIn), Bro, Per (VerfasserIn)
Format:	Buch
Sprache:	Englisch
Veröffentlicht:	New York, NY [u.a.] Plenum Press 1994
Schlagwörter:	Accumulateurs - Accidents Accumulateurs - Mesures de sécurité Celulas primarias (energia eletroquimica) Piles électriques Electric batteries > Accidents Electric batteries > Safety measures Unfallverhütung Zuverlässigkeit Batterie
Links:	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007078611&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Umfang:	XIV, 351 S. graph. Darst.
ISBN:	0306447584

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adam_text	CONTENTS PART I. INTRODUCTION TO BATTERIES AND SAFETY 1. BATTERIES AND BATTERY PROCESSES 3 1.1. BATTERY STRUCTURES 6 1.2. ACTIVE MATERIALS 8 1.3. ELEMENTARY PROCESSES 12 1.3.1. PRIMARY AQUEOUS ELECTROLYTE CELLS 13 1.3.2. PRIMARY LITHIUM CELLS 14 1.3.3. RECHARGEABLE NICKEL/CADMIUM CELLS 17 1.3.4. RECHARGEABLE LEAD-ACID CELLS 18 1.3.5. PRIMARY MULTICELL BATTERIES 19 1.3.6. RECHARGEABLE MULTICELL BATTERIES 20 REFERENCES 21 2. THE NATURE OF BATTERY HAZARDS AND ACCIDENTS 23 2.1. BATTERY HAZARDS 23 2.2. ACCIDENT REPORTS 35 REFERENCES 38 PART II. FUNDAMENTAL ASPECTS OF BATTERY SAFETY 3. BATTERY LEAKAGE 43 3.1. GAS GENERATION IN BATTERIES 43 3.1.1. SPONTANEOUS GAS GENERATION, INTERNAL DRIVERS 44 3.1.2. ELECTRICAL GAS GENERATION, EXTERNAL DRIVERS ... 48 3.1.3. GAS-GENERATED CELL PRESSURES 55 3.2. OTHER INTERNAL LEAKAGE DRIVERS 58 3.3. LEAKAGE PATHS 60 3.3.1. CRIMP SEALS 61 3.3.2. HERMETIC SEALS 65 3.3.3. CORROSION-INDUCED LEAKAGE PATHS 69 3.4. EXTERNALLY INDUCED LEAKAGE 71 3.5. LEAKAGE RATES 76 3.5.1. ELECTROLYTE LEAKAGE 77 3.5.2. GAS LEAKAGE 80 REFERENCES 84 4. RUPTURES 87 4.1. MECHANICAL STRESS AND PRESSURE TOLERANCE OF CELLS 88 4.2. SAFETY VENTS 95 REFERENCES 97 5. EXPLOSIONS 99 5.1. THE CAUSE OF BATTERY EXPLOSIONS 101 5.2. THE EXPLOSIVE PROCESS 104 REFERENCES ILL 6. THERMAL RUNAWAY 113 6.1. HIGH DISCHARGE RATES 115 6.2. SHORT CIRCUITS 117 6.3. CHARGING AND OVERCHARGING 125 BIBLIOGRAPHY 131 PART III. AQUEOUS ELECTROLYTE BATTERIES 7. PRIMARY BATTERIES 135 7.1. ZINC/CARBON BATTERIES (LECLANCHE BATTERIES) 136 7.2. ZINC/CHLORIDE BATTERIES (HEAVY-DUTY ZINC/CARBON BATTERIES) 138 7.3. ALKALINE MANGANESE BATTERIES 139 7.4. SILVER OXIDE BATTERIES 140 7.5. MERCURIC OXIDE BATTERIES 142 7.6. CADMIUM/MERCURIC OXIDE BATTERIES 144 7.7. ZINC/AIR BATTERIES 145 7.8. PRIMARY BATTERY MATERIALS AND TOXICITY 147 7.8.1. CADMIUM 148 7.8.2. MANGANESE 148 7.8.3. MERCURY 149 7.8.4. SILVER 150 7.8.5. ZINC 151 7.9. AQUEOUS ELECTROLYTE TOXICITY 151 7.9.1. AMMONIACAL ELECTROLYTES 152 7.9.2. ALKALINE ELECTROLYTES 153 7.9.3. ZINC CHLORIDE ELECTROLYTES 155 REFERENCES 156 8. RECHARGEABLE BATTERIES 157 8.1. LEAD-ACID BATTERIES, VENTED AND SEALED 158 8.2. NICKEL/CADMIUM BATTERIES, VENTED AND SEALED 162 8.3. NICKEL/METAL HYDRIDE BATTERIES 165 8.4. NICKEL/ZINC BATTERIES 168 8.5. SILVER/ZINC BATTERIES 169 8.6. MANGANESE/ZINC BATTERIES 173 8.7. ZINC/AIR BATTERIES 174 8.8. RECHARGEABLE BATTERY MATERIALS AND TOXICITY 177 8.8.1. ANTIMONY 177 8.8.2. ARSENIC 178 8.8.3. CADMIUM 179 8.8.4. COBALT 179 8.8.5. LEAD 180 8.8.6. MANGANESE 181 8.8.7. NICKEL 181 8.8.8. SILVER 182 8.8.9. ZINC 182 8.8.10. METAL HYDRIDES 183 8.9. AQUEOUS ELECTROLYTE TOXICITY 184 8.9.1. ALKALINE ELECTROLYTES 184 8.9.2. SULFURIC ACID 184 REFERENCES 186 PART IV. LITHIUM BATTERIES 9. SOLID CATHODE LITHIUM SYSTEMS 189 9.1. LITHIUM/MANGANESE DIOXIDE 189 9.1.1. GENERAL SAFETY CONSIDERATIONS 190 9.1.2. CHEMISTRY 190 9.1.3. SAFETY-RELATED DESIGN FEATURES 191 9.1.4. ABUSE TESTS 192 9.2. LITHIUM/POLY(CARBONMONOFLUORIDE) 193 9.2.1. SAFETY-RELATED DESIGNS 194 9.2.2. SAFETY/ABUSE TESTS 194 9.3. LITHIUM/COPPER OXIDE 195 9.3.1. SAFETY-RELATED DESIGN FEATURES 196 9.3.2. SAFETY/ABUSE TESTS 196 9.4. LITHIUM/COPPER OXYPHOSPHATE 197 9.4.1. SAFETY FEATURES 198 9.5. LITHIUM/COPPER SULFIDE 198 9.5.1. CHEMISTRY 198 9.5.2. DESIGN FEATURES 199 9.5.3. SAFETY/ABUSE TESTS 199 9.6. LITHIUM/VANADIUM PENTOXIDE 200 9.6.1. CHEMISTRY 200 9.6.2. ABUSE CONDITIONS 201 9.7. LITHIUM/CHROMIUM OXIDE 201 9.7.1. SAFETY/ABUSE TESTS 201 9.8. LITHIUM/IRON SULFIDE 202 9.8.1. DESIGN FEATURES 202 9.8.2. SAFETY/ABUSE TESTS 203 9.9. LITHIUM/SILVER VANADIUM OXIDE 203 9.9.1. SAFETY TESTS 203 9.10. LITHIUM/IODINE 204 9.11. OTHER SYSTEMS 205 9.11.1. LITHIUM/SILVER CHROMATE 205 9.11.2. LITHIUM/SILVER-BISMUTH CHROMATE 205 9.11.3. LITHIUM/BISMUTH OXYCHROMATE 206 9.11.4. LITHIUM/BISMUTH OXIDE 206 9.11.5. LITHIUM/LEAD IODIDE 206 9.11.6. LITHIUM/BISMUTH-LEAD OXIDE 206 9.11.7. LITHIUM/COBALT POLYSULFIDE 206 REFERENCES 206 10. LITHIUM/THIONYL CHLORIDE BATTERIES 211 10.1. DOCUMENTED SAFETY INCIDENTS 211 10.2. HAZARDOUS REACTIONS 212 10.2.1. NORMAL DISCHARGE 212 10.2.2. FORCED OVERDISCHARGE INTO REVERSAL 213 10.2.3. CHARGING 213 10.2.4. OTHER STUDIES 214 10.2.5. INCREASED PRESSURE 214 10.3. CELL DESIGNS 215 10.3.1. CONFIGURATION 215 10.3.2. BALANCE 216 10.3.3. VENTS 219 10.3.4. SEPARATORS 220 10.3.5. OTHER SAFETY INNOVATIONS 220 10.4. THERMAL STUDIES 222 10.5. CATALYSTS 223 10.6. MODELING 223 10.7. SAFETY/ABUSE TESTS 224 10.7.1. WOUND CELLS 224 10.7.2. BOBBIN CELLS 225 10.7.3. PRISMATIC CELLS 225 10.7.4. RAT CIRCULAR CELLS 225 10.7.5. SMALL AND LARGE CELLS 225 10.7.6. ALLOY ANODE CELLS 226 REFERENCES 226 11. LITHIUM/SULFUR DIOXIDE BATTERIES 233 11.1. HAZARDOUS REACTIONS 233 11.1.1. NORMAL DISCHARGE 233 11.1.2. FORCED OVERDISCHARGE 235 11.1.3. CHARGING 236 11.1.4. REACTION ENHANCEMENT 236 11.2. CELL DESIGNS 237 11.2.1. BALANCE 237 11.2.2. VENTS 238 11.2.3. OTHER SAFETY-RELATED FEATURES 238 11.3. THERMAL STUDIES 239 11.4. MODELING 241 11.5. SAFETY/ABUSE TESTS 241 11.6. MULTICELL BATTERY PACKS 242 11.6.1. BATTERY DESIGN 242 11.6.2. SO 2 GETTER 243 REFERENCES 243 12. OTHER SOLUBLE DEPOLARIZER LITHIUM SYSTEMS 249 12.1. LITHIUM/BROMINE COMPLEX 249 12.1.1. CHEMISTRY 249 12.1.2. SAFETY/ABUSE TESTS 250 12.1.3. DESIGN 251 12.2. LITHIUM/SULFURYL CHLORIDE 251 12.2.1. CHEMISTRY 251 12.2.2. ABUSE TESTS 252 12.3. LITHIUM/CHLORINE IN SULFURYL CHLORIDE 252 12.3.1. SAFETY DESIGN FEATURES 252 12.3.2. ABUSE TESTS 253 REFERENCES 254 13. RECHARGEABLE LITHIUM SYSTEMS 257 13.1. LITHIUM/MOLYBDENUM DISULFIDE 257 13.1.1. GENERAL/DESIGN 257 13.1.2. SAFETY/ABUSE TESTS 258 13.2. LITHIUM TITANIUM DISULFIDE 259 13.2.1. SAFETY-RELATED CHEMISTRY 260 13.2.2. DESIGN 261 13.2.3. OVERCHARGE PROTECTION 261 13.2.4. SAFETY/ABUSE TESTS 261 13.3. LITHIUM/MANGANESE DIOXIDE 262 13.3.1. DESIGN 262 13.3.2. CHEMISTRY 262 13.3.3. ABUSE TESTS 263 13.4. LITHIUM/SULFUR DIOXIDE 263 13.4.1. CHEMISTRY 264 13.4.2. SAFETY/ABUSE TESTS 264 13.5. LITHIUM/COBALT OXIDE 265 13.5.1. DESIGN FEATURES 265 13.5.2. GAS EVOLUTION 266 13.5.3. ABUSE TESTS 266 13.6. LITHIUM/NIOBIUM TRISELENIDE 266 13.6.1. SAFETY/ABUSE TESTS 267 13.7. LITHIUM/VANADIUM OXIDE 267 13.8. LITHIUM/CHROMIUM OXIDE 268 13.9. LITHIUM/NIOBIUM PENTOXIDE 268 13.10. LITHIUM ION SYSTEMS 268 13.10.1. LITHIUM ION/COBALT OXIDE 269 13.10.2. OTHER SYSTEMS 269 REFERENCES 270 14. HIGH-TEMPERATURE SYSTEMS 273 14.1. SODIUM/SULFUR 273 14.1.1. CHEMISTRY 273 14.1.2. CELL DESIGN 274 14.1.3. MULTICELL BATTERY DESIGN 275 14.1.4. SAFETY/ABUSE TESTS 276 14.1.5. SAFETY STATUS 278 14.2. LITHIUM/IRON SULFIDE 278 14.2.1. DESIGN 279 14.2.2. SAFETY TESTS 279 14.3. LITHIUM/IRON DISULFIDE THERMAL BATTERIES 280 14.3.1. DESIGN 280 14.3.2. SAFETY/ABUSE TESTS 281 REFERENCES 281 PART V. ACCIDENT PREVENTION 15. SAFETY EVALUATION 287 15.1. TYPES OF SAFETY/ABUSE TESTS 287 15.1.1. ELECTRICAL TESTS 287 15.1.2. ENVIRONMENTAL TESTS 289 15.2. TEST PROTOCOLS FOR LITHIUM BATTERIES 291 15.2.1. U.S. NAVY 291 15.2.2. UNDERWRITERS LABORATORY 291 15.3. TEST PROTOCOLS FOR NONLITHIUM BATTERIES 293 15.4. SAFETY TESTING DURING DESIGN 294 15.4.1. ACCELERATING RATE CALORIMETRY 295 15.4.2. CELL PRESSURE MEASUREMENTS 296 15.4.3. OTHER CONSIDERATIONS 296 15.5. SAFETY PROCEDURES 296 15.5.1. HOT CELLS 297 15.5.2. FIRES 297 REFERENCES 298 16. AQUEOUS ELECTROLYTE BATTERIES 299 16.1. DESIGNING FOR SAFETY 299 16.2. BATTERY OPERATING PROCEDURES 306 16.3. REGULATORY ASPECTS 309 16.4. BATTERY DISPOSAL 311 17. AMBIENT TEMPERATURE LITHIUM SYSTEMS 313 17.1. PRIMARY CELLS 314 17.1.1. DESIGNING CELLS FOR SAFETY 314 17.1.2. SAFE HANDLING OF LITHIUM CELLS AND BATTERIES . . 316 17.1.3. MULTICELL BATTERIES 317 17.1.4. FIRE SAFETY 319 17.2. RECHARGEABLE CELLS 319 17.2.1. CHEMICAL CONSIDERATIONS 320 17.2.2. OVERCHARGE PROTECTION 320 17.2.3. SHORT-CIRCUIT PREVENTION 321 17.2.4. LITHIUM DENDRITE SUPPRESSION 321 17.2.5. MULTICELL BATTERIES 322 REFERENCES 322 18. STORAGE, TRANSPORTATION, AND DISPOSAL OF LITHIUM CELLS 325 18.1. STORAGE 325 18.2. TRANSPORTATION 326 18.2.1. CELLS CONTAINING LESS THAN 0.5 G OF LITHIUM . . . 326 18.2.2. CELLS CONTAINING MORE THAN 0.5 G OF LITHIUM . . 326 18.2.3. SPECIAL EXEMPTIONS 328 18.2.4. DISCHARGED CELLS 328 18.2.5. SHIPMENT OUTSIDE THE UNITED STATES 329 18.3. DISPOSAL 329 18.3.1. TREATMENTS 329 18.3.2. TECHNOLOGIES 330 REFERENCES 332 DEFINITIONS AND ABBREVIATIONS 333 APPENDIX: SPECIALTY BATTERIES 337 1. NICKEL/HYDROGEN CELLS 337 2. SILVER/HYDROGEN CELLS 338 3. REDOX FLOW BATTERIES 338 3.1. IRON-CHROMIUM REDOX SYSTEM 339 3.2. ZINC/FERRICYANIDE SYSTEM 339 4. LIQUID AMMONIA BATTERY 339 5. ALUMINUM-AIR SYSTEM 340 6. ZINC/BROMINE BATTERY 341 7. ZINC/CHLORINE BATTERY 342 REFERENCES 343 INDEX 345
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spellingShingle	Levy, Samuel C. Bro, Per Battery hazards and accident prevention Accumulateurs - Accidents ram Accumulateurs - Mesures de sécurité ram Celulas primarias (energia eletroquimica) larpcal Piles électriques ram Electric batteries Accidents Electric batteries Safety measures Unfallverhütung (DE-588)4061706-3 gnd Zuverlässigkeit (DE-588)4059245-5 gnd Batterie (DE-588)4004687-4 gnd
subject_GND	(DE-588)4061706-3 (DE-588)4059245-5 (DE-588)4004687-4
title	Battery hazards and accident prevention
title_auth	Battery hazards and accident prevention
title_exact_search	Battery hazards and accident prevention
title_full	Battery hazards and accident prevention Samuel C. Levy and Per Bro
title_fullStr	Battery hazards and accident prevention Samuel C. Levy and Per Bro
title_full_unstemmed	Battery hazards and accident prevention Samuel C. Levy and Per Bro
title_short	Battery hazards and accident prevention
title_sort	battery hazards and accident prevention
topic	Accumulateurs - Accidents ram Accumulateurs - Mesures de sécurité ram Celulas primarias (energia eletroquimica) larpcal Piles électriques ram Electric batteries Accidents Electric batteries Safety measures Unfallverhütung (DE-588)4061706-3 gnd Zuverlässigkeit (DE-588)4059245-5 gnd Batterie (DE-588)4004687-4 gnd
topic_facet	Accumulateurs - Accidents Accumulateurs - Mesures de sécurité Celulas primarias (energia eletroquimica) Piles électriques Electric batteries Accidents Electric batteries Safety measures Unfallverhütung Zuverlässigkeit Batterie
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007078611&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT levysamuelc batteryhazardsandaccidentprevention AT broper batteryhazardsandaccidentprevention

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