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Bibliographic Details
Main Author:	Hirsch, Andreas 1960- (Author)
Format:	Book
Language:	German
Published:	Stuttgart u.a. Thieme 1994
Series:	Thieme organic chemistry monograph series
Subjects:	Fullerenes Fullerene
Links:	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006396586&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Physical Description:	203 S. graph. Darst.
ISBN:	3131368012

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MARC


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Record in the Search Index

DE-BY-TUM_call_number	0302 CHE 667f 1994 A 6073
DE-BY-TUM_katkey	628006
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adam_text	THE CHEMISTRY OF THE FUUERENES ANDREAS HIRSCH UNIVERSITY OF TUEBINGEN GEORG THIEME VERLAG STUTTGART * NEW YORK 1994 CONTENTS CHAPTER 1 THE PARENT FULLERENES 1 1.1 THE FULLERENES: MOLECULAR AETIOTROPES OF CARBON 2 1.2 THE DISCOVERY OF THE FULLERENES 5 1.3 FULLERENE PRODUCTION 7 1.3.1 FULLERENE GENERATION BY VAPORIZATION OF GRAPHITE 7 1.3.1.1 RESITIVE HEATING OF GRAPHITE ...7 13.1.2 ARE HEATING OF GRAPHITE 10 13.1.3 SOLAR GENERATORS 10 13.1.4 INDUCTIVE HEATING OF GRAPHITE 11 1.3.2 FULLERENE SYNTHESIS IN COMBUSTION 11 1.3.3 FORMATION OF FULLERENES BY PYROLYSIS OF NAPHTHALENE 12 1.3.4 ENDOHEDRALS 12 1.3.5 THE FORMATION PROCESS 15 1.4 SEPARATION AND PURIFICATION 21 1.5 PROPERTIES 25 1.5.1 STRUCTURES 25 1.5.2 PHYSICAL AND SPECTROSCOPIC PROPERTIES 29 REFERENCES 33 CHAPTER 2 REDUCTION 37 2.1 INTRODUCTION 38 2.2 FUELLENDE ANIONS 38 2.3 REDUCTIVE ELECTROSYNTHESIS 42 2.3.1 ELECTROCRYSTALLIZATION 42 2.3.2 ELECTROPHILIC ADDITIONS TO FUELLENDE ANIONS 43 2.4 REDUCTION WITH METALS 44 2.4.1 ALKALI METAL FUELLENDES 44 2.4.1.1 GENERATION IN SOLUTION AND QUENCHING EXPERIMENTS 44 2.4.1.2 SYNTHESIS AND PROPERTIES OF ALKALI METAL FUELLENDE SOLIDS 45 2.4.2 ALKALINE EARTH METAL FULLERIDES 50 2.4.3 REDUCTION WITH MERCURY 51 2.5 REDUCTION WITH ORGANIC DONOR MOLECULES 51 REFERENCES 53 CHAPTER 3 NUCLEOPHILIC ADDITIONS 56 3.1 INTRODUCTION 57 3.2 ADDITION OF CARBON NUCLEOPHILES 57 3.2.1 HYDROALKYLATION AND HYDROARYLATION OF CG 0 AND C70 57 3.2.2 LANGMUIR - BLODGETT FILMS OF C 60 HF-BU 63 X CONTENTS 3.2.3 ADDITION OF MACROMOLECULAR CARBANIONS - FUUERENE POLYMERS 64 3.2.4 CYCLOPROPANATION OF C^N AND C70 66 3.3 ADDITION OF AMINES 73 3.4 ADDITION OF HYDROXIDE 76 REFERENCES 77 CHAPTER4 CYCLOADDITIONS 79 4.1 INTRODUCTION 80 4.2 [4+2] CYCLOADDITIONS 80 4.3 [3+2] CYCLOADDITIONS 87 4.3.1 ADDITION OF DIAZOMETHANES, DIAZOACETATES AND DIAZOAMIDES 87 4.3.2 ADDITION OF AZIDES 99 4.3.3 ADDITION OFTRIMETHYLENEMETHANES 99 4.3.4 ADDITION OF AZOMETHINE YLIDES 103 4.3.5 ADDITION OFNITRILE OXIDES 105 4.3.6 ADDITION OF SULFINIMIDES 106 4.3.7 ADDITION OF DISILIRANES 106 4.4 [2+2] CYCLOADDITIONS 10 7 4.4.1 ADDITION OF BENZYNE 107 4.4.2 ADDITION OF ENONES 107 4.4.3 ADDITION OF QUADRICYCLANE 108 4.4.4 ADDITION OF ELECTRON RIEH ALKYNES ? 109 4.4.5 PHOTOPOLYMERIZATION OF COEO 110 4.5 [2+1] CYCLOADDITIONS 111 4.5.1 ADDITION OF CARBENES 111 4.5.2 ADDITION OF SILYLENES 111 REFERENCES 112 CHAPTERS HYDROGENATION 115 5.1 INTRODUCTION 116 5.2 OLIGOHYDROFULLERENES C5OH 2N AND C7OH 2N (N = 1 - 6) 116 5.2.1 HYDROGENATION VIA HYDROBORATION, HYDROZIRCONATION AND ZINC/ACID REDUCTION 117 5.2.2 THEORETICAL INVESTIGATIONS 119 5.3 POLYHYDROFULLERENES C^TYN AND C 70 H 2N (N = 7 - 70) 125 5.3.1 BIRCH - HUECKEL REDUCTION 125 5.3.2 TRANSFER HYDROGENATION OF CGQ AND C70 127 5.3.3 CATALYTIC HYDROGENATION 129 5.3.4 THEORETICAL INVESTIGATIONS 129 REFERENCES 134 CHAPTER 6 RADICAL ADDITIONS 136 6.1 INTRODUCTION 137 6.2 ESR INVESTIGATIONS OF RADICAL ADDITIONS 137 CONTENTS XI 6.2.1 ADDITION OF SINGLE RADICALS 137 6.2.2 MULTIPLE RADICAL ADDITIONS 143 6.3 METALATION OF C^O WITH PENTACARBONYLRHENIUM RADICALS 146 6.4 HYDROSTANNYLATION OF CGG 147 6.5 ADDITION OF BIS(TRIFLUOROMETHYL)NITROXIDE 147 6.6 RADICAL COPOLYMERIZATION OF CGO AND PARACYCLOPHANE 147 REFERENCES 148 CHAPTER 7 TRANSITION METAL COMPLEX FORMATION 150 7.1 INTRODUCTION 151 7.2 (TI 2 -COEO) TRANSITION METAL COMPLEXES 151 7.3 HYDROMETALATION REACTIONS 159 7.4 ORGANOPALLADIUM POLYMERS OF CGO 160 REFERENCES 160 CHAPTER 8 OXIDATION AND REACTIONS WITH ELECTROPHILES 162 8.1 INTRODUCTION 163 8.2 ELECTROCHEMICAL OXIDATION OF CGO AND C70 163 8.3 OXYGENATION 163 8.4 OSMYLATION 166 8.5 HALOGENATION 172 8.5.1 FLUORINATION 172 8.5.2 CHLORINATION 175 8.5.3 BROMINATION 177 8.5.4 REACTION WITH IODINE 180 8.6 REACTIONS WITH STRONG OXIDIZING REAGENTS AND ACIDS 180 8.7 REACTION WITH LEWIS ACIDS AND FULLERENATION OF AROMATICS 182 REFERENCES 183 CHAPTER 9 PRINCIPLES AND PERSPECTIVES OF FULLERENE CHEMISTRY 185 9.1 INTRODUCTION 186 9.2 REACTIVITY 186 9.3 REGIOCHEMISTRY OF ADDITION REACTIONS 190 9.4 THE FUTUREOF FULLERENE CHEMISTRY 195 9.4.1 MULTIPLE ADDITION PRODUCTS WITH A DEFINED THREE-DIMENSIONAL STRUCTURE 195 9.4.2 HETEROFULLERENES 196 9.4.3 RING-OPENING AND DEGRADATION REACTIONS - SYNTHESIS OF ENDOHEDRALS 196 9.4.4 CHEMISTRY WITH HIGHER FULLERENES 197 9.5 PERSPECTIVES FOR PRACTICAL APPLICATIONS 197 9.6 CONCLUDING REMARKS 199 REFERENCES 200 INDEX 202
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author	Hirsch, Andreas 1960-
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indexdate	2024-12-20T09:40:18Z
institution	BVB
isbn	3131368012
language	German
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physical	203 S. graph. Darst.
publishDate	1994
publishDateSearch	1994
publishDateSort	1994
publisher	Thieme
record_format	marc
series2	Thieme organic chemistry monograph series
spellingShingle	Hirsch, Andreas 1960- The chemistry of the fullerenes Fullerenes Fullerene (DE-588)4305238-1 gnd
subject_GND	(DE-588)4305238-1
title	The chemistry of the fullerenes
title_auth	The chemistry of the fullerenes
title_exact_search	The chemistry of the fullerenes
title_full	The chemistry of the fullerenes Andreas Hirsch
title_fullStr	The chemistry of the fullerenes Andreas Hirsch
title_full_unstemmed	The chemistry of the fullerenes Andreas Hirsch
title_short	The chemistry of the fullerenes
title_sort	the chemistry of the fullerenes
topic	Fullerenes Fullerene (DE-588)4305238-1 gnd
topic_facet	Fullerenes Fullerene
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006396586&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT hirschandreas thechemistryofthefullerenes

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Call Number:	0302 CHE 667f 1994 A 6073 Floor plan
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