Ion association:
Gespeichert in:
Beteilige Person: | |
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Format: | Buch |
Sprache: | Englisch |
Veröffentlicht: |
London
Butterworth
1962
|
Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006124316&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
Umfang: | VIII, 190 S. graph. Darst. |
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Datensatz im Suchindex
DE-BY-TUM_call_number | 0024 62 A 1835 |
---|---|
DE-BY-TUM_katkey | 830949 |
DE-BY-TUM_location | Mag |
DE-BY-TUM_media_number | 040002538841 |
_version_ | 1821931108750589952 |
adam_text | I O N
ASSOCIATION
CW DAVIES
D Sc ,FRIC
Associate Director of Research,
Battersea College of Technology, and
Emeritus Professor at the University of Wales
LONDON
BUTTERWORTHS
CONTENTS
PREFACE v
1INTRODUCTION1
METHODS OF STUDYING ION-PAIRING
2 CONDUCTIVITY METHODS 9
Calculation of K from the limiting equation 12
Unsymmetrical electrolytes • 16
Simultaneous determination of A , and K 1 8
Theoretical conductance equations at higher concentrations 20
The theory of Onsager and Fuoss 22
Qualitative detection of ion-pairing 24
Empirical extensions of the conductance equation 24
The conductivity of mixtures 27
Conductivities at high field strengths 31
3 ACTIVITY MEASUREMENTS 34
Stoichiometric and ionic activity coefficients 34
Conversion of concentration scales 37
The determination of pK values from activity measurements 37
The determination of pK % from solubility measurements 48
4 SPECTROPHOTOMETRY METHODS 55
Indirectdeterminationsusingindicators60
5 ELECTROMETRIC MEASUREMENTS 62
6 OTHER METHODS 66
Polarography • 66
Ion exchange 66
Distribution between two solvents 68
Raman spectra 69
Reaction kinetics 69
Other methods 70
RESULTS
7 REVIEW OF RESULTS IN WATER 77
Hydroxides84
vii
CONTENTS
8 RESULTS IN MIXED SOLVENTS
Methanol-water
Ethanol—water
Ethylene glycol-water
Acetone-water
Dioxan-water
9 NON-AQUEOUS SOLUTIONS
CONSEQUENCES
10 THE DISSOCIATION MINIMUM
The condition for a minimum
Conductivity evidence
Non-aqueous solutions
11 COLLOIDAL SOLUTIONS
Colloidal electrolytes
The dissociation minimum in micelle formation
Polyelectrolytes
12 THERMODYNAMIC PROPERTIES OF THE ION-PAIR
Heats of dissociation of ion-pairs
Entropy changes in the dissociation of ion-p;iirs
13 KINETICS AND MECHANISMS OF REACTIONS INVOLVING IONS
AND ION-PAIRS -
The primary salt effect
Ion assoSiation and salt effects
Ion association and organic reaction mechanisms
Ion association in inorganic reactions
Determination of dissociation constants
14 THE SOLVATION OF IONS AND ION-PAIRS
Electrolytictransferofwater
Ionic mobilities
Equilibrium properties
The structure of water
15 THEORIES OF ION ASSOCIATION
Comparison of Bjerrum s theory with experiment
APPENDIX
INDEX
VLLL
|
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author | Davies, Cecil W. 1895- |
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building | Verbundindex |
bvnumber | BV009213649 |
classification_rvk | VE 6350 |
ctrlnum | (OCoLC)600534455 (DE-599)BVBBV009213649 |
discipline | Chemie / Pharmazie |
format | Book |
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id | DE-604.BV009213649 |
illustrated | Illustrated |
indexdate | 2024-12-20T09:34:22Z |
institution | BVB |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006124316 |
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physical | VIII, 190 S. graph. Darst. |
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publishDate | 1962 |
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publisher | Butterworth |
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spellingShingle | Davies, Cecil W. 1895- Ion association |
title | Ion association |
title_auth | Ion association |
title_exact_search | Ion association |
title_full | Ion association C. W. Davies |
title_fullStr | Ion association C. W. Davies |
title_full_unstemmed | Ion association C. W. Davies |
title_short | Ion association |
title_sort | ion association |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006124316&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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Bibliotheksmagazin
Signatur: |
0024 62 A 1835
Lageplan |
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Exemplar 1 | Ausleihbar Am Standort |