A guide to the study of electrode kinetics:
Gespeichert in:
| Beteiligte Personen: | , |
|---|---|
| Format: | Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
London
Acad. Press
1972
|
| Schlagwörter: | |
| Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001498331&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| Umfang: | XIII, 174 S. |
| ISBN: | 0126877505 |
Internformat
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Datensatz im Suchindex
| _version_ | 1819270194907840512 |
|---|---|
| adam_text | A Guide to the Study of
ELECTRODE KINETICS
H R THIRSK
J A HARRISON
School of Chemistry
The University
Newcastle-upon-Tyne
England
ACADEMIC PRESS • London and New York
Contents
Preface v
General References ix
Symbols xi
Chapter 1 Stationary Methods 1
Introduction I
Factors which determine current-voltage curves 1
Measurement at a single electrode 1
Current-voltage behaviour 1
Double layer 2
Definition of Interfacial Rates of Reaction 3
Stationary methods 5
Simple Electron Transfer * 6
General treatment of equation (1 14) 10
Equation of equation (1 14) 14
Consecutive Electron Transfer 14
Chemical Reactions Preceding Electron Transfer 16
Chemical Reactions Following Electron Transfer 16
Surface Processes 18
lixperimental Procedure 20
Review of experimental method 24
References 25
Chapter 2 Non-Stationary Methods 21
Introduction to the Theory and Reaction Schemes 28
Techniques and Reaction Schemes 37
Potential step method 37
Current step method; galvanostatic method or chronopotentiometry 50
Polarography 55
Single linear potential sweep 60
Bridge methods; measurement of impedance 73
Faradaic rectification 83
A C polarography 83
The rotating disc 83
The rotating ring-disc 95
The thin layer cell 100
Controlled potential coulometry 102
Synthesis at constant potential 107
) Experimental results 110
References 110
v i i
viii CONTENTS
Chapter 3 Electrocrystallisation 115
Introduction 115
Nucleation and Growth Model (without Edge Effects) 115
Potential step method 115
Current step method 126
A C method 126
Nucleation and Growth Model (with Edge Effects) 127
Potential step method 127
Adatom model 132
Formation of thick films 133
Experimental Results 134
References 134
Chapter 4 Ancillary Techniques 136
Introduction 1 3 6
Cells 136
Optical Procedures and the Examination of Surfaces During Kinetic Studies 137
X-ray Methods for in situ Studies 146
Surface Examination Prior and Subsequent to Kinetic Experiments 147
Electron diffraction and conventional electron microscopy 148
Surface replicating methods 151
Scanning electron microscopy 154
Electron probe analysis and the analytical electron microscope 159
References 160
Author Index 163
Subject Index 169
|
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| discipline | Chemie / Pharmazie |
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| id | DE-604.BV002280182 |
| illustrated | Not Illustrated |
| indexdate | 2024-12-20T07:48:48Z |
| institution | BVB |
| isbn | 0126877505 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001498331 |
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| physical | XIII, 174 S. |
| psigel | TUB-nveb |
| publishDate | 1972 |
| publishDateSearch | 1972 |
| publishDateSort | 1972 |
| publisher | Acad. Press |
| record_format | marc |
| spellingShingle | Thirsk, Harold R. Harrison, John A. A guide to the study of electrode kinetics Cinétique chimique Eletroquimica larpcal Électrochimie Chemical kinetics Electrochemistry Elektrodenreaktion (DE-588)4151784-2 gnd Elektrochemie (DE-588)4014241-3 gnd |
| subject_GND | (DE-588)4151784-2 (DE-588)4014241-3 |
| title | A guide to the study of electrode kinetics |
| title_auth | A guide to the study of electrode kinetics |
| title_exact_search | A guide to the study of electrode kinetics |
| title_full | A guide to the study of electrode kinetics Harold R. Thirsk ; John A. Harrison* |
| title_fullStr | A guide to the study of electrode kinetics Harold R. Thirsk ; John A. Harrison* |
| title_full_unstemmed | A guide to the study of electrode kinetics Harold R. Thirsk ; John A. Harrison* |
| title_short | A guide to the study of electrode kinetics |
| title_sort | a guide to the study of electrode kinetics |
| topic | Cinétique chimique Eletroquimica larpcal Électrochimie Chemical kinetics Electrochemistry Elektrodenreaktion (DE-588)4151784-2 gnd Elektrochemie (DE-588)4014241-3 gnd |
| topic_facet | Cinétique chimique Eletroquimica Électrochimie Chemical kinetics Electrochemistry Elektrodenreaktion Elektrochemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001498331&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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