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Bibliographic Details
Previous Title:	Hawkes, Herbert E. Geochemistry in mineral exploration
Main Authors:	Rose, Arthur W. (Author), Hawkes, Herbert Edwin 1872- (Author), Webb, John S. (Author)
Format:	Book
Language:	English
Published:	London [u.a.] Acad. Press 1979
Edition:	2. ed.
Subjects:	Prospection géochimique Geochemical prospecting Geochemie Prospektion Bohrung
Links:	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001434184&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
Physical Description:	XVII, 657 S. graph. Darst., Kt.
ISBN:	0125962509 0125962525

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adam_text	Contents PREFACE Chapter 1 INTRODUCTION I. Geochemistry in Mineral Exploration ..... 2 II. Scales and Sampling Media in Geochemical Exploration . . 2 A. Reconnaissance surveys ....... 2 B. Detailed surveys........ 4 III. History........... 5 IV. Present Status......... 6 V. Literature.......... 9 VI. Related Fields of Applied Geochemistry . . . . . 11 Chapter 2 BASIC PRINCIPLES I. The Geochemical Environment ...... 13 II. Geochemical Dispersion ....... 16 III. Geochemical Mobility........ 18 IV. Geochemical Reactions ........ 18 A. Dispersion of elements under deep-seated conditions . . 20 B. Mobility under surficial conditions ..... 23 V. Association of Elements........ 25 VI. Patterns of Geochemical Distribution ..... 28 A. Normal background values ...... 30 B. Statistical distribution of background values ... 32 C. The geochemical anomaly...... 34 VII. Principles of Interpretation ....... 35 vii viii Contents Chapter 3 PRINCIPLES OF TRACE ANALYSIS I. Mode of Occurrence of Trace Elements in Solids ... 44 A. Stability of important minerals..... 46 II. Preparation of Samples ........ 46 III. Decomposition of Samples ....... 49 A. Volatilization ........ 51 B. Fusion.......... 51 C. Vigorous acid attack....... 51 D. Attack by weak aqueous extractants .... 52 E. Oxidation - reduction agents...... 53 IV. Separation.......... 53 A. Separation in liquid phase...... 53 B. Separation in solid phase....... 54 V. Estimation.......... 54 A: Colorimetry ......... 54 B. Emission spectrometry and spectrography .... 56 C. Atomic absorption ........ 57 D. X-ray fluorescence spectrometry ..... 58 E. Fluorimetry ......... 58 F. Radiometric methods ....... 58 G. Electroanalytical methods ...... 59 H. Chromatographic methods ...... 59 I. Mass spectrometry ........ 60 J. Other methods........ 60 K. Units for reporting chemical analyses .... 61 VI. Reliability of Geochemical Analyses ..... 61 A. Precision ......... 62 B. Accuracy ......... 65 C. Routine checks of precision and accuracy .... 66 VII. Analytical Procedures ........ 66 VHI. Selected References on Techniques of Chemical Analysis . . 70 Chapter 4 PATTERNS OF DEEP-SEATED ORIGIN—ORE TYPES, GEOCHEMICAL PROVINCES, AND PRODUCTIVE PLUTONS I. Classification of Mineral Deposits ...... 72 A. Ore-forming processes ....... 72 B. Geochemical recognition of ore types .... 72 II. Productive Environments of Deep-seated Origin ... 77 HI. Geochemical and Metallogenic Provinces ..... 78 Contents ix IV. Processes Forming Productive Plutons ..... 84 V. Ores Related to Productive Plutons...... 87 A. Pegmatites......... 87 B. Magmatic copper-nickel sulfides..... 88 C. Ores associated with granitic rocks ..... 89 D. Hydrothermal tin deposits ...... 90 E. Molybdenum, tungsten, and gold deposits ... 93 F. Base-metal sulfide deposits ...... 93 G. Porphyry-copper deposits ...... 94 H. Volcanogenic massive sulfides ...... 95 Chapter 5 EPIGENETIC ANOMALIES IN BEDROCK I. Formation of Diffusion Aureoles ...... 98 II. Formation of Leakage Anomalies...... 101 III. Zoning in Epigenetic Orebodies and Aureoles . . . . 104 IV. Examples of Diffusion Aureoles . . . . . . 107 V. Examples of Leakage Anomalies and Zoning .... 109 A. Polymetallic vein and replacement deposits . . . 109 B. Porphyry-copper and molybdenum deposits . . . 114 C. Epithermal deposits of Au-Ag-As-Sb-Hg . . . 118 D. Volcanogenic massive-sulfide deposits . . . . 119 E. Mississippi-valley type lead-zinc deposits . . . . 120 F. Leakage anomalies in specific types of material . . 121 VI. Geochemical Rock Surveys ....... 121 A. Orientation surveys . . . . . . . 122 B. Collection and processing of samples .... 124 C. Preparation of maps and handling of data . . . 125 D. Interpretation of data . . . . . . . 126 Chapter 6 WEATHERING I. Nature of Weathering........ 128 n. Weathering Processes........ 129 A. Physical weathering . . . . . . . 130 B. Chemical weathering . . . . . . . 131 C. Biologic agents in weathering . . . . . . 133 III. Factors Affecting Weathering Processes..... 134 A. Resistance of minerals in weathering . . . . 134 B. Permeability......... 136 Contents C. Climate ..... D. Relief and drainage .... IV. Products of Weathering .... A. Residual primary minerals from the parent rock B. Secondary minerals .... C. Soluble products..... D. Residual structures and textures V. Selected References on Weathering . Chapter 7 SOIL FORMATION I. Soil Profile Development...... n. Factors Affecting Soil Formation..... A. Parent material ....... B. Climate........ C. Biologic activity ....... D. Relief......... E. Time......... HI. Classification of Soils ....... A. The Soil Taxonomy system ..... B. Old classification of soils ..... IV. Soils of Humid Regions....... A. Podzolic and related soils of temperate forested regions B. Tropical soils....... C. Intrazonal hydromorphic soils..... V. Soils of Subhumid and Arid Regions .... A. Grassland soils ....... B. Desert soils........ C. Soils of arctic areas...... D. Intrazonal saline and alkali soils .... VI. Mountain Soils........ VII. Selected References on Soil Formation .... Chapter 8 CHEMICAL EQUILIBRIA IN THE SURFICIAL ENVIRONMENT I. Composition of Natural Waters ...... II. Eh-pH Relationships........ A. Hydrogen-ion concentration ...... B. Oxidation-reduction potential ..... C. Eh-pH diagrams ........ Contents xi D. Forms of sulfur and carbon in solution . . . . 188 III. Formation of Complexes....... 191 IV. Solubility of Minerals........ 192 V. Adsorption and Ion Exchange on Colloidal Particles . . . 195 A. Ion exchange in clay minerals ...... 196 B. Adsorption on surfaces....... 197 VI. Organic Matter......... 206 A. Simple organic compounds...... 206 B. Humic substances ........ 208 VII. Electrochemical Dispersion . . . . . . . 212 VIII. Selected References on Chemical Equilibria in the Surficial Environ- ment ........... 214 Chapter 9 MECHANICAL AND BIOLOGICAL DISPERSION IN THE SURFICIAL ENVIRONMENT I. Mechanical Factors ........ 216 A. Simple gravity movement ...... 216 B. Dispersion in ground water...... 220 C. Mechanics of dispersion in surface water .... 224 D. Dispersion by glaciers . . . . . . .231 E. Dispersion by wind action ...... 235 F. Dispersion by animal activity...... 235 G. Dispersion in permafrost areas..... 236 II. Biological Factors ......... 236 A. The effect of vegetation ....... 236 B. The effect of microorganisms ...... 238 III. The Influence of Environment on Dispersion .... 238 A. Climate......... 238 B. Relief.......... 239 C. Rock types......... 239 D. Life processes ........ 240 E. Time.......... 240 IV. Selected References on Dispersion in the Surficial Environment . 241 Chapter 10 SURFICIAL DISPERSION PATTERNS I. Classification of Surficial Dispersion Patterns .... 242 II. Syngenetic Patterns........244 A. Clastic patterns........244 ii Contents B. Hydromorphic patterns....... 245 C Biogenic patterns ........ 245 HI. Epigenetic Patterns........ 245 A. Hydromorphic patterns....... 245 B. Biogenic patterns . . . . ... . . 246 IV. Partition of Dispersed Constituents Between Liquid and Solid Media........... 246 A. Liquid media ........ 246 B. Solid media......... 248 V. Extractability of Metal from Clastic Samples .... 249 VI. Contrast.......... 250 VII. Form of Surficial Patterns....... 252 A. Clastic patterns........ 252 B. Hydromorphic patterns....... 254 C. Biogenic patterns........ 256 Anomalies Not Related to Mineral Deposits .... 256 A. High-background source rocks ..... 257 B. Contamination........ 258 C. Sampling errors........ 259 D. Analytical errors ........ 260 IX. Suppression of Significant Anomalies ..... 260 Chapter 11 ANOMALIES IN RESIDUAL OVERBURDEN I. Anomalies in Gossans and Leached Outcrops of Ore . . 261 II. Syngenetic Anomalies in Residual Soil ..... 266 A. Mode of occurrence ....... 266 B. Form and magnitude of the anomaly .... 269 C. Homogeneity ........ 278 D. Variations with depth and soil type..... 281 III. Hydromorphic Anomalies in Residual Soil .... 285 IV. Anomalies Not Related to Mineral Deposits .... 285 Chapter 12 ANOMALIES IN TRANSPORTED OVERBURDEN I. Common Features of Anomalies in Transported Overburden . 288 A. Syngenetic anomalies ....... 289 B. Epigenetic anomalies ....... 289 C. Anomalies not related to mineral deposits . . . 290 n. Glacial Overburden ........ 290 A. Syngenetic (clastic) anomalies...... 291 Contents xiii B. Hydromorphic anomalies ...... 300 C. Biogenic anomalies ....... 304 D. Superjacent anomalies of complex origin . . . 305 E. Schematic models of dispersion in glaciated areas . . 306 III. Organic Deposits ......... 306 IV. Colluvium and Alluvium . . . . . . . 311 A. Syngenetic anomalies . . . . . . . 313 B. Epigenetic anomalies ....... 314 V. Other Types of Transported Overburden .... 317 Chapter 13 GEOCHEMICAL SOIL SURVEYS I. Orientation Surveys ........ 320 A. Residual soil ........ 321 B. Transported overburden ...... 325 C. Contamination ........ 325 D. Choice of procedures ....... 328 II. Field Operations......... 329 A. Sampling pattern ........ 329 B. Sampling procedure....... 333 C. Locating and identifying samples..... 336 D. Sample preparation and analysis ..... 337 E. Preparation of geochemical maps ..... 339 III. Interpretation of Data ........ 341 A. Estimation of background and threshold values . . . 341 B. Recognition of non-significant anomalies .... 342 C. Distinction between lateral and superjacent anomalies . . 344 D. Appraisal of anomalies ....... 345 IV. General Procedure for Follow-up...... 346 Chapter 14 ANOMALIES IN NATURAL WATERS I. Mode of Occurrence of Elements ...... 348 II. Factors Affecting Composition of Natural Waters . . . 351 A. Composition of rain water . . . . . . 351 B. Reaction with soil and rock ...... 352 C. Regional and climatic factors ...... 354 D. Age of ground water ....... 355 E. Oxidation-reduction ....... 355 F. Adsorption ......... 355 xiv Contents G. Mixing of waters........ 358 H. Background content of natural waters .... 358 III. Persistence of Anomalies ....... 358 A. Contrast at source ........ 358 B. Decay by dilution........ 361 C. Decay at precipitation barriers ..... 363 D. Re-solution at precipitation barriers ..... 368 IV. Time Variations......... 368 V. Ground-water Anomalies....... 373 VI. Stream-water Anomalies........ 377 VII. Lake-water Anomalies........ 380 VIII. Anomalies Not Related to Mineral Deposits .... 381 Chapter 15 ANOMALIES IN DRAINAGE SEDIMENTS I. Spring and Seepage Areas...... 383 II. Active Stream Sediments ...... 392 A. Mode of occurrence ...... 392 B. Contrast........ 394 C. Decay patterns ....... 399 D. Anomaly enhancement ...... 406 E. Effect of precipitation barriers .... 411 F. Lateral homogeneity ...... 413 G. Vertical homogeneity ...... 415 H. Time variations ....... 415 III. Flood-plain Sediments....... 416 IV. Lake Sediments........ 419 A. Mode of occurrence ...... 420 B. Homogeneity and contrast..... 421 C. Decay patterns ....... 424 V. Drainage Anomalies Not Related to Mineral Deposits 426 VI. Marine Sediments........ 427 Chapter 16 GEOCHEMICAL DRAINAGE SURVEYS Orientation Surveys........ 431 A. Water.......... 432 B. Drainage sediment........ 433 C. Contamination ........ 434 Contents xv II. Choice of Material to be Sampled...... 435 A. Water.......... 435 B. Seepage soils......... 435 C. Stream sediments........ 437 D. Heavy minerals........ 438 E. Organic sediment........ 439 F. Lake sediment and water...... 439 III. Sample Layout ......... 440 A. Ground-water patterns ....... 441 B. Drainage channel patterns ...... 442 IV. Collection and Processing of Samples..... 444 A. Water.......... 445 B. Stream and seepage sediment...... 447 C. Lake sediment........ 449 D. Heavy minerals........ 450 V. Preparation of Maps........ 450 VI. Interpretation of Data........ 453 VII. Follow-up Techniques........ 454 Chapter 17 VEGETATION I Uptake of Mineral Matter by Plants..... 457 A. Plant nutrition........ 457 B. Availability of elements in soil ..... 458 C. Reactions in the root tips of plants ..... 458 D. Movement and storage within plants .... 463 II. Biogeochemical Anomalies ....... 464 A. Variation between plant species..... 464 B. Variation between plant parts...... 464 C. Depth of root penetration...... 466 D. Variation with other factors...... 467 E. Contrast......... 468 F. Homogeneity ........ 470 G. Form of anomalies ....... 470 III. Biogeochemical Surveying Techniques . . . . .471 A. Orientation survey . ¦ . . . . . 473 B. Choice of sampling medium ...... 473 C. Collecting and processing of samples .... 474 D. Choice of analytical method ...... 474 E. Interpretation of data ....... 475 F. Advantages and disadvantages of biogeochemical surveys . 475 IV. Geobotanical Indicators....... 476 xvi Contents A. Indicators of ground water...... 478 B. Indicators of saline deposits...... 479 C. Indicators of hydrocarbons...... 479 D. Indicators of rock types....... 481 E. Indicators of ore........ 481 V. Geobotanical Surveying Techniques ...... 484 VI. Remote Sensing of Geobotanical Anomalies .... 485 Chapter 18 VOLATILES AND AIRBORNE PARTICULATES I. Properties of Gases and Aerosols ...... 490 II. Units of Measurement . . . . . . . .491 III. Source of Naturally Occurring Gases ..... 492 A. Atmospheric gases....... 492 B. Deep-seated gases ........ 494 C. Radiogenic gases........ 495 D. Biogenic gases........ 495 E. Gases generated in sulfide deposits..... 495 F. Atmospheric particulates...... 497 IV. Reactivity of Gases........ 498 V. Movement of Gases ........ 500 A. Diffusion......... 500 B. Water transport........ 502 C. Transfer between water and vapor phases .... 503 D. Vapor transport........ 504 E. Relative effects of infiltration versus diffusion . . . 505 VI. Geochemical Behavior of Selected Gases .... 506 VII. Applications of Vapor Geochemistry..... 511 A. Exploration for sulfide deposits . . . . . 511 B. Exploration for uranium . . . . . . 512 C. Exploration for petroleum ...... 513 D. Location of buried faults...... 514 E. Forecasting of earthquakes...... 514 F. Forecasting of volcanic eruptions ..... 514 G. Location of geothermal areas ...... 514 VIII. Vapor Survey Techniques....... 514 A. Soil air.......... 516 B. Water.......... 516 C. Gas traps......... 517 D. Atmospheric air ........ 517 Contents xvii Chapter 19 COMPUTERIZED DATA-HANDLING AND STATISTICAL INTERPRETATION I. Data-handling by Computer ....... 520 A. Recording of data ........ 520 B. Production of tables, histograms, and summaries . . 521 C. Computer-generated maps . . . . . . 521 D. Contouring of concentrations ...... 523 E. Moving averages and trend surfaces ..... 523 II. Multivariate Statistical Methods...... 525 A. Regression analysis ....... 525 B. Discriminant analysis ....... 527 C. Factor analysis . . . . . . . .531 D. Cluster analysis ........ 533 Chapter 20 GEOCHEMICAL METHODS IN MINERAL EXPLORATION I. Optimization of Exploration ....... 535 II. Planning of Exploration ........ 536 A. Selection of professional leadership ..... 536 B. Selection of areas ........ 538 C. The exploration sequence ...... 538 III. Choice of Exploration Methods...... 540 A. Target size......... 543 B. Property control........ 544 C. Reliability of method....... 544 D. Cost.......... 544 E. Value of expected ore....... 545 F. Comparison of programs....... 545 G. The role of geochemistry in an exploration system . . 545 IV. Organization and Operations ....... 546 A. Field operations ........ 546 B. Laboratory......... 547 C. Supervision ......... 548 APPENDIX. Geochemical Characteristics of the Elements ... 549 REFERENCES.......... 583 SUBJECT INDEX.......... 637
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record_format	marc
spellingShingle	Rose, Arthur W. Hawkes, Herbert Edwin 1872- Webb, John S. Geochemistry in mineral exploration Prospection géochimique Prospection géochimique ram Geochemical prospecting Geochemie (DE-588)4020198-3 gnd Prospektion (DE-588)4047505-0 gnd Bohrung (DE-588)4146246-4 gnd
subject_GND	(DE-588)4020198-3 (DE-588)4047505-0 (DE-588)4146246-4
title	Geochemistry in mineral exploration
title_auth	Geochemistry in mineral exploration
title_exact_search	Geochemistry in mineral exploration
title_full	Geochemistry in mineral exploration Arthur W. Rose ; Herbert E. Hawkes ; John S. Webb
title_fullStr	Geochemistry in mineral exploration Arthur W. Rose ; Herbert E. Hawkes ; John S. Webb
title_full_unstemmed	Geochemistry in mineral exploration Arthur W. Rose ; Herbert E. Hawkes ; John S. Webb
title_old	Hawkes, Herbert E. Geochemistry in mineral exploration
title_short	Geochemistry in mineral exploration
title_sort	geochemistry in mineral exploration
topic	Prospection géochimique Prospection géochimique ram Geochemical prospecting Geochemie (DE-588)4020198-3 gnd Prospektion (DE-588)4047505-0 gnd Bohrung (DE-588)4146246-4 gnd
topic_facet	Prospection géochimique Geochemical prospecting Geochemie Prospektion Bohrung
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001434184&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT rosearthurw geochemistryinmineralexploration AT hawkesherbertedwin geochemistryinmineralexploration AT webbjohns geochemistryinmineralexploration

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Call Number:	0001 78.2001 A 3125
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