Chemiluminescence in organic chemistry:
Gespeichert in:
| Beteiligte Personen: | , |
|---|---|
| Format: | Buch |
| Sprache: | Englisch |
| Veröffentlicht: |
Berlin [u.a.]
Springer
1987
|
| Schriftenreihe: | Reactivity and structure
23 |
| Schlagwörter: | |
| Links: | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000406631&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| Umfang: | X, 217 S. graph. Darst. |
| ISBN: | 354017155X |
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| 100 | 1 | |a Gundermann, Karl-Dietrich |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Chemiluminescence in organic chemistry |c Karl-Dietrich Gundermann ; Frank McCapra |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 1987 | |
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Datensatz im Suchindex
| DE-BY-TUM_call_number | 0302 CHE 626f 1987 A 5832 |
|---|---|
| DE-BY-TUM_katkey | 1020444 |
| DE-BY-TUM_location | 03 |
| DE-BY-TUM_media_number | 040030045515 |
| _version_ | 1821931511259070464 |
| adam_text | KARL-DIETRICH GUNDERMANN * FRANK MCCAPRA CHEMUEUMINESCENCE IN ORGANIC
CHEMISTRY WITH 30 FIGURES SPRINGER-VERLAG BERLIN HEIDELBERG NEW YORK
LONDON PARIS TOKYO TABLE OF CONTENTS /. INTRODUCTION 1 A. PHYSIOCHEMICAL
BACKGROUND 5 //. GENERAL CONCEPTS IN CHEMILUMINESCENCE 7 II. 1
CHEMILUMINESCENCE EFFICIENCY 7 II.1.1 ENERGETICSOFTHEREACTIONS 8 II. 1.2
FORMATION OF THE EXCITED STATE 9 II. 1.2.1 THE REACTION CO-ORDINATE 9
11. 1.2.2 MOLECULAR GEOMETRY 9 11. 1.2.3 SPIN RESTRICTIONS 9 II. 1.2.4
SYMMETRY RESTRICTIONS 10 II. 1.2.5 POTENTIAL ENERGY SURFACES 10 II.2
ELECTRON TRANSFER REACTIONS 11 II. 3 SINGLET OXYGEN AS A CAUSE OF CHEMI-
AND BIOLUMINESCENCE; THE ROLEOFTRIPLET OXYGEN 12 II.4
REFERENCES(FORPREFACE,CHAPS.IANDII) 15 B. CHEMILUMINESCENT REACTIONS 17
///. AUTOXIDATION REACTIONS 19 111. 1 HYDROCARBONS 19 111.1.1
THEEXCITATIONSTEP 22 111.1.2 POLYMERS 24 III. 1.3 BASE-CATALYSED
AUTOXIDATION OF CARBONYL COM- POUNDS 26 III. 1.4 GRIGNARD COMPOUNDS 28
III.1.5 INHIBITORS 30 III. 1.6 MISCELLANEOUS OXIDATION REACTIONS 30
III.1.6.1 OXIDATIVE CHEMILUMINESCENCE OF COALS . . 30 III. 1.6.2
CYSTEINE AND GLUTATHIONE 30 111.2 REFERENCES 31 IV. CHEMILUMINESCENT
PEROXIDE DECOMPOSITIONS,! (EXCEPT DIOXETANS) . 33 IV. 1 PEROXIDE
CHEMILUMINESCENCE BY CIEEL 33 IV.2 ACYCLICSEC.-PEROXY-ESTERS 35 TABLE OF
CONTENTS IV.3 DIOXETANONES 37 IV.4 DIPHENOYL PEROXIDE 41 IV.5 OTHER
CYCLICDIACYL PEROXIDES. PHTHALOYL PEROXIDE 42 IV. 6 CHEMILUMINESCENCE OF
O-DICARBOXYLIC ACID CHLORIDES ... 45 IV.7 OTHER CYCLIC PEROXIDES 46 IV.8
ACENE ENDO-PEROXIDES 48 IV.9 POLYHYDROXY-PHENOL- AND PURPUROGALHN
CHEMILUMINES- CENCE 50 IV.10 REFERENCES 51 PEROXIDE DECOMPOSITIONS, II:
DIOXETANS 54 V.L SIMPLE DIOXETANS 55 V.2 EXCITATION YIELDS AND
MULTIPLICITY 56 V.3 MEASUREMENT OF SINGLET AND TRIPLET YIELDS 56 V.4
THERMOCHEMISTRY AND KINETICS 57 V.5 MECHANISMOFEXCITED STATE FORMATION
FROM DIOXETANS .... 58 V.5.1 THE DIRADICAL MECHANISM 59 V.5.2 THE
CONCERTED OR ELECTRON TRANSFER MECHANISM .... 60 V.6 QUENCHING REACTIONS
OF DIOXETANS 65 V.7 SYMMETRY FORBIDDEN REACTIONS IN CHEMILUMINESCENCE
.... 66 V.8 REFERENCES 67 PEROXY OXALATE CHEMILUMINESCENCE 69 VI.L
REQUIREMENTS FOR OXALATE CHEMILUMINESCENCE 70 VI.2 THE MECHANISM 74 VI.3
REFERENCES 76 LUMINOL AND RELATED COMPOUNDS 77 VII. 1 STRUCTURE AND
ACTIVITYOFPHTHALIC ACID HYDRAZIDES 77 VII. 1.1 MISCELLANEOUS CYCLIC
HYDRAZIDES 80 VII. 1.1.1 COMPOUNDS WITH MULTIPLE HYDRAZIDE GROUPS 80
VII.2 THEEMITTINGSPECIES 82 VII.3 ENERGY TRANSFER IN LUMINOL TYPE
CHEMILUMINESCENCE ... 85 VII.4 SOLVENT EFFECTS 88 VII.5 EFFECT
OFMICELLE-FORMINGAGENTS 88 VII.6 CATALYSTACTIVITY 89 VII.7 THE MECHANISM
OF LUMINOL CHEMILUMINESCENCE 89 VII.7.1 IONIC SPECIES DERIVED FROM
LUMINOL 90 VII.7.2 DIAZAQUINONE CHEMILUMINESCENCE 91 VII.7.3
INTERMEDIATE PEROXIDES 96 VII.7.4 1,4-DIALKOXY PHTHALAZINES AS POTENTIAL
PRECURSORS OFTHELUMINOL- ENDOPEROXIDE 99 VII TABLE OF CONTENTS VII.7.5
LUMINOL RADICAL ANIONS AS INTERMEDIATES (PULSE RADIOLYSIS EXPERIMENTS)
99 VII.7.6 PRESENT STATE OF HYPOTHESES ON LUMINOL CHEMILUMINESCENCE
MECHANISM 101 VII.8 MONOACYLHYDRAZIDES 104 VII.8.1 CHEMILUMINESCENCE
MECHANISM OF MONOACYLHYD- RAZIDES 105 VII.9 REFERENCES 106 VIII.
ACRIDINE DERIVATIVES 109 VIII. 1 LUCIGENIN 109 VIII. 1.1 THE REACTION
MECHANISM 109 VIII .1.2 ENERGY TRANSFER IN LUCIGENIN CHEMILUMINESCENCE
113 VIII. 1.3 INFLUENCE OF MICELLE FORMING AGENTS ON THE LUCIGENIN
REACTION 114 VIII.2 ACRIDINIUM SALTS AND ACRIDANS 114 VIII.3 REFERENCES
117 IX. OTHER NITROGEN-CONTAINING COMPOUNDS-IMINE PEROXIDES 119 IX. 1
TETRAKIS-DIALKYLAMINOETHYLENES 119 IX.2 BIS-ISOQUINOLINIUM SALTS 120
IX.3 LOPHINE AND RELATED COMPOUNDS 121 IX.4 INDOLE DERIVATIVES 122 IX. 5
CHEMILUMINESCENT SCHIFF BASES 123 IX.6 REFERENCES 123 X. MISCELLANEOUS
COMPOUNDS 125 X.L CHLORINATED CYCLICCARBONATES,GLYCOLIDES AND ETHERS
.... 125 X.2 SULFURANES 126 X.3 THIOESTERS 127 X.4 VINYLHALIDES 127 X.5
STRAINED HYDROCARBON ISOMERISATION 128 X.6 METALPHOSPHIDES 128 X.7
REFERENCES 129 XI. ELECTRON TRANSFER CHEMILUMINESCENCE 130 XI. 1
ELECTROGENERATED CHEMILUMINESCENCE (ECL) 130 XI. 1.1 ENERGY-SUFFICIENT
AND ENERGY-DEFICIENT ECL 132 XI. 1.1.1 ENERGY-DEFICIENT ECL 133 XI. 1.2
CHEMILUMINESCENT REACTIONS OF ELECTROGENERATED RADICAL ANIONS WITH
ORGANIC HALIDES 136 VIII TABLE OF CONTENTS XL 1.3 EFFICIENCYOFECL
REACTIONS 136 XL 1.4 RUTHENIUM CHELATE COMPLEXES 137 XL 2
CHEMILUMINESCENT REACTIONS OF RADICAL ANIONS WITH VARIOUS ELECTRON
ACCEPTORS 140 XI.2.1 WURSTER S BLUE-TYPE COMPOUNDS, SUBST. TRIPHENYL-
AMINES 141 XL2.2 ELECTRON TRANSFER REACTIONS IN METAL COMPLEXES . . .
144 XL 3 DISTINCTIONS BETWEEN RADICAL MECHANISMS FOR THE GENERATION
OFEXCITED STATES 145 XI.4 REFERENCES 146 C. BIOLUMINESCENCE 149 XII.
BIOLUMINESCENCE AS A SPECIAL CASE OF CHEMILUMINESCENCE 151 XII.1
BIOLUMINESCENT ORGANISMS 151 XII.1.1 THEFIREFLY 152 XII.1.2 MODELS FOR
FIREFLY LUCIFERIN 153 XII. 1.3 CYPRIDINA AND COELENTERATE
BIOLUMINESCENCE . . . 154 XII.1.4 BACTERIALBIOLUMINESCENCE 156 XII.2
GENERAL MODELS FOR BIOLUMINESCENT REACTIONS 158 XII.2.1 ELECTRON-RICH
DIOXETANS 158 XII.2.2 ACRIDANS AS MODEL COMPOUNDS 159 XII.2.3 MODELS FOR
THE EXCITATION STEP 160 XII.3 OTHER BIOLUMINESCENT ORGANISMS 162 XII.4
REFERENCES 162 D. APPLICATIONS 165 XIII. ANALYTICAL AND OTHER
APPLICATIONS OF CHEMI-AND BIOLUMINESCENCE . 167 XIII. A ANALYTICAL
APPLICATIONS 167 XIII. A.L GENERAL AND INORGANIC CHEMISTRY 168
XIII.A.1.1 ACID-BASE-TITRATIONS 168 XIII.A.1.2 REDOX TITRATIONS 168
XIII.A.1.2.1 OXIDANTS 168 XIII.A.1.2.1.1 MOLECULAROXYGEN;OZONE 170
XIII.A.1.3 METALLONS 170 XIII.A.1.4 NEGATIVE (INHIBITORY) METAL
CATALYSIS . . . . 171 XIII.A.1.5 BIOLUMINESCENT METAL ASSAYS 172
XIII.A.2 ORGANIC COMPOUNDS 173 XIII.A.2.1 AMINOACIDS 173 XIII.A.2.2
OXIMES 173 XIII.A.2.3 ORGANOPHOSPHORUS COMPOUNDS 173 IX TABLE OF
CONTENTS XIII.A.2.4 PHENOLS, NAPHTHOLS 174 XIII.A.2.5 AUTOXIDATIONS 174
XIII. A.2.5.1 OXIDATIVE DEGRADATION OF MOLECULES CON- TAINING LONG-CHAIN
ALIPHATIC RESIDUES . . 174 XIII.A.2.5.2 EFFICIENCY OF RADICAL CHAIN
INHIBITORS AND INITIATORS 175 XIII.A.2.5.3 DETERMINATION OF LOW
CONCENTRATIONS OF MOLECULAROXYGEN;THE OXYGENDROP . . 176 XIII.A.2.5.4
OTHERMETHODSOFOXYGEN DETERMINATION . 177 XIII.A.2.6 GLUCOSE 177
XIII.A.2.7 ALCOHOLSANDALDEHYDES 177 XIII.A.3 BIOLOGICAL SYSTEMS 178
XIII.A.3.1 ATP ASSAYWITH FIREFLYBIOLUMINESCENCE . . 178 XIII. A.3.1.1
SCOPEOFTHE ATP ASSAY 179 XIII. A.3.1.2 CREATINE KINASE AND PYRUVATE
KINASE . . . 179 XIII.A.3.2 ANALYTICAL APPLICATIONS OF BACTERIAL BIO-
LUMINESCENCE 179 XIII.A.3.2.1 ACTIVITYOFLIPASES 179 XIII.A.3.2.2
MUTAGENICACTIVITY 180 XIII.A.3.2.3 NAD (P)H-ASSAY 180 XIII.A.4
PHAGOCYTOSIS 180 XIII.A.5 CHEMILUMINESCENT IMMUNOASSAYS 181 XIII.A.5.1
DRUGASSAY 183 XIII. B OTHER APPLICATIONS 185 XIII.B.L EMERGENCYLIGHTING
185 XIII.B.2 SIGNALLINGANDMARKING 186 XIII.B.3 SPECIAL DISPLAY DEVICES
186 XIII.B.4 AS INDICATOR SYSTEMS IN PROCESSES INVOLVING OXIDANTS 186
XIII.C REFERENCES 186 XIV. INSTRUMENTATION 192 XIV.L REFERENCES 193 XV.
CHEMILUMINESCENT DEMONSTRATIONS 195 XV. 1 REFERENCES AND SOURCESOF
MATERIALS 201 XVI. CHEMILUMINESCENCE IN THE FUTURE 20 3 APPENDIX: TABLE
OFLUMINOL TYPE HYDRAZIDES 204 SUBJECTLNDEX 209 X
|
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| id | DE-604.BV000652542 |
| illustrated | Illustrated |
| indexdate | 2024-12-20T07:24:31Z |
| institution | BVB |
| isbn | 354017155X |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-000406631 |
| oclc_num | 439146929 |
| open_access_boolean | |
| owner | DE-12 DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-355 DE-BY-UBR DE-29T DE-634 DE-83 DE-188 |
| owner_facet | DE-12 DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-355 DE-BY-UBR DE-29T DE-634 DE-83 DE-188 |
| physical | X, 217 S. graph. Darst. |
| publishDate | 1987 |
| publishDateSearch | 1987 |
| publishDateSort | 1987 |
| publisher | Springer |
| record_format | marc |
| series | Reactivity and structure |
| series2 | Reactivity and structure |
| spellingShingle | Gundermann, Karl-Dietrich MacCapra, Frank Chemiluminescence in organic chemistry Reactivity and structure Biolumineszenz (DE-588)4145636-1 gnd Chemilumineszenz (DE-588)4147623-2 gnd Organische Verbindungen (DE-588)4043816-8 gnd |
| subject_GND | (DE-588)4145636-1 (DE-588)4147623-2 (DE-588)4043816-8 |
| title | Chemiluminescence in organic chemistry |
| title_auth | Chemiluminescence in organic chemistry |
| title_exact_search | Chemiluminescence in organic chemistry |
| title_full | Chemiluminescence in organic chemistry Karl-Dietrich Gundermann ; Frank McCapra |
| title_fullStr | Chemiluminescence in organic chemistry Karl-Dietrich Gundermann ; Frank McCapra |
| title_full_unstemmed | Chemiluminescence in organic chemistry Karl-Dietrich Gundermann ; Frank McCapra |
| title_short | Chemiluminescence in organic chemistry |
| title_sort | chemiluminescence in organic chemistry |
| topic | Biolumineszenz (DE-588)4145636-1 gnd Chemilumineszenz (DE-588)4147623-2 gnd Organische Verbindungen (DE-588)4043816-8 gnd |
| topic_facet | Biolumineszenz Chemilumineszenz Organische Verbindungen |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000406631&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000895108 |
| work_keys_str_mv | AT gundermannkarldietrich chemiluminescenceinorganicchemistry AT maccaprafrank chemiluminescenceinorganicchemistry |
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Teilbibliothek Chemie
| Signatur: |
0302 CHE 626f 1987 A 5832 Lageplan |
|---|---|
| Exemplar 1 | Ausleihbar Am Standort |